A process of purification of coal-based coke powder as anode the treatment of coke powder with dilute hydrofluoric acid solution, for Li-ion batteries was attempted. The process started with followed by united-acid-le...A process of purification of coal-based coke powder as anode the treatment of coke powder with dilute hydrofluoric acid solution, for Li-ion batteries was attempted. The process started with followed by united-acid-leaching using sulfuric acid and hydrochloric acid. The effects of altering the hydrofluoric acid addition, hydrofluoric acid concentration, contact time, temperature and acid type were investigated. A minimum ash content of 0.35% was obtained when proper conditions were applied. The electrochemical performance of purified coke powder shows greatly improved electrochemical performance. The as-purified coke powder presented an initial reversible capacity of 257.4 mAh/g and a retention rate of 95% after 50 cycles. The proposed purification process paves a way to prepare a promising anode material with good performance with low cost of coke powder for Li-ion batteries.展开更多
A quantum dynamic calculation on a five-dimensional O2/LiF （001） model system is performed using themulti-configuration time-dependent Hartree method.The obtained results show that the mechanism of rotational anddif...A quantum dynamic calculation on a five-dimensional O2/LiF （001） model system is performed using themulti-configuration time-dependent Hartree method.The obtained results show that the mechanism of rotational anddiffractive excitation in details: Comparison with the rotational excited state, the initially non-rotational state is seento favor the inelastic scattering in the rotational excitation process.The surface corrugation can damp the quantuminterferences and produce a greater amount of rotational inelastic scattering at the expense of the elastic process inthe rotational excitation process.The diffraction process and the average energy transferred into the rotational anddiffractive mode are also discussed.展开更多
基金Projects(51274240,51204209) supported by the National Natural Science Foundation of ChinaProject(2012M521545) supported by the National Postdoctoral Science Foundation of China
文摘A process of purification of coal-based coke powder as anode the treatment of coke powder with dilute hydrofluoric acid solution, for Li-ion batteries was attempted. The process started with followed by united-acid-leaching using sulfuric acid and hydrochloric acid. The effects of altering the hydrofluoric acid addition, hydrofluoric acid concentration, contact time, temperature and acid type were investigated. A minimum ash content of 0.35% was obtained when proper conditions were applied. The electrochemical performance of purified coke powder shows greatly improved electrochemical performance. The as-purified coke powder presented an initial reversible capacity of 257.4 mAh/g and a retention rate of 95% after 50 cycles. The proposed purification process paves a way to prepare a promising anode material with good performance with low cost of coke powder for Li-ion batteries.
基金Support by the National Natural Science Foundation of China under Grant No.10776022 the Specialized Research Fund for the Doctoral Program of Higher Education under Grant No.20090181110080
文摘A quantum dynamic calculation on a five-dimensional O2/LiF （001） model system is performed using themulti-configuration time-dependent Hartree method.The obtained results show that the mechanism of rotational anddiffractive excitation in details: Comparison with the rotational excited state, the initially non-rotational state is seento favor the inelastic scattering in the rotational excitation process.The surface corrugation can damp the quantuminterferences and produce a greater amount of rotational inelastic scattering at the expense of the elastic process inthe rotational excitation process.The diffraction process and the average energy transferred into the rotational anddiffractive mode are also discussed.
