We have investigated the dynamics of the F＋C4H6 reaction using the universal crossed molecular beam method. The C4H5F＋H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have ...We have investigated the dynamics of the F＋C4H6 reaction using the universal crossed molecular beam method. The C4H5F＋H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have been measured for the C4H5F product. Prod- uct angular distributions as well as kinetic energy distributions were determined for this product channel. Experimental results show that the C4H5F product is largely backward scattered with considerable forward scattering signal, relative to the F atom beam direction. This suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct SN2 type mechanism.展开更多
文摘We have investigated the dynamics of the F＋C4H6 reaction using the universal crossed molecular beam method. The C4H5F＋H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have been measured for the C4H5F product. Prod- uct angular distributions as well as kinetic energy distributions were determined for this product channel. Experimental results show that the C4H5F product is largely backward scattered with considerable forward scattering signal, relative to the F atom beam direction. This suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct SN2 type mechanism.
