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双氧水装置氢化塔设备的应力腐蚀研究及防护
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作者 沈冬奎 冯晓刚 +3 位作者 闫风影 殷天峰 李家雄 张忠超 《石油和化工设备》 CAS 2015年第10期74-77,共4页
本文介绍了双氧水生产的基本工艺流程,分析了氢化塔氢化反应的工艺流程,重点阐述了氢化塔在定期检验中发现的问题,分析了氢化塔应力腐蚀裂纹产生的原因,针对氢化塔的应力腐蚀问题提出了针对性的改进和预防措施,为氢化塔的氢化工序安全... 本文介绍了双氧水生产的基本工艺流程,分析了氢化塔氢化反应的工艺流程,重点阐述了氢化塔在定期检验中发现的问题,分析了氢化塔应力腐蚀裂纹产生的原因,针对氢化塔的应力腐蚀问题提出了针对性的改进和预防措施,为氢化塔的氢化工序安全运行提供了参考依据。 展开更多
关键词 双氧水氢化塔 应力腐蚀 裂纹 氯离子 防护
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过氧化氢装置中氢化塔三节塔串联运行小结
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作者 于俊涛 《氮肥与合成气》 2021年第7期36-37,共2页
在蒽醌法生产过氧化氢的工艺中,氢化塔是整个生产工艺中的核心设备,设备内钯触媒的活性高低直接影响了装置的产量及消耗。通过对氢化塔三节塔串联生产工艺的应用研究,克服遇到的问题及难点,有效利用闲置触媒,提高钯触媒利用率,保证装置... 在蒽醌法生产过氧化氢的工艺中,氢化塔是整个生产工艺中的核心设备,设备内钯触媒的活性高低直接影响了装置的产量及消耗。通过对氢化塔三节塔串联生产工艺的应用研究,克服遇到的问题及难点,有效利用闲置触媒,提高钯触媒利用率,保证装置高产低耗、安全稳定运行。 展开更多
关键词 氢化塔 钯触媒 串联 效率
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蒽醌法制过氧化氢主要塔设备设计进展 被引量:3
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作者 王雪琦 张惠平 +1 位作者 程天来 王磊 《化学推进剂与高分子材料》 CAS 2017年第2期48-51,共4页
介绍了蒽醌法制过氧化氢工艺流程中主要设备氢化塔、氧化塔和萃取塔的设计;随生产工艺的改进和生产规模的不断扩大,为满足生产要求,详细叙述了上述3塔体积及内件设计的发展进程。
关键词 氢化塔 萃取 规模 内件
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双氧水装置氢化塔制作安装质量控制
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作者 杨志军 《科学家》 2016年第9期73-73,113,共2页
本文介绍了双氧水装置中的氢化塔从制造、安装及酸洗钝化各阶段的相关质量控制点进行了分析,对相关设备的质量控制具有借鉴意义。
关键词 氢化塔 制造安装 质量控制
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100kt/a蒽醌法过氧化氢装置稳产高产技改小结
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作者 张宇 朱家凤 《化工设计通讯》 CAS 2014年第5期87-89,共3页
针对100kt/a蒽醌法过氧化氢装置存在的诸多问题,通过工艺优化和设备改造,实现了装置的稳产高产,并指出系统仍存在的问题及挖潜的方向。
关键词 蒽醌法过氧装置 萃余 残液 氢化塔 液分离器 改造
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10万t/a过氧化氢项目实施总结
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作者 韩小刚 《氯碱工业》 CAS 2013年第1期31-33,37,共4页
从工艺、主要设备选择、安全环保设施、施工及试生产等方面总结了蒽醌法过氧化氢生产项目的实施经验。
关键词 过氧 蒽醌法工艺 氢化塔 萃取 安全设施 环保设施 运行情况
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蒽醌法过氧化氢生产装置试运行总结
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作者 孔凡锐 《氯碱工业》 CAS 2021年第5期27-28,共2页
总结了蒽醌法过氧化氢生产装置试运行中的注意事项及安全管理经验。
关键词 蒽醌法工艺 过氧 氢化塔 萃取 电气系统
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双氧水生产过程中萃取塔的积料问题 被引量:2
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作者 孟凡会 《化学工业与工程技术》 CAS 2006年第4期48-49,共2页
对双氧水生产过程中切换氢化塔的固定床时引发的萃取塔积料问题进行了深入分析,并结合实际生产经验,提出了具体的解决方法和预防措施。
关键词 双氧水生产 氢化塔 固定床 萃取 积料
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6万吨/年双氧水装置运行总结
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作者 李东帆 《化工管理》 2018年第27期81-82,共2页
氢化塔和氧化塔是双氧水装置的关键设备。氢化反应在固定床进行,床层压差很关键。循环水压力对氧化塔的温度控制很关键。
关键词 氢化塔 新型钯触媒 循环水
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双氧水装置扩能降耗技术改造
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作者 项翔 杨程 姚莉莉 《科技经济市场》 2016年第7期24-25,共2页
以湖北三宁化工股份有限公司15万吨/年(27.5%)双氧水装置扩能降耗技术改造为例,介绍了双氧水装置氢化和萃取工序存在的问题、技术改造措施及改造后的效果,供双氧水同行们参考。
关键词 双氧水 氢化塔 萃取 技术改造
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Biotreatment of Odor Waste Gases by Immobilized Ceramsite Biofilter 被引量:1
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作者 万俊杰 曾志聪 +4 位作者 谢键羽 庄煜培 罗凯平 柯志梅 黎志坤 《Agricultural Science & Technology》 CAS 2016年第3期737-741,共5页
[Objective] To find out the process conditions and influence factors for the biotreatment of odor gases of hydrogen sulfide(H2S) and ammonia(NH3). [Method]The degradation performances on H2 S and NH3 were investig... [Objective] To find out the process conditions and influence factors for the biotreatment of odor gases of hydrogen sulfide(H2S) and ammonia(NH3). [Method]The degradation performances on H2 S and NH3 were investigated during the start-up and stable operation process of biofilter with ceramsites as the packing microorganisms. [Result] The biofilm formation of the biofilter system to purify the waste gas of H2 S was completed within 9 d, and the removal rate of H2 S could reach up to 99% with the initial concentration of 100-1 000 mg/m^3 and empty bed residence time(EBRT) of142-290 s. The biofilm formation of the biofilter system to purify the waste gas of NH3 was completed within 10 d with the removal rate reaching up to 94.61%.[Conclusion] Under suitable conditions, the biofilter showed high removal rates to both H2 S and NH3. 展开更多
关键词 BIOFILTER AMMONIA Hydrogen sulfide BIOTREATMENT
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Gas-liquid mass transfer of carbon dioxide capture by magnesium hydroxide slurry in a bubble column reactor 被引量:6
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作者 XIE Peng-fei LI Li-qing +1 位作者 HE Zhi-cheng SU Chang-qing 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第6期1592-1606,共15页
Magnesium hydroxide(Mg(OH)2)has been considered as a potential solvent for CO2 removal of coal-fired power plant and biomass gas.The chemistry action and mass to transfer mechanism of CO2-H2O-Mg(OH)2 system in a slurr... Magnesium hydroxide(Mg(OH)2)has been considered as a potential solvent for CO2 removal of coal-fired power plant and biomass gas.The chemistry action and mass to transfer mechanism of CO2-H2O-Mg(OH)2 system in a slurry bubble column reactor was described,and a reliable computational model was developed.The overall mass transfer coefficient and surface area per unit volume were obtained using experimental approach and simulation with software assistance.The results show that the mass transfer process of CO2 absorbed by Mg(OH)2 slurry is mainly liquid-controlled,and slurry concentration and temperature are main contributory factors of volumetric mass transfer coefficient and liquid side mass transfer coefficient.High concentration of CO2 has an adverse effect on its absorption because it leads to the fast deposition of MgCO3·3H2O crystals on the surfaces of unreacted Mg(OH)2 particles,reducing the utilization ratio of magnesium hydroxide.Meanwhile,high CO3^2– ion concentration limits the dissolution of MgCO3 to absorb CO2 continually.Concentration of 0.05 mol/L Mg(OH)2,15%vol CO2 gas and operation temperature at 35℃are recommended for this CO2 capture system. 展开更多
关键词 mass transfer CO2 capture magnesium hydroxide bubble column
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Stark Effect Dependence on Hydrogenic Impurities in GaAs Parabolic Quantum-Well Wires 被引量:1
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作者 WANG Sheng WEI Guo-Zhu HAN Yu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第11期953-959,共7页
The ground-state and lowest excited-state binding energies of a hydrogenic impurity in GaAs parabolic quantum-well wires (Q WWs) subjected to external electric and magnetic fields are investigated using the finite-d... The ground-state and lowest excited-state binding energies of a hydrogenic impurity in GaAs parabolic quantum-well wires (Q WWs) subjected to external electric and magnetic fields are investigated using the finite-difference method within the quasi-one-dimensional effective potential model. We define an effective radius Pen of a cylindrical QWW, which can describe the strength of the lateral confinement. For the ground state, the position of the largest probability density of electron in x-y plane is located at a point, while for the lowest excited state, is located on a circularity whose radius is Pen. The point and circularity are pushed along the left haft of the center axis of the quantum-well wire by the electric field dire ted along the right half. When an impurity is located at the point or within the circularity, the ground-state or lowest excited-state binding energies are the largest; when the impurity is apart from the point or circularity, the ground-state or lowest excited-state binding energies start to decrease. 展开更多
关键词 hydrogenic impurity quantum-well wire magnetic field binding energy
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Applications of Inverted Pyramids Corroded by TMAH in PERL Silicon LED
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作者 GENG Bo-yun LI Xiao-yun NIU Ping-juan 《Semiconductor Photonics and Technology》 CAS 2009年第4期229-234,共6页
In this paper, a novel and reliable structure of the side passivated emitter and the rear locallydiffused(PERL) silicon light emitting diodes (LEDs) is proposed. The inverted pyramids surface, the important interf... In this paper, a novel and reliable structure of the side passivated emitter and the rear locallydiffused(PERL) silicon light emitting diodes (LEDs) is proposed. The inverted pyramids surface, the important interface in this structure, is given according to the experiment. The results show that the inverted pyramids surface has a low refection about 8%, in the anisotropic etching 70 ℃, 5% TMAH concentration, corrosion time of 90 min or 30 rain. Low refection means high light emitting rate. Most of the structure and manufacturing process can be compatible with planar CMOS technology, which makes the silicon LED greater potential for development in the future. 展开更多
关键词 PERL structure silicon LED inverted pyramids TMAH
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Geochemistry and possible origin of the hydrocarbons from Wells Zhongshen1 and Zhongshen1C, Tazhong Uplift 被引量:15
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作者 SONG DaoFu WANG TieGuan LI MeiJun 《Science China Earth Sciences》 SCIE EI CAS CSCD 2016年第4期840-850,共11页
In 2013, a great breakthrough of deep petroleum exploration was achieved in the Cambrian pre-salt intervals of Wells Zhongshen1(ZS1) and Zhongshen1C(ZS1C), Tazhong Uplift. However, the hydrocarbon discovery in the Cam... In 2013, a great breakthrough of deep petroleum exploration was achieved in the Cambrian pre-salt intervals of Wells Zhongshen1(ZS1) and Zhongshen1C(ZS1C), Tazhong Uplift. However, the hydrocarbon discovery in the Cambrian pre-salt intervals has triggered extensive controversy regarding the source of marine oils in the Tarim Basin. The geochemistry and origin of the Cambrian pre-salt hydrocarbons in Wells ZS1 and ZS1 C were investigated using GC, GC-MS and stable carbon isotope technique. These hydrocarbons can be easily distinguished into two genetic families based on their geochemical and carbon isotopic compositions. The oil and natural gases from the Awatage Formation of Well ZS1 are derived from Middle-Upper Ordovician source rocks. In contrast, the condensate and gases from the Xiaoerbulake Formation of Wells ZS1 and ZS1 C probably originate from Cambrian source rocks. The recent discovery of these hydrocarbons with two different sources in Wells ZS1 and ZS1 C suggests that both Middle-Upper Ordovician-sourced hydrocarbons and Cambrian-sourced petroleums are accumulated in the Tazhong Uplift, presenting a great exploration potential. 展开更多
关键词 Tazhong Uplift Wells ZS1 and ZS1C HYDROCARBON Organic geochemistry Oil/gas source identification
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