Chromatography-mass spectrometry(GC-MS)was used to analyze the volatile components of cut tobacco samples with the help of heuristic evolving latent projections(HELP).After extracting with simultaneous distillation an...Chromatography-mass spectrometry(GC-MS)was used to analyze the volatile components of cut tobacco samples with the help of heuristic evolving latent projections(HELP).After extracting with simultaneous distillation and extraction method,the volatile components in cut tobacco were detected by GC-MS.Then the obtained original two-dimensional data were resolved into pure mass spectra and chromatograms.The qualitative analysis was performed by similarity searches in the national institute of standards and technology(NIST)mass database with the obtained pure mass spectrum of each component and the quantitative results were obtained by calculating the volume of total two-way response.The accuracy of qualitative and quantitative results were greatly improved by using the two-dimensional comprehensive information of chromatograms and mass spectra.107 of 141 separated constituents in the total ion chromatogram of the volatile components were identified and quantified,accounting for about 88.01% of the total content.The result proves that the developed method is powerful for the analysis of complex cut tobacco samples.展开更多
In this study,the authors focus on the cut-off low pressure systems(COLs)lingering over East Asia in late spring and early summer and quantify the two-way stratosphere–troposphere exchange(STE)by 3D trajectory in...In this study,the authors focus on the cut-off low pressure systems(COLs)lingering over East Asia in late spring and early summer and quantify the two-way stratosphere–troposphere exchange(STE)by 3D trajectory integrations,achieved using a revised version of the UK Universities Global Atmospheric Modelling Programme Offline Trajectory Code(Version 3).By selecting 10 typical COLs and calculating the cross-tropopause air mass fluxes,it is found that stratosphere-to-troposphere transport(STT)fluxes exist in the center of COLs;and in the periphery of the COL center,troposphereto-stratosphere transport(TST)fluxes and STT fluxes are distributed alternately.Net transport fluxes in COLs are from stratosphere to troposphere,and the magnitude is about 10-4 kg m-2 s-1.The ratio between the area-averaged STT and TST fluxes increases with increasing strength of the COLs.By adopting appropriate residence time,the spurious transports are effectively excluded.Finally,the authors compare the results with previous studies,and find that the cross-tropopause fluxes(CTFs)induced by COLs are about one to two orders of magnitude larger than global CTFs.COLs play a significant role in local,rapid air mass exchanges,although they may only be responsible for a fraction of the total STE.展开更多
Gasification efficiency is an important factor that determines the actual technical operation as well as the economic viability of using a gasifier system for energy production. In this study, the impact of the physic...Gasification efficiency is an important factor that determines the actual technical operation as well as the economic viability of using a gasifier system for energy production. In this study, the impact of the physical properties of torrefied bagasse and the influence of gasifier design and operating variables were investigated in a computer simulated downdraft gasification system. Results obtained from the study indicated an interrelationship between feedstock characteristics, especially with regard to feed size, design variables such as throat angle and throat diameter as well as gasifier operating conditions such as temperature of input air and feed input. These variables influenced the efficiency of the gasification process of sugarcane bagasse because of increased enhancement of combustion zone reactions, which liberated huge amount of heat that led to a rise in the temperature of the gasification process. This condition also created increased tar cracking within the gasification system, contributing to reduction in the overall yield of tar.展开更多
Steam generator is optimized by applying entransy dissipation extremum principle and constructal theory and adopting analyti-cal method.The obtained results show that the optimal spacing between adjacent tubes,the mas...Steam generator is optimized by applying entransy dissipation extremum principle and constructal theory and adopting analyti-cal method.The obtained results show that the optimal spacing between adjacent tubes,the mass flow rate of gas and the maximum entransy dissipation rate all depend on the dimensionless diameter of one tube,the dimensionless pressure difference number and the dimensionless length of flow channel of gas.Besides the three dimensionless groups,the optimal numbers of riser tubes and downcomer tubes and their summation all depend on the dimensionless height of one tube.The maximum entransy dissipation rate increases as the pressure difference that drives the gas flowing increases,and as the diameter of one tube and the length of flow channel both decrease.The mean heat flux in the heat transfer process of hot gas grows greatly,and the performance of the system is improved.Compared with the optimal construct with heat transfer rate maximization,the optimal construct with entransy dissipation rate maximization can improved the heat transfer effect of the steam generator more.展开更多
基金Project supported by the Postdoctoral Foundation of Changde Cigarette FactoryProject(20060400887) supported by China Postdoctoral Science Foundation
文摘Chromatography-mass spectrometry(GC-MS)was used to analyze the volatile components of cut tobacco samples with the help of heuristic evolving latent projections(HELP).After extracting with simultaneous distillation and extraction method,the volatile components in cut tobacco were detected by GC-MS.Then the obtained original two-dimensional data were resolved into pure mass spectra and chromatograms.The qualitative analysis was performed by similarity searches in the national institute of standards and technology(NIST)mass database with the obtained pure mass spectrum of each component and the quantitative results were obtained by calculating the volume of total two-way response.The accuracy of qualitative and quantitative results were greatly improved by using the two-dimensional comprehensive information of chromatograms and mass spectra.107 of 141 separated constituents in the total ion chromatogram of the volatile components were identified and quantified,accounting for about 88.01% of the total content.The result proves that the developed method is powerful for the analysis of complex cut tobacco samples.
基金supported by the Special Fund for Strategic Pilot Technology,Chinese Academy of Sciences[grant number XDA05040300]
文摘In this study,the authors focus on the cut-off low pressure systems(COLs)lingering over East Asia in late spring and early summer and quantify the two-way stratosphere–troposphere exchange(STE)by 3D trajectory integrations,achieved using a revised version of the UK Universities Global Atmospheric Modelling Programme Offline Trajectory Code(Version 3).By selecting 10 typical COLs and calculating the cross-tropopause air mass fluxes,it is found that stratosphere-to-troposphere transport(STT)fluxes exist in the center of COLs;and in the periphery of the COL center,troposphereto-stratosphere transport(TST)fluxes and STT fluxes are distributed alternately.Net transport fluxes in COLs are from stratosphere to troposphere,and the magnitude is about 10-4 kg m-2 s-1.The ratio between the area-averaged STT and TST fluxes increases with increasing strength of the COLs.By adopting appropriate residence time,the spurious transports are effectively excluded.Finally,the authors compare the results with previous studies,and find that the cross-tropopause fluxes(CTFs)induced by COLs are about one to two orders of magnitude larger than global CTFs.COLs play a significant role in local,rapid air mass exchanges,although they may only be responsible for a fraction of the total STE.
文摘Gasification efficiency is an important factor that determines the actual technical operation as well as the economic viability of using a gasifier system for energy production. In this study, the impact of the physical properties of torrefied bagasse and the influence of gasifier design and operating variables were investigated in a computer simulated downdraft gasification system. Results obtained from the study indicated an interrelationship between feedstock characteristics, especially with regard to feed size, design variables such as throat angle and throat diameter as well as gasifier operating conditions such as temperature of input air and feed input. These variables influenced the efficiency of the gasification process of sugarcane bagasse because of increased enhancement of combustion zone reactions, which liberated huge amount of heat that led to a rise in the temperature of the gasification process. This condition also created increased tar cracking within the gasification system, contributing to reduction in the overall yield of tar.
基金supported by the National Natural Science Foundation of China (Grant No 10905093)the Program for New Century Excellent Talents in University of China (Grant No NCET-04-1006)the Foun-dation for the Author of National Excellent Doctoral Dissertation of China (Grant No 200136)
文摘Steam generator is optimized by applying entransy dissipation extremum principle and constructal theory and adopting analyti-cal method.The obtained results show that the optimal spacing between adjacent tubes,the mass flow rate of gas and the maximum entransy dissipation rate all depend on the dimensionless diameter of one tube,the dimensionless pressure difference number and the dimensionless length of flow channel of gas.Besides the three dimensionless groups,the optimal numbers of riser tubes and downcomer tubes and their summation all depend on the dimensionless height of one tube.The maximum entransy dissipation rate increases as the pressure difference that drives the gas flowing increases,and as the diameter of one tube and the length of flow channel both decrease.The mean heat flux in the heat transfer process of hot gas grows greatly,and the performance of the system is improved.Compared with the optimal construct with heat transfer rate maximization,the optimal construct with entransy dissipation rate maximization can improved the heat transfer effect of the steam generator more.