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氧化玫瑰的合成研究
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作者 张方丽 陈立功 +1 位作者 白国义 泮锋纲 《化学通报》 CAS CSCD 北大核心 2003年第11期775-778,共4页
以 (R) (+ ) 香茅醇为原料 ,经溴化甲氧基化、消除、酸诱导环合三步反应合成了氧化玫瑰 ,三步总收率为 75 6 %。所得氧化玫瑰顺反异构体比例为 70 30~ 75 2 5 ,可用于配制高级玫瑰香精。
关键词 氧化玫瑰 合成 2-(2-甲基-丙烯基)-4-甲基-四氢吡喃 香精
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玫瑰花状氢氧化钴的结构和浸润性(英文) 被引量:2
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作者 马麦霞 梁君飞 丁春梅 《无机化学学报》 SCIE CAS CSCD 北大核心 2015年第6期1071-1075,共5页
在没有任何表面活性剂条件下,通过简单的方法首次合成了玫瑰花状β-Co(OH)2微晶。玫瑰花状β-Co(OH)2微晶宽3~5μm,厚2~3μm,是由平均厚度为15 nm的纳米片所组成。玫瑰花状β-Co(OH)2组成的薄膜的接触角为158.5°±1.2&... 在没有任何表面活性剂条件下,通过简单的方法首次合成了玫瑰花状β-Co(OH)2微晶。玫瑰花状β-Co(OH)2微晶宽3~5μm,厚2~3μm,是由平均厚度为15 nm的纳米片所组成。玫瑰花状β-Co(OH)2组成的薄膜的接触角为158.5°±1.2°,表面处于任意的角度,水滴都不会滴落。 展开更多
关键词 晶体结构 微观结构 玫瑰花状氢氧化 表面 粘附力
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Arg54保守位点对嗜热玫瑰红球菌肌氨酸氧化酶的底物适应性和催化效率的影响
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作者 唐萌蔚 黄爱敏 +2 位作者 顾正华 辛瑜 张梁 《食品与发酵工业》 CAS CSCD 北大核心 2022年第11期1-9,共9页
嗜热玫瑰红球菌肌氨酸氧化酶(thermophilus sarcosine oxidase,TrSOX)是一种N-甲基脱除酶,对底物具有特异的手性选择性并且对高温和有机溶剂具有良好的耐受性。在同源家族中,Arg54是催化中心严格保守的5个残基之一,为了研究该位点对酶... 嗜热玫瑰红球菌肌氨酸氧化酶(thermophilus sarcosine oxidase,TrSOX)是一种N-甲基脱除酶,对底物具有特异的手性选择性并且对高温和有机溶剂具有良好的耐受性。在同源家族中,Arg54是催化中心严格保守的5个残基之一,为了研究该位点对酶学性质的影响并筛选出具有良好催化效率的突变体,在预先构建的木糖诱导质粒pMA5-Pxyl-trsox中进行Arg54位点的定点饱和突变,并将得到的质粒转化到枯草芽孢杆菌WB600中进行表达。在19个突变体中,共有15个突变体可以表达并进行制备,其中几乎所有突变体的粗酶液蛋白含量相较野生型TrSOX都有所降低,只有R54D提高约2.5倍。所有突变体都保持了优异的热稳定性,除R54Q、R54N、R54K、R54D和R54V外,其他大多数突变体的二级结构组成均受到一定影响。突变体对底物的手性特异性与野生型TrSOX相同,能特异性识别N-甲基-L-氨基酸类底物,并能将甲基脱除。R54D和R54K对N-甲基-L-氨基酸类底物的催化效率显著提高,而其他突变体的催化效率降低甚至完全失活。此外,包括R54P、R54K和R54I在内的一些突变体能够识别新的非氨基酸相关底物,如1,2,3,4-四氢异喹啉、1-甲基-1,2,3,4-四氢异喹啉、己内酰胺、2-甲基哌啶、哌啶和(3S)-(+)-3-(甲氨基)吡咯烷等,拓展了TrSOX的底物适应性。 展开更多
关键词 嗜热玫瑰红球菌肌氨酸氧化 定点饱和突变 N-甲基脱除 酶学性质 保守位点
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食品中二氧化硫含量的测定方法
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作者 孙正宏 晁丽 强音 《中外食品工业(下)》 2013年第8期25-26,共2页
随着人们生活水平的提升,人们对于食品安全的关注度也在逐渐增高。其中,关于食品中二氧化硫含量也逐渐引起了人们的重视。测定食品中二氧化硫的残留量,保护消费者的利益成为食品检测中的一项重要工作。
关键词 食品二氧化硫含量测定方法盐酸副玫瑰苯胺比色法蒸馏法
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Isolation of Red Rose Anthocyanin Pigment and Its Application to Inhibit Lipid Oxidation in Yoghurt 被引量:2
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作者 E. A. Saati B. W. Simon +1 位作者 Yunianta Aulanni'am 《Journal of Agricultural Science and Technology(A)》 2011年第8期1192-1195,共4页
Anthocyanin is a water soluble natural pigmen, which could be extracted from Red Rose. Color is an important factor to determine the quality of foods, so that the pigments isolation must be selected type of solvent fo... Anthocyanin is a water soluble natural pigmen, which could be extracted from Red Rose. Color is an important factor to determine the quality of foods, so that the pigments isolation must be selected type of solvent for extraction process. Besides functioning as dyes, anthocyanins have a role as a good antioxidant, so it can be used to protect the fat content of fermented milk such as yoghurt. This experiment was to find out the effect of different solvent type on extraction pigment (aquadest: sitrat acid/lactic acid/sulfate acid/chloride acid) and to determine the effect of the addition of anthocyanins in protecting the fat content of yogurt on several levels addition. The research result showed that anthocyanin's pigment of red rose from petal flower's could be effective solvent extracted using lactic acid 0.02 M and increased fat stability of yoghurt. The anthocyanin pigment showed with HPLC analysis that pigment resulted TLC analysis at rite time 13.10 (as Cyanidin glucoside) and 22.61 (as Malvidin glucoside). Yoghurt that given anthocyanin pigment has proven that fat content can be maintained its 86.7% (fat content with 2% pigment as such as 0.117% and without pigment 0.087%) after being stored for 6 days at cold and room temperature. 展开更多
关键词 Anthocyanin pigment ISOLATION ROSE yoghurt.
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Rose Essential Oil Extraction from Fresh Petals Using Synergetic Microwave & Ultrasound Energy: Chemical Composition and Antioxidant Activity Assessment 被引量:2
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作者 Mariana Patrascu Marilena Radoiu 《Journal of Chemistry and Chemical Engineering》 2016年第3期136-142,共7页
The aim of the present work was to investigate the synergetic effect of microwave and ultrasound treatment on the production, chemical composition and antioxidant activity of rose essential oil. The rose essential oil... The aim of the present work was to investigate the synergetic effect of microwave and ultrasound treatment on the production, chemical composition and antioxidant activity of rose essential oil. The rose essential oil was extracted from fresh Rosa x damciscena Mill. petals by four methods, hydrodistillation, steam distillation, organic solvent extraction and ultrasounds followed by microwave hydrodistillation. The chemical composition of the extracts was analysed by GC-MS, and the antioxidant capacity by DPPH. It was found that both chemical composition and the antioxidant activity of the extracts depend on the extraction method. Overall it was found that microwaves coupled with ultrasonic treatment can be used effectively for the intensification of the extraction of monoterpenes and sesquiterpenes--fragrance bearing molecules--and equally, for increased antioxidant activity while using about 4 time shorter extraction time. The scale-up of the method was also evaluated. The results obtained in this research support the possible use of the US/MW method for the extraction of rose essential oil for the pharmaceutical and fragrance industry. 展开更多
关键词 2.45 GHz microwaves ULTRASOUNDS rose petals essential oil scale-up hydrodistillation.
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