The tribological behavior of a Zr-based bulk metallic glass（BMG） was investigated using pin-on-disk sliding measurements in two different environments,i.e.,air and argon,against an yttria-stabilized zirconia counter...The tribological behavior of a Zr-based bulk metallic glass（BMG） was investigated using pin-on-disk sliding measurements in two different environments,i.e.,air and argon,against an yttria-stabilized zirconia counterface.It was found that the wear of the Zr-based BMG was reduced by more than 45% due to the removal of oxygen from the test environment at two different loads,i.e.,16 N and 23 N.The wear pins were examined using X-ray diffractometry,differential scanning calorimetry,scanning electron microscopy and optical surface profilometry.A number of abrasive particles and grooves presented on the worn surface of the pin tested in air,while a relatively smooth worn surface was observed in the specimens tested in argon.The wear mechanism of the pin worn in air was dominated by abrasive wear compared with an adhesive wear controlled process in the tests performed in argon.展开更多
Dry wear tests under atmospheric conditions at 25-200 °C and loads of 12.5-300 N were performed for AM60B alloy. The wear rate increases with increasing the load; the mild-to-severe wear transitions occur under t...Dry wear tests under atmospheric conditions at 25-200 °C and loads of 12.5-300 N were performed for AM60B alloy. The wear rate increases with increasing the load; the mild-to-severe wear transitions occur under the loads of 275 N at 25 °C, 150 N at 100 °C and 75 N at 200 °C, respectively. However, as the load is less than 50 N, the wear rate at 200 °C is lower than that at 25 °C or 100 °C. In mild wear regimes, the wear mechanisms can be classified into abrasive wear, oxidation wear and delamination wear. Delamination wear prevailed as the mild-to-severe wear transition starts to occur; the delamination occurs from the inside of matrix. Subsequently, plastic-extrusion wear as severe wear prevails accompanied with the transition. The thick and hard tribo-layer postpones the mild-to-severe wear transition due to restricting the occurrence of massive plastic deformation of worn surfaces.展开更多
ZnO varistor ceramics doped with Bi2O3, Sb2O3, CO2O3, Cr2O3, and MnO2 were prepared separately by two high-energy ball milling processes： oxide-doped and varistor ceramic powder. A comparison in the electrical and mi...ZnO varistor ceramics doped with Bi2O3, Sb2O3, CO2O3, Cr2O3, and MnO2 were prepared separately by two high-energy ball milling processes： oxide-doped and varistor ceramic powder. A comparison in the electrical and microstructural properties of the samples obtained by both methods was made. The best results on these characteristics were achieved through the high-energy ball milling varistor ceramic powder route, obtaining a nonlinear coefficient of 57 and a breakdown field of 617 V/mm at a sintering temperature of 1000 ℃ for 3 h. The samples synthesized by this technique show not only high density value, 95% of the theoretical density, but also a homogeneous microstructure, which compete with those obtained by the high-energy ball milling oxide-doped powder route. With the advantage that the high-energy ball milling varistor ceramic powder route can refine grain, increase the driving force of sintering, accelerate the sintering process, and reduce the sintering temperature.展开更多
The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and ...The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and X-ray photoelectron spectroscopy.The results show that the friction logs are mixed fretting regime and gross slip regime with the magnitudes of displacement of 10 and 20 μm,respectively.Severe wear and friction oxidation occur on the material surface.A large number of granular debris produced in the fretting process can be easily congregated and adhered at the contact zone after repeated crushes.The resultant of friction oxidation is mainly composed of Fe3O4,Fe2O3,Cr2O3 and NiO.Temperature and friction are the major factors affecting the oxidation reaction rate.The fretting friction effect can enhance the oxidation reaction activity of surface atoms of 0Cr20Ni32AlTi alloy and reduce the oxidation activation energy.As result,the oxidation reaction rate is accelerated.展开更多
Magnetite concentrate was recovered from ferrous sulphate by co-precipitation and magnetic separation. In co-precipitation process, the effects of reaction conditions on iron recovery were studied, and the optimal rea...Magnetite concentrate was recovered from ferrous sulphate by co-precipitation and magnetic separation. In co-precipitation process, the effects of reaction conditions on iron recovery were studied, and the optimal reaction parameters are proposed as follows： n（CaO）/n（Fe2＋） 1.4：1, reaction temperature 80 ℃, ferrous ion concentration 0.4 mol/L, and the final mole ratio of Fe3＋ to FJ＋ in the reaction solution 1.9-2.1. In magnetic separation process, the effects of milling time and magnetic induction intensity on iron recovery were investigated. Wet milling played an important part in breaking the encapsulated magnetic phases. The results showed that the mixed product was wet-milled for 20 min before magnetic separation, the grade and recovery rate of iron in magnetite concentrate were increased from 51.41% and 84.15% to 62.05% and 85.35%, respectively.展开更多
In order to solve the problems of environment pollution and high cost in traditional process of bismuth subcarbonate preparation, a new process using ball-milling transformation method from NH4HCO3 and Bi2O3 was propo...In order to solve the problems of environment pollution and high cost in traditional process of bismuth subcarbonate preparation, a new process using ball-milling transformation method from NH4HCO3 and Bi2O3 was proposed. Additionally, the kinetics of bismuth subcarbonate preparation was studied. Effects of reaction temperature, particle size of bismuth oxide, solid-to-liquid ratio and concentrations of ammonium bicarbonate on the conversion rate of bismuth oxide were studied. The results indicate that the conversion rate of bismuth oxide significantly increased under the conditions of higher temperature, smaller particle size, higher concentration of ammonium bicarbonate and smaller solid-to-liquid ratio. The XRD and ICP-AES analyses show that the purity of product is high. The reaction kinetics with activation energy of 9.783 kJ/mol was analyzed by shrinking core model, and the whole transformation process is controlled by solid product layer diffusion. A semi-empirical kinetics equation was obtained to describe the conversion process.展开更多
Plasma electrolytic oxidation of a cast A356 aluminum alloy was carried out in aluminate electrolytes to develop wear and corrosion resistant coatings. Different concentrations of 2, 16 and 24 g/L NaAlO2 solutions and...Plasma electrolytic oxidation of a cast A356 aluminum alloy was carried out in aluminate electrolytes to develop wear and corrosion resistant coatings. Different concentrations of 2, 16 and 24 g/L NaAlO2 solutions and a silicate electrolyte （for comparison） were employed for the investigation. Wear performance and corrosion resistance of the coatings were evaluated by WC （tungsten carbide） ball-on-flat dry sliding tests and electrochemical methods, respectively. The results show that the coating formed for a short duration of 480 s in 24 g/L NaAlO2 solution generated the best protection. The coating sustained 30 N load for sliding time of 1800 s, showing very low wear rate of -4.5×10^-7 mm3/（N· m）. A low corrosion current density of -8.81×10^-9 A/cm2 was also recorded. Despite low α-Al2O3 content of the coating, the compact and nearly single layer nature of the coating guaranteed the excellent performances.展开更多
Plasma electrolytic oxidation(PEO)coatings developed under voltage-controlled mode on various commercial wrought,gravity cast and rheocast aluminium alloys were discussed with respect to enhancement of their tribologi...Plasma electrolytic oxidation(PEO)coatings developed under voltage-controlled mode on various commercial wrought,gravity cast and rheocast aluminium alloys were discussed with respect to enhancement of their tribological and corrosionperformance and minimization of the PEO energy consumption.It is demonstrated that use of conventional porous anodic filmprecursors reduces the PEO energy consumption by up to50%.The wear of6082alloy with PEO coatings with addedα-Al2O3particles is two times lower compared with electrolytic hard chrome.The long-term corrosion resistance of the PEO-coatedA356rheocast alloy is enhanced via use of a precursor and hydrophobic post-treatment.展开更多
基金Project(DE-FG02-07ER46392) supported by U.S.Department of Energy,Office of Basic Energy ScienceProject(2011JQ002) supported by the Fundamental Research Funds for the Central Universities,ChinaProject supported by the Open-End Fund for the Valuable and Precision Instruments of Central South University,China
文摘The tribological behavior of a Zr-based bulk metallic glass（BMG） was investigated using pin-on-disk sliding measurements in two different environments,i.e.,air and argon,against an yttria-stabilized zirconia counterface.It was found that the wear of the Zr-based BMG was reduced by more than 45% due to the removal of oxygen from the test environment at two different loads,i.e.,16 N and 23 N.The wear pins were examined using X-ray diffractometry,differential scanning calorimetry,scanning electron microscopy and optical surface profilometry.A number of abrasive particles and grooves presented on the worn surface of the pin tested in air,while a relatively smooth worn surface was observed in the specimens tested in argon.The wear mechanism of the pin worn in air was dominated by abrasive wear compared with an adhesive wear controlled process in the tests performed in argon.
基金Project (51071078) supported by the National Natural Science Foundation of ChinaProject (AE201035) supported by the Research Fund of Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, China
文摘Dry wear tests under atmospheric conditions at 25-200 °C and loads of 12.5-300 N were performed for AM60B alloy. The wear rate increases with increasing the load; the mild-to-severe wear transitions occur under the loads of 275 N at 25 °C, 150 N at 100 °C and 75 N at 200 °C, respectively. However, as the load is less than 50 N, the wear rate at 200 °C is lower than that at 25 °C or 100 °C. In mild wear regimes, the wear mechanisms can be classified into abrasive wear, oxidation wear and delamination wear. Delamination wear prevailed as the mild-to-severe wear transition starts to occur; the delamination occurs from the inside of matrix. Subsequently, plastic-extrusion wear as severe wear prevails accompanied with the transition. The thick and hard tribo-layer postpones the mild-to-severe wear transition due to restricting the occurrence of massive plastic deformation of worn surfaces.
基金Project (BK2011243) supported by the Natural Science Foundation of Jiangsu Province,ChinaProject (EIPE11204) supported by the State Key Laboratory of Electrical Insulation and Power Equipment,China+4 种基金Project (KF201104) supported by the State Key Laboratory of New Ceramic and Fine Processing,ChinaProject (KFJJ201105) supported by the Opening Project of State Key Laboratory of Electronic Thin Films and Integrated Devices,ChinaProject (2011-22) supported by State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,ChinaProject (10KJD430002) supported by the Universities Natural Science Research Project of Jiangsu Province,ChinaProject (11JDG084) supported by the Research Foundation of Jiangsu University,China
文摘ZnO varistor ceramics doped with Bi2O3, Sb2O3, CO2O3, Cr2O3, and MnO2 were prepared separately by two high-energy ball milling processes： oxide-doped and varistor ceramic powder. A comparison in the electrical and microstructural properties of the samples obtained by both methods was made. The best results on these characteristics were achieved through the high-energy ball milling varistor ceramic powder route, obtaining a nonlinear coefficient of 57 and a breakdown field of 617 V/mm at a sintering temperature of 1000 ℃ for 3 h. The samples synthesized by this technique show not only high density value, 95% of the theoretical density, but also a homogeneous microstructure, which compete with those obtained by the high-energy ball milling oxide-doped powder route. With the advantage that the high-energy ball milling varistor ceramic powder route can refine grain, increase the driving force of sintering, accelerate the sintering process, and reduce the sintering temperature.
基金Project (51075342) supported by the National Natural Science Foundation of ChinaProject (2007CB714704) supported by the National Basic Research Program of China
文摘The fretting wear behavior of 0Cr20Ni32AlTi alloy was investigated with crossed cylinder contact under 80 N at 300 and 400 °C.Wear scar and debris were analyzed systematically by scanning electron microscopy and X-ray photoelectron spectroscopy.The results show that the friction logs are mixed fretting regime and gross slip regime with the magnitudes of displacement of 10 and 20 μm,respectively.Severe wear and friction oxidation occur on the material surface.A large number of granular debris produced in the fretting process can be easily congregated and adhered at the contact zone after repeated crushes.The resultant of friction oxidation is mainly composed of Fe3O4,Fe2O3,Cr2O3 and NiO.Temperature and friction are the major factors affecting the oxidation reaction rate.The fretting friction effect can enhance the oxidation reaction activity of surface atoms of 0Cr20Ni32AlTi alloy and reduce the oxidation activation energy.As result,the oxidation reaction rate is accelerated.
基金Project(2013A090100013)supported by the Special Project on the Integration of Industry,Education and Research of Guangdong Province,ChinaProject(201407300993)supported by the High Technology Research and Development Program of Xinjiang Uygur Autonomous Region,China
文摘Magnetite concentrate was recovered from ferrous sulphate by co-precipitation and magnetic separation. In co-precipitation process, the effects of reaction conditions on iron recovery were studied, and the optimal reaction parameters are proposed as follows： n（CaO）/n（Fe2＋） 1.4：1, reaction temperature 80 ℃, ferrous ion concentration 0.4 mol/L, and the final mole ratio of Fe3＋ to FJ＋ in the reaction solution 1.9-2.1. In magnetic separation process, the effects of milling time and magnetic induction intensity on iron recovery were investigated. Wet milling played an important part in breaking the encapsulated magnetic phases. The results showed that the mixed product was wet-milled for 20 min before magnetic separation, the grade and recovery rate of iron in magnetite concentrate were increased from 51.41% and 84.15% to 62.05% and 85.35%, respectively.
基金Project(50774099)supported by the National Natural Science Foundation of China
文摘In order to solve the problems of environment pollution and high cost in traditional process of bismuth subcarbonate preparation, a new process using ball-milling transformation method from NH4HCO3 and Bi2O3 was proposed. Additionally, the kinetics of bismuth subcarbonate preparation was studied. Effects of reaction temperature, particle size of bismuth oxide, solid-to-liquid ratio and concentrations of ammonium bicarbonate on the conversion rate of bismuth oxide were studied. The results indicate that the conversion rate of bismuth oxide significantly increased under the conditions of higher temperature, smaller particle size, higher concentration of ammonium bicarbonate and smaller solid-to-liquid ratio. The XRD and ICP-AES analyses show that the purity of product is high. The reaction kinetics with activation energy of 9.783 kJ/mol was analyzed by shrinking core model, and the whole transformation process is controlled by solid product layer diffusion. A semi-empirical kinetics equation was obtained to describe the conversion process.
基金Projects(51071066,51671084)supported by the National Natural Science Foundation of ChinaProject(NCET-12-0172)supported by the Program for New Century Excellent Talents in University,Ministry of Education,China
文摘Plasma electrolytic oxidation of a cast A356 aluminum alloy was carried out in aluminate electrolytes to develop wear and corrosion resistant coatings. Different concentrations of 2, 16 and 24 g/L NaAlO2 solutions and a silicate electrolyte （for comparison） were employed for the investigation. Wear performance and corrosion resistance of the coatings were evaluated by WC （tungsten carbide） ball-on-flat dry sliding tests and electrochemical methods, respectively. The results show that the coating formed for a short duration of 480 s in 24 g/L NaAlO2 solution generated the best protection. The coating sustained 30 N load for sliding time of 1800 s, showing very low wear rate of -4.5×10^-7 mm3/（N· m）. A low corrosion current density of -8.81×10^-9 A/cm2 was also recorded. Despite low α-Al2O3 content of the coating, the compact and nearly single layer nature of the coating guaranteed the excellent performances.
基金supported by Regional Government of Madrid and EU Structural Funds via Multimat Challenge Programme(S2013/MIT-2862-CM)Proyecto Retos Jovenes Investigadores Programme(MAT2015-73355-JIN)funded by MINECO,Spain
文摘Plasma electrolytic oxidation(PEO)coatings developed under voltage-controlled mode on various commercial wrought,gravity cast and rheocast aluminium alloys were discussed with respect to enhancement of their tribological and corrosionperformance and minimization of the PEO energy consumption.It is demonstrated that use of conventional porous anodic filmprecursors reduces the PEO energy consumption by up to50%.The wear of6082alloy with PEO coatings with addedα-Al2O3particles is two times lower compared with electrolytic hard chrome.The long-term corrosion resistance of the PEO-coatedA356rheocast alloy is enhanced via use of a precursor and hydrophobic post-treatment.
