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SO_2在高岭土表面气-粒转化及影响因素 被引量:2
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作者 焦坤灵 袁猛 +3 位作者 张连科 孙鹏 李玉梅 武文斐 《环境工程学报》 CAS CSCD 北大核心 2016年第9期5082-5088,共7页
利用自制气溶胶反应器通过实验研究了不同相对湿度(RH)、光照、NOx和NH3条件对SO_2在高岭土表面的气-粒转化过程和SO_2-4生成量的影响。结果表明:RH是影响高岭土表面SO_2转化及SO_2-4生成的最重要因素,随着RH的增加,高岭土表面SO_2的转... 利用自制气溶胶反应器通过实验研究了不同相对湿度(RH)、光照、NOx和NH3条件对SO_2在高岭土表面的气-粒转化过程和SO_2-4生成量的影响。结果表明:RH是影响高岭土表面SO_2转化及SO_2-4生成的最重要因素,随着RH的增加,高岭土表面SO_2的转化量及SO_2-4的生成量也明显增加,其中SO_2转化量最大增幅达600%;光照条件对高岭土表面SO_2的转化及SO_2-4的生成也有一定影响,光照越强SO_2的转化量及SO_2-4的生成量越高;NOx和NH3的存在会促进SO_2在高岭土表面的转化和SO_2-4的生成,协同作用明显。 展开更多
关键词 溶胶反应器 SO_2 高岭土 气-粒转化
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珠三角地区大气新粒子增长-缩小过程特征 被引量:8
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作者 岳玎利 钟流举 +4 位作者 沈劲 张涛 袁鸾 周炎 曾立民 《环境污染与防治》 CAS CSCD 北大核心 2016年第3期1-7,共7页
广东大气超级监测站新粒子生成事件中,在新粒子快速增长后观测到明显的颗粒物缩小过程(即新粒子增长-缩小过程)。结合3~1 000nm颗粒物数谱分布、颗粒物化学组成和重要气态污染物的变化,具体分析这类新粒子生成事件出现颗粒物缩小过程的... 广东大气超级监测站新粒子生成事件中,在新粒子快速增长后观测到明显的颗粒物缩小过程(即新粒子增长-缩小过程)。结合3~1 000nm颗粒物数谱分布、颗粒物化学组成和重要气态污染物的变化,具体分析这类新粒子生成事件出现颗粒物缩小过程的特性和成因。结果表明,秋季新粒子生成事件发生频率和新粒子增长-缩小过程出现频率均较高。新粒子增长速率为3.0~12.0nm/h,颗粒物缩小速率为2.2~10.9nm/h。新粒子增长过程中,颗粒有机物对PM_(2.5)浓度贡献最大;颗粒物缩小过程中,SO_4^(2-)对PM_(2.5)浓度贡献最大,且SO_4^(2-)、NH_4^+和元素碳对PM_(2.5)浓度的贡献有所提高;NO_3^-和颗粒有机物对PM_(2.5)浓度的贡献下降,且颗粒有机物中二次有机颗粒物对PM_(2.5)浓度贡献的下降幅度明显大于颗粒有机物对PM_(2.5)浓度贡献的下降幅度。经分析,固态NH4NO3分解和低挥发性有机物挥发是颗粒物缩小的重要直接原因,扩散条件改善和大气氧化性减弱可能是推动新粒子增长转为颗粒物缩小过程的重要条件。 展开更多
关键词 子生成新子增长颗物缩小气-粒转化
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Torrefied Pellets as Fuel for Two-Stage Technology of Biomass Conversion into Synthesis Gas
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作者 Victor Zaichenko Valentin Kosov Julia Kuzmina Vladimir Lavrenov 《Journal of Energy and Power Engineering》 2014年第1期79-84,共6页
One of the most important properties of the torrefied pellets, along with high calorific value, is their hydrophobicity. Inability to absorb moisture and self-destruct under its influence determine possibility of usin... One of the most important properties of the torrefied pellets, along with high calorific value, is their hydrophobicity. Inability to absorb moisture and self-destruct under its influence determine possibility of using of pellets in the pyrolysis reactor. For the technology of two-stage thermal processing of biomass, developed at the Joint Institute for High Temperatures, the amount of synthesis gas which can be obtained from one kilogram of torrefied pellets is also important. A construction of the pilot torrefaction reactor powered by flue gas is shown. The results of experimental investigations of hydrophobicity of torrefied pellets produced by the reactor and quantity of synthesis gas which can be obtained by two-stage thermal processing of the pellets are presented. It is shown that torrefaction allows simplifying the process of conversion of pellets into synthesis gas without significant reduction in the volume of the gas. 展开更多
关键词 Biomass conversion TORREFACTION PYROLYSIS syngas.
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Experimental study on the spatial distribution of particle rotation in the upper dilute zone of a cold CFB riser 被引量:1
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作者 Xue-cheng WU Qin-hui WANG +3 位作者 Chen TIAN Zhong-yang LUO Meng-xiang FANG Ke-fa CEN 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2008年第7期922-931,共10页
Particle rotation plays an important role in gas-solid flows. This paper presents an experimental investigation on the spatial distribution of average rotation speed for glass beads in the upper dilute zone of a cold ... Particle rotation plays an important role in gas-solid flows. This paper presents an experimental investigation on the spatial distribution of average rotation speed for glass beads in the upper dilute zone of a cold circulating fluidized bed(CFB) riser. It is shown that in the horizontal direction,the average rotation speed in the near-wall area is larger than that in the center area,while in the vertical direction,it decreases as the height increases. The reason resulting in this distribution is analyzed by considering several factors including particle size,particle shape,particle number density,particle collision behavior,and the surrounding flow field,etc. The effects of CFB operation conditions on the spatial distribution of average rotation speed are also studied. The results show that the increasing superficial gas velocity increases the average rotation speed of particles in the near wall area but takes nearly no effect on that in the center area. The external solids mass flux,however,takes the opposite effect. It is found that the average rotation speeds of particles in both areas are increased as the total amount of bed material increases. 展开更多
关键词 Particle rotation Gas-solid two-phase flow Circulating fluidized bed (CFB)
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Effects of dietary fresh fermented soybean meal on growth performance, ammonia and particulate matter emissions, and nitrogen excretion in nursery piglets 被引量:17
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作者 Sai-sai CHENG Yuan LI +3 位作者 Shi-jie GENG Luan-sha HU Xiong-feng FU Xin-yan HAN 《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》 SCIE CAS CSCD 2017年第12期1083-1092,共10页
This study was conducted to investigate the effects of fresh fermented soybean meal(FSM) on the growth performance of nursery piglets, nitrogen excretion in feces, and the concentrations of ammonia(NH3) and partic... This study was conducted to investigate the effects of fresh fermented soybean meal(FSM) on the growth performance of nursery piglets, nitrogen excretion in feces, and the concentrations of ammonia(NH3) and particulate matter(PM) in the piggery. A total of 472 nursery piglets(Landrace×Yorkshire,(16.3±0.36) kg body weight) were randomly allocated into two treatments with 236 pigs in each treatment. The pigs were fed the basal diet without fresh FSM(control) or diet containing 10%(100 g/kg) fresh FSM(FSM group), and the crude protein content of the two groups was consistent. The feeding trial lasted for 28 d. The results showed that the pigs fed fresh FSM had increased(P〈0.05) average daily gain(ADG) compared with the control. There was no significant difference(P〈0.05) in feed to gain ratio(F:G) between the two groups. During the whole experiment, the concentration of NH3 in the piggery decreased(P〈0.05) by 19.0%, and the concentrations of PM(PM(10) and PM(2.5)) in the piggery decreased(P〈0.05) by 19.9% and 11.6%, respectively, in the FSM group, compared with the control. The ammonia nitrogen and nitrite content in feces increased(P〈0.05) by 32.9% and 28.4%, respectively, in the FSM group. The fecal p H declined(P〈0.05) significantly in the FSM group compared with the control. At the end of experiment, total protein(TP) concentration was increased(P〈0.05) significantly and blood urea nitrogen(BUN) concentration was decreased(P〈0.05) for pigs fed the diet with fresh FSM. The results indicated that dietary fresh FSM not only improved the growth performance of nursery piglets, but also reduced the NH3 concentration in the piggery due to nitrogen conversion, and decreased the concentrations of PM(10) and PM(2.5) in the piggery. 展开更多
关键词 Fresh fermented soybean meal AMMONIA Particulate matter Nitrogen conversion Nursery piglet
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