Reactive mechanical alloying(RMA)was carried out in a planetary ball mill for the synthesis of ternary hydride Mg2FeH6 for hydrogen storage.The formation mechanism of Mg2FeH6 in RMA process and the sorption properties...Reactive mechanical alloying(RMA)was carried out in a planetary ball mill for the synthesis of ternary hydride Mg2FeH6 for hydrogen storage.The formation mechanism of Mg2FeH6 in RMA process and the sorption properties of the products were investigated.The results show that Mg2FeH6 has a yield ratio around 80%,and a grain size below 10 nm in the powder synthesized by milling 3Mg+Fe mixture for 150 h under the hydrogen pressure of 1 MPa.The synthesized powder possesses a high hydrogen capacity and good sorption kinetics,and absorbs 4.42%(mass fraction)of hydrogen within 200 s at 623 K under the hydrogen pressure of 4.0 MPa.In releasing hydrogen at 653 K under 0.1 MPa,it desorbs 4.43%(mass fraction)of hydrogen within 2 000 s.The addition of Ti increases the hydrogen desorption rate of the complex in the initial 120 s of the desorption process.展开更多
The use of electric energy in marine vessels has been increasing in recent years. In general, it is motivated by the low ecological impact. However, in the case of underwater vehicles it is functionally essential. The...The use of electric energy in marine vessels has been increasing in recent years. In general, it is motivated by the low ecological impact. However, in the case of underwater vehicles it is functionally essential. The objective of this study is to demonstrate the advantage of electric power generation and storage based on on-board hydrogen generation via the reaction between activated aluminum and water and application of the hydrogen in a fuel cell. The original activation process enabling a spontaneous reaction with water to produce hydrogen as well as a parametric study of hydrogen generation rate and yield are briefly described. The potential increase in specific energy （energy per unit mass） and energy density （energy per unit volume） vs. batteries and other means of hydrogen storage is presented. It is shown that the use of the present technology may result in a substantial increase of specific electric energy along with a reduction in volume or an increase in operating time for the same overall mass of energy storage and generation system.展开更多
基金Project(50574105)supported by the National Natural Science Foundation of ChinaProject(10JJ2037)supported by Hunan Provincial Natural Science Foundation of ChinaProject(200902)supported by Innovation Foundation of State Key Laboratory for Powder Metallurgy,Central South University,China
文摘Reactive mechanical alloying(RMA)was carried out in a planetary ball mill for the synthesis of ternary hydride Mg2FeH6 for hydrogen storage.The formation mechanism of Mg2FeH6 in RMA process and the sorption properties of the products were investigated.The results show that Mg2FeH6 has a yield ratio around 80%,and a grain size below 10 nm in the powder synthesized by milling 3Mg+Fe mixture for 150 h under the hydrogen pressure of 1 MPa.The synthesized powder possesses a high hydrogen capacity and good sorption kinetics,and absorbs 4.42%(mass fraction)of hydrogen within 200 s at 623 K under the hydrogen pressure of 4.0 MPa.In releasing hydrogen at 653 K under 0.1 MPa,it desorbs 4.43%(mass fraction)of hydrogen within 2 000 s.The addition of Ti increases the hydrogen desorption rate of the complex in the initial 120 s of the desorption process.
文摘The use of electric energy in marine vessels has been increasing in recent years. In general, it is motivated by the low ecological impact. However, in the case of underwater vehicles it is functionally essential. The objective of this study is to demonstrate the advantage of electric power generation and storage based on on-board hydrogen generation via the reaction between activated aluminum and water and application of the hydrogen in a fuel cell. The original activation process enabling a spontaneous reaction with water to produce hydrogen as well as a parametric study of hydrogen generation rate and yield are briefly described. The potential increase in specific energy （energy per unit mass） and energy density （energy per unit volume） vs. batteries and other means of hydrogen storage is presented. It is shown that the use of the present technology may result in a substantial increase of specific electric energy along with a reduction in volume or an increase in operating time for the same overall mass of energy storage and generation system.
