An alternative and fast method for the analysis of a mixture of nine triazines herbicides in soil is presented. The method is based on MAE （microwave-assisted extraction） of herbicides using ethyl acetate as extract...An alternative and fast method for the analysis of a mixture of nine triazines herbicides in soil is presented. The method is based on MAE （microwave-assisted extraction） of herbicides using ethyl acetate as extractant. The economy in the use of solvents coupled with the decrease in extraction time and lower power consumption make MAE a technique that meets the principles of green chemistry. MAE operational parameters, extraction time, mass of the sample and extraction temperature, were optimized by RSM （response surface methodology）. Determination of analytes was completed using gas chromatograph coupled to mass spectrometry detection. The selected triazines could be efficiently extracted by the solvent at 80 ℃ for 10 min, with 80% output of maximum power. When the optimized method was applied to analysis samples, the recoveries of analytes ranged from 81.8 to 106.0% and relative standard deviations were lower than 8.41%. The method is stable and reasonable, which can be used for the determination of ninetriazine herbicides residues in soil.展开更多
This paper reports some experimental detecting results of pollutants in the atmosphere by means of laser mass spectrometry. For toluene as calibration gas, the calibration procedure was also given. Benzene, toluene an...This paper reports some experimental detecting results of pollutants in the atmosphere by means of laser mass spectrometry. For toluene as calibration gas, the calibration procedure was also given. Benzene, toluene and xylene were discovered in testing indoor atmosphere resulting from dope in the course of fitment. Meanwhile, it is noticeable that the concentration of various harmful elements is obviously decreasing as timegoeson.展开更多
This paper proposes a new and distribution-free test called ＂Group Contingency＂ test （GC, for short） for testing two or several independent samples. Compared with traditional nonparametric tests, GC test tends to ...This paper proposes a new and distribution-free test called ＂Group Contingency＂ test （GC, for short） for testing two or several independent samples. Compared with traditional nonparametric tests, GC test tends to explore more information based on samples, and it＇s location-, scale-, and shapesensitive. The authors conduct some simulation studies comparing GC test with Wilcoxon rank sum test （W）, Kolmogorov-Smirnov test （KS） and Wald-Wolfowitz runs test （WW） for two sample case, and with Kruskal-Wallis （KW） for testing several samples. Simulation results reveal that GC test usually outperforms other methods.展开更多
文摘An alternative and fast method for the analysis of a mixture of nine triazines herbicides in soil is presented. The method is based on MAE （microwave-assisted extraction） of herbicides using ethyl acetate as extractant. The economy in the use of solvents coupled with the decrease in extraction time and lower power consumption make MAE a technique that meets the principles of green chemistry. MAE operational parameters, extraction time, mass of the sample and extraction temperature, were optimized by RSM （response surface methodology）. Determination of analytes was completed using gas chromatograph coupled to mass spectrometry detection. The selected triazines could be efficiently extracted by the solvent at 80 ℃ for 10 min, with 80% output of maximum power. When the optimized method was applied to analysis samples, the recoveries of analytes ranged from 81.8 to 106.0% and relative standard deviations were lower than 8.41%. The method is stable and reasonable, which can be used for the determination of ninetriazine herbicides residues in soil.
文摘This paper reports some experimental detecting results of pollutants in the atmosphere by means of laser mass spectrometry. For toluene as calibration gas, the calibration procedure was also given. Benzene, toluene and xylene were discovered in testing indoor atmosphere resulting from dope in the course of fitment. Meanwhile, it is noticeable that the concentration of various harmful elements is obviously decreasing as timegoeson.
基金This research is supported-by the National Natural Science Foundation of China under Grant No. 10731010 and Ph.D. Program Foundation of Ministry of Education of China under Grant No. 20090001110005.
文摘This paper proposes a new and distribution-free test called ＂Group Contingency＂ test （GC, for short） for testing two or several independent samples. Compared with traditional nonparametric tests, GC test tends to explore more information based on samples, and it＇s location-, scale-, and shapesensitive. The authors conduct some simulation studies comparing GC test with Wilcoxon rank sum test （W）, Kolmogorov-Smirnov test （KS） and Wald-Wolfowitz runs test （WW） for two sample case, and with Kruskal-Wallis （KW） for testing several samples. Simulation results reveal that GC test usually outperforms other methods.
