Islet transplantation as a promising treatment for type 1 diabetes has received widespread attention. Oxidative stress plays an essential role in cell injury during islet isolation and transplantation procedures. Anti...Islet transplantation as a promising treatment for type 1 diabetes has received widespread attention. Oxidative stress plays an essential role in cell injury during islet isolation and transplantation procedures. Antioxidants have been used in various studies to improve islet transplantation procedures. The present study reviews the role of oxidative stress and the benefits of antioxidants in islet transplantation procedures. The bibliographical databases Pubmed and Scopus were searched up to November 2008. All relevant human and animal in-vivo and in-vitro studies, which investigated antioxidants on islets, were included. Almost all the tested antioxidants used in the in-vitro studies enhanced islet viability and insulin secretion. Better control of blood glucose after transplantation was the major outcome of antioxidant therapy in all in-vivo studies. The data also indicated that antioxidants improved islet transplantation procedures. Although there is still insuffi cient evidence to draw definitive conclusions about the efficacy of individual supplements, the benefi ts of antioxidants in islet isolation procedures cannot be ignored.展开更多
We systematically reviewed the clinical trials which recruited antioxidants in the therapy of pancreatitis and evaluated whether antioxidants improve the outcome of patients with pancreatitis. Electronic bibliographic...We systematically reviewed the clinical trials which recruited antioxidants in the therapy of pancreatitis and evaluated whether antioxidants improve the outcome of patients with pancreatitis. Electronic bibliographic databases were searched for any studies which investigated the use of antioxidants in the management of acute pancreatitis (AP) or chronic pancreatitis (CP) and in the prevention of post-endoscopic retrograde cholangio-pancreatography (post-ERCP) pancreatitis (PEP) up to February 2009. Twenty-two randomized, placebo-controlled, clinical trials met our criteria and were included in the review. Except for a cocktail of antioxidants which showed improvement in outcomes in three different clinical trials, the results of the administration of other antioxidants in both AP and CP clinical trials were incongruent and heterogeneous.Furthermore, antioxidant therapy including allopurinol and N-acetylcysteine failed to prevent the onset of PEP in almost all trials. In conclusion, the present data do not support a benefit of antioxidant therapy alone or in combination with conventional therapy in the management of AP, CP or PER Further double blind, randomized, placebo-controlled clinical trials with large sample size need to be conducted.展开更多
AIM: To test whether antioxidant treatment could prevent the progression of Barrett's esophagus to adenocarcinoma. METHODS: In a rat model of gastroduodenoesophageal reflux by esophagojejunal anastomosis with gastr...AIM: To test whether antioxidant treatment could prevent the progression of Barrett's esophagus to adenocarcinoma. METHODS: In a rat model of gastroduodenoesophageal reflux by esophagojejunal anastomosis with gastric preservation, groups of 6-10 rats were randomized to receive treatment with superoxide dismutase (SOD) or vehicle and followed up for 4 too. Rat's esophagus was assessed by histological analysis, superoxide anion and peroxinitrite generation, SOD levels and DNA oxidative damage. RESULTS: All rats undergoing esophagojejunostomy developed extensive esophageal mucosal ulceration and inflammation by mo 4. The process was associated with a progressive presence of intestinal metaplasia beyond the anastomotic area (9% 1st mo and 50% 4th too) (94% at the anastomotic level) and adenocarcinoma (11% 1^ST mo and 60% 4th too). These changes were associated with superoxide anion and peroxinitrite mucosal generation, an early and significant increase of DNA oxidative damage and a significant decrease in SOD levels (P〈0.05). Exogenous administration of SOD decreased mucosal superoxide levels, increased mucosal SOD levels and reduced the risk of developing intestinal metaplasia beyond the anastomotic area (odds ratio = 0.326; 95%CI: 0.108-0.981; P = 0.046), and esophageal adenocarcinoma (odds ratio = 0.243; 95%CI: 0.073-0.804; P = 0.021). CONCLUSION: Superoxide dismutase prevents the progression of esophagitis to Barrett's esophagus and adenocarcinoma in this rat model of gastrointestinal reflux, supporting a role of antioxidants in the chemoprevention of esophageal adenocarcinoma.展开更多
Most lowlands in Northeast Thailand(Isaan region)are cultivated with rice and large areas are affected by salinity, which drastically limits rice production.A field experiment was conducted during the 2003 rainy seaso...Most lowlands in Northeast Thailand(Isaan region)are cultivated with rice and large areas are affected by salinity, which drastically limits rice production.A field experiment was conducted during the 2003 rainy season to explore the interactions between salinity and land management in two fields representative of two farming practices:an intensively managed plot with organic inputs and efficient water management,and one without organic matter addition.Field measurements,including pH,Eh,electrical conductivity(EC),and soil solution chemistry,were performed at three depths, with a particular focus on Fe dynamics,inside and outside saline patches. High reducing conditions appeared after flooding particularly in plots receiving organic matter and reduction processes leading to oxide reduction and to the release of Fe and,to a lesser extend,Mn to the soil solution.Oxide reduction led to the consumption of H^+ and the more the Fe reduction was,the higher the pH was,up to 6.5.Formation of hydroxy-green rust were likely to be at the origin of the pH stabilization.In the absence of organic amendments,high salinity prevented the establishment of the reduction processes and pH value remained around 4.Even under high reduction conditions,the Fe concentrations in the soil solution were below commonly observed toxic values and the amended plot had better rice production yield.展开更多
Hydrogen peroxide(H2O2)is a very useful chemical reagent,but the current industrial methods for its production suffer from serious energy consumption problems.Using high-activity and high-selectivity catalysts to elec...Hydrogen peroxide(H2O2)is a very useful chemical reagent,but the current industrial methods for its production suffer from serious energy consumption problems.Using high-activity and high-selectivity catalysts to electrocatalyze the oxygen reduction reaction(ORR)through a two-electron(2e^-)pathway is a very promising route to produce H2O2.In this work,we obtained partially oxidized multi-walled carbon nanotubes(MWCNTs)with controlled structure and composition by oxidation with concentrated sulfate and potassium permanganate at 40℃ for 1 h(O-CNTs-40-1).The outer layers of O-CNTs-40-1 are damaged with defects and oxygen-containing functional groups,while the inner layers are maintained intact.The optimized structure and composition of the partially oxidized MWCNTs ensure that O-CNTs-40-1 possesses both a sufficient number of catalytic sites and good conductivity.The results of rotating ring disk electrode measurements reveal that,among all oxidized MWCNTs,O-CNTs-40-1 shows the greatest improvement in hydrogen peroxide selectivity(from ~ 30% to ~ 50%)and electron transfer number(from ~ 3.4 to ~ 3.0)compared to those of the raw MWCNTs.The results of electrochemical impedance spectroscopy measurements indicate that both the charge-transfer and intrinsic resistances of O-CNTs-40-1 are lower than those of the raw MWCNTs and of the other oxidized MWCNTs.Finally,direct tests of the H2O2 production confirm the greatly improved catalytic activity of O-CNTs-40-1 relative to that of the raw MWCNTs.展开更多
Co-integration theory has been employed in this paper and Granger causes are found between urbanization rate and GDP, between capital stock and GDP. Scenario analysis of GDP is performed using the GDP model establishe...Co-integration theory has been employed in this paper and Granger causes are found between urbanization rate and GDP, between capital stock and GDP. Scenario analysis of GDP is performed using the GDP model established in the paper. The energy consumptions in Germany, Japan and other developed countries are analyzed and compared with the energy consumption in China. Environmental friendly scenario of energy demand and CO2 emissions for sustainable China has been formed based on the results of comparison. Under environmental friendly scenario, the primary energy consumption will be 4.31 billion ton coal equivalence (tee) and CO2 emissions will be 1.854 billion t-c in 2050; energy per capital will be 3.06 tee that is 1.8 times of energy consumed in 2005 in China and 51% of consumed energy per capital in Japan in 2003. In 2050, the energy requirement of unit GDP will be 20% lower than that of Germany in 2003, but will be still 37% higher than that in Japan in 2003. It is certain that to fulfill the environmental friendly Scenario of energy demand and CO2 emissions is a difficult task and it needs long term efforts of the whole society, not only in production sectors but also in service and household sectors,展开更多
Vanadium oxide (VOx) nanostructures, synthesized by hydrothermal treatment using dodecylamine as template, were evaluated for the selective catalytic reduction of NOx with ammonia (NH3-SCR), The effect of solvent ...Vanadium oxide (VOx) nanostructures, synthesized by hydrothermal treatment using dodecylamine as template, were evaluated for the selective catalytic reduction of NOx with ammonia (NH3-SCR), The effect of solvent type in the reaction mixture (EtOH/(EtOH + H20)) and time of hydrolysis was studied. The obtained materials were characterized by XRD, SEM, TEM and BET, The VOx nanorods (80-120 nm diameter and 1-4 μm length) were synthesized in 25 vol% EtOH/(EtOH + H20) and the open-ended multiwalled VOx nanotube (50-100 nm inner diameter, 110-180 nm outer diameter and 0,5-2 pm length) synthesized in 50 vol% EtOH/(EtOH + H20). VOx nanotuhes performed the superior NH3-SCR activity under a gas hourly space velocity of 12,000 h-1 at low temperature of 250 ~C (NOx conversion of 893g & N2 selectivity of 100%), while most of the developed Vanadia base catalysts are active at high temperature (〉350 ℃). The superior NH3-SCR activity ofVOx nanotubes at low tem- perature is related to nanocrystalline structure, special nanotube morphology as well as high specific surface area.展开更多
The Inohana Lake is a branch lake of the Hamana Lake. The Inohana Lake is an estuary rather than a brackish lake, and has suffered environmental problems such as eutrophication and bottom hypoxic water. In this study,...The Inohana Lake is a branch lake of the Hamana Lake. The Inohana Lake is an estuary rather than a brackish lake, and has suffered environmental problems such as eutrophication and bottom hypoxic water. In this study, the coupled hydrodynamic and ecological models (eco-hydrodynamic model) were used to construct the strategy for preventing the bottom hypoxic water and improving or recovering the water quality in the lake. Using the model input obtained from the summertime data over 1998-2002, the summer-average flow field and oxygen concentration and budget of the standard run were calculated. Remedial measures used in this study are divided into two parts: the biogeochemical and physical changes in the present situation. For the remedial measures including the biogeochemical changes in the present situation, the simulations considering the reductions of the nutrient inputs from the river, main lake (land) and bottom sediment, and the sediment oxygen demand (SOD) were carried out. For the remedial measures including the physical changes, the 50 and 100 m extensions of the inlet width were considered in the model runs. These simulated results were compared in terms of changes in the dissolved oxygen (DO) concentration and oxygen budget in the bottom layer in the Inohana Lake. There was no significant change in the DO concentration and oxygen stock in the simulations for the reduction of the nutrient inputs from the land and bottom sediment, however increases in those in the simulations for the reduction of SOD. When SOD was reduced by 50%, the bottom DO concentration increased by approximately 2 mg/L and the oxygen stock in the bottom layer increased by 47% comparing the present situation (the standard run) of the lake. The simulation results for inlet width extension showed that the extension of width makes the DO concentration and oxygen stock lower. The remedial measures for the sediment control were proposed to prevent the bottom hypoxia and manage the water quality.展开更多
Wastewater treatment plants (WWTPs) can represent risks source for human health and environment, due to the use of chemicals and substances produced by the treatment process. In particular, considering a conventiona...Wastewater treatment plants (WWTPs) can represent risks source for human health and environment, due to the use of chemicals and substances produced by the treatment process. In particular, considering a conventional urban wastewater treatment plant, two case studies have been considered in this paper: the phase of disinfection with Peracetic Acid (PAA), used as reactant and the sludge anaerobic digestion, generating biogas. The aim of the experience is to find out some management suggestions that could make safer these sections of a WWTP.展开更多
Pool boiling of saturated water on a plain Ti surface and surfaces covered with vertically-oriented TiO2 nanotube arrays(NTAs) has been studied.The technique of potentiostatic anodization using non-aqueous electrolyte...Pool boiling of saturated water on a plain Ti surface and surfaces covered with vertically-oriented TiO2 nanotube arrays(NTAs) has been studied.The technique of potentiostatic anodization using non-aqueous electrolytes was adopted to fabricate three types of TiO2 NTAs distinguished by their anodization time.Compared to the bare Ti surface,the incipient boiling wall superheat on the TiO2 NTAs was decreased by 11 K.Both the critical heat flux and heat transfer coefficient of pool boiling on the TiO2 NTAs were higher than those from boiling on a bare Ti surface.The measured maximum critical heat flux and heat transfer coefficient values were 186.7 W/cm2 and 6.22 W/cm2K,respectively.Different performances for the enhancement of heat transfer by the three types of TiO2 NTAs were attributed to the different degrees of deformation in the nanostructure during boiling.Long-term performance of the nanomaterial-coated surfaces for enhanced pool boiling showed degradation of the TiO2 NTAs prepared with an anodization time of 3 hours.展开更多
A detailed three-dimensional mechanistic model of a large-scale solid oxide fuel cell(SOFC) unit running on partially pre-reformed methane is developed. The model considers the coupling effects of chemical and electro...A detailed three-dimensional mechanistic model of a large-scale solid oxide fuel cell(SOFC) unit running on partially pre-reformed methane is developed. The model considers the coupling effects of chemical and electrochemical reactions, mass transport, momentum and heat transfer in the SOFC unit. After model validation, parametric simulations are conducted to investigate how the methane pre-reforming ratio affects the transport and electrochemistry of the SOFC unit. It is found that the methane steam reforming reaction has a "smoothing effect", which can achieve more uniform distributions of gas compositions, current density and temperature among the cell plane. In the case of 1500 W/m^2 power density output, adding 20% methane absorbs 50% of internal heat production inside the cell, reduces the maximum temperature difference inside the cell from 70 K to 22 K and reduces the cathode air supply by 75%, compared to the condition of completely pre-reforming of methane. Under specific operating conditions, the pre-reforming ratio of methane has an optimal range for obtaining a good temperature distribution and good cell performance.展开更多
Well crystallized niobium-doped TiO; nanotube arrays (TiNbO-NT) were successfully synthesized via the anodization of titanium/niobium alloy sheets, followed with a heat treatment at 550 ℃ for 2 h. Morphology analys...Well crystallized niobium-doped TiO; nanotube arrays (TiNbO-NT) were successfully synthesized via the anodization of titanium/niobium alloy sheets, followed with a heat treatment at 550 ℃ for 2 h. Morphology analysis results demonstrated that both the titanium/niobium alloy microstructure and the dissolution strength of electrolyte played major roles in the formation of nanotube structure. A single-phase microstructure was more favorable to the formation of uniform nanotube arrays, while modulating the dissolution strength of electrolyte was required to obtain nanotube arrays from the alloys with multi-phase microstructures. X-ray diffraction (XRD) and X-ray photoelectron (XPS) analysis results clearly demonstrated that niobium dopants (Nb^5+) were successfully doped into TiO2 anatase lattice by substituting Ti^4+ in this approach.展开更多
At elevated temperature regimes and abundant precipitation, mobilization and accretion of weathered iron oxides are promoted especially in a reduced environments in the tropics. This may lead to the formation of plint...At elevated temperature regimes and abundant precipitation, mobilization and accretion of weathered iron oxides are promoted especially in a reduced environments in the tropics. This may lead to the formation of plinthite, which hardens irreversibly upon repeated wetting and drying to form petroplinthite. The need for this review stems from the seemingly dearth of information on the subject and a need to clarify different terms used in describing plinthite. We review various research works on plinthite and its associated pedogenic forms in the tropics. Furthermore, we proffer recommendations as to the most appropriate land use management practices that could help minimise the environmental and agronomic problems associated with plinthite and its related pedogenic forms. Parent material, temperature, seasonality and geomorphology are critical factors that influence soil water regime which in turn affect the pedogenesis of plinthite. Soil pH and mineralogy are additional factors that could also promote plinthite formation. Fossil plinthic soils are potential proxies for palaeoenvironmental reconstruction. Measures used in the management of plinthic soils include mechanically breaking the hardpans and the use of organic and inorganic amendments to modify the structure and chemistry of the soils. Avoidance of practices that would predispose soils to erosion would also prevent plinthization. We call for the relinquishment of the term "[aterite" which is a generM term for all forms of iron oxide-enriched earthy materials as used for plinthite. Plinthic horizon should also be incorporated into the United States Department of Agriculture Soil Taxonomy in view of its growing importance in soils.展开更多
Editor's comments Formaldehyde (HCHO) emitted from chemical manufacturing plants including methanol-gasoline/diesel fuel vehicles and the construction and decoration materials is one of the major air pollutions, wh...Editor's comments Formaldehyde (HCHO) emitted from chemical manufacturing plants including methanol-gasoline/diesel fuel vehicles and the construction and decoration materials is one of the major air pollutions, which induces photochemical pollution and hazards human health. Great efforts have been made for the reduction or control of the emission of HCHO to satisfy the stringent environmental regulations. Now, a new study supported by the National Natural Science Foundation of China reports mesoporous manganese oxide with novel nanostructures for the decomposition of HCHO. The obtained manganese oxide nanomaterials showed high catalytic activities for oxidative decomposition of HCHO at low temperatures. Complete conversion of HCHO to CO2 and H2O were achieved, and no harmful by- products were detected in effluent gases. The catalytic activities of these nanomaterials are significantly higher than those of previously reported manganese oxide octahedral molecular sieve (OMS-2) nanorods , MnO x powders, and alumnina-supported mangnaese-palladium oxide catalysts. These results provide a new route for the removal of HCHO and other air pollutions.展开更多
The full solution-processed oxide thin-film-transistors(TFTs) have the advantages of transparency, ease of large-area fabrication, and low cost, offering great potential applications in switching and driving fields, a...The full solution-processed oxide thin-film-transistors(TFTs) have the advantages of transparency, ease of large-area fabrication, and low cost, offering great potential applications in switching and driving fields, and attracting extensive research interest. However, the performance of the solution-processed TFTs is generally lower than that of the vacuum-deposited ones. In this article, the full-solution processed TFTs with zinc-tin-oxide(ZTO) semiconductor and aluminium(Al_2O_3) dielectrics were fabricated, and their mobilities in the saturation region are high. Besides, the effect of the Al_2O_3 dielectrics' preparation technology on ZTO TFTs' performance was studied. Comparing the ZTO TFTs using the spin-coated Al_2O_3 dielectrics of 1–4 layers, the ZTO TFT with 3-layer Al_2O_3 dielectrics achieved the optimal performance as its field-effect carrier mobility in the saturation region is 112 cm^2/V s, its threshold voltage is 2.4 V, and its on-to-off current ratio is 2.8×105. This is also the highest reported carrier mobility of the solution-processed ZTO TFTs.展开更多
文摘Islet transplantation as a promising treatment for type 1 diabetes has received widespread attention. Oxidative stress plays an essential role in cell injury during islet isolation and transplantation procedures. Antioxidants have been used in various studies to improve islet transplantation procedures. The present study reviews the role of oxidative stress and the benefits of antioxidants in islet transplantation procedures. The bibliographical databases Pubmed and Scopus were searched up to November 2008. All relevant human and animal in-vivo and in-vitro studies, which investigated antioxidants on islets, were included. Almost all the tested antioxidants used in the in-vitro studies enhanced islet viability and insulin secretion. Better control of blood glucose after transplantation was the major outcome of antioxidant therapy in all in-vivo studies. The data also indicated that antioxidants improved islet transplantation procedures. Although there is still insuffi cient evidence to draw definitive conclusions about the efficacy of individual supplements, the benefi ts of antioxidants in islet isolation procedures cannot be ignored.
文摘We systematically reviewed the clinical trials which recruited antioxidants in the therapy of pancreatitis and evaluated whether antioxidants improve the outcome of patients with pancreatitis. Electronic bibliographic databases were searched for any studies which investigated the use of antioxidants in the management of acute pancreatitis (AP) or chronic pancreatitis (CP) and in the prevention of post-endoscopic retrograde cholangio-pancreatography (post-ERCP) pancreatitis (PEP) up to February 2009. Twenty-two randomized, placebo-controlled, clinical trials met our criteria and were included in the review. Except for a cocktail of antioxidants which showed improvement in outcomes in three different clinical trials, the results of the administration of other antioxidants in both AP and CP clinical trials were incongruent and heterogeneous.Furthermore, antioxidant therapy including allopurinol and N-acetylcysteine failed to prevent the onset of PEP in almost all trials. In conclusion, the present data do not support a benefit of antioxidant therapy alone or in combination with conventional therapy in the management of AP, CP or PER Further double blind, randomized, placebo-controlled clinical trials with large sample size need to be conducted.
基金Supported by grants from CICYT (SAF2000-0123) and Instituto de Salud Carlos Ⅲ (C03/02). Elena Piazuelo is supported by Instituto de Salud Carlos Ⅲ and Instituto Aragones de Ciencias de la Salud
文摘AIM: To test whether antioxidant treatment could prevent the progression of Barrett's esophagus to adenocarcinoma. METHODS: In a rat model of gastroduodenoesophageal reflux by esophagojejunal anastomosis with gastric preservation, groups of 6-10 rats were randomized to receive treatment with superoxide dismutase (SOD) or vehicle and followed up for 4 too. Rat's esophagus was assessed by histological analysis, superoxide anion and peroxinitrite generation, SOD levels and DNA oxidative damage. RESULTS: All rats undergoing esophagojejunostomy developed extensive esophageal mucosal ulceration and inflammation by mo 4. The process was associated with a progressive presence of intestinal metaplasia beyond the anastomotic area (9% 1st mo and 50% 4th too) (94% at the anastomotic level) and adenocarcinoma (11% 1^ST mo and 60% 4th too). These changes were associated with superoxide anion and peroxinitrite mucosal generation, an early and significant increase of DNA oxidative damage and a significant decrease in SOD levels (P〈0.05). Exogenous administration of SOD decreased mucosal superoxide levels, increased mucosal SOD levels and reduced the risk of developing intestinal metaplasia beyond the anastomotic area (odds ratio = 0.326; 95%CI: 0.108-0.981; P = 0.046), and esophageal adenocarcinoma (odds ratio = 0.243; 95%CI: 0.073-0.804; P = 0.021). CONCLUSION: Superoxide dismutase prevents the progression of esophagitis to Barrett's esophagus and adenocarcinoma in this rat model of gastrointestinal reflux, supporting a role of antioxidants in the chemoprevention of esophageal adenocarcinoma.
基金the French Ministry of Research under the ACI-FNS"ECCO-PNBC"project"Evaluation du r~■le des paramètres environnementaux et des activités bactériennes dans la dynamique du fer et du manganèse dans la rhizosphère des plantes:application aux sols de rizières"by the French Embassy in Bangkok.
文摘Most lowlands in Northeast Thailand(Isaan region)are cultivated with rice and large areas are affected by salinity, which drastically limits rice production.A field experiment was conducted during the 2003 rainy season to explore the interactions between salinity and land management in two fields representative of two farming practices:an intensively managed plot with organic inputs and efficient water management,and one without organic matter addition.Field measurements,including pH,Eh,electrical conductivity(EC),and soil solution chemistry,were performed at three depths, with a particular focus on Fe dynamics,inside and outside saline patches. High reducing conditions appeared after flooding particularly in plots receiving organic matter and reduction processes leading to oxide reduction and to the release of Fe and,to a lesser extend,Mn to the soil solution.Oxide reduction led to the consumption of H^+ and the more the Fe reduction was,the higher the pH was,up to 6.5.Formation of hydroxy-green rust were likely to be at the origin of the pH stabilization.In the absence of organic amendments,high salinity prevented the establishment of the reduction processes and pH value remained around 4.Even under high reduction conditions,the Fe concentrations in the soil solution were below commonly observed toxic values and the amended plot had better rice production yield.
基金supported by the National Natural Science Foundation of China(21576299,21576300)Guangzhou Science and Technology Project(201607010104,201707010079)+3 种基金Science and Technology Planning Project of Guangdong Province(2017A050501009)the National Key Research and Development Program of China(2016YFB0101204)Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program(2016TQ03N322)the fundamental Research Funds for Central Universities(17lgzd14)~~
文摘Hydrogen peroxide(H2O2)is a very useful chemical reagent,but the current industrial methods for its production suffer from serious energy consumption problems.Using high-activity and high-selectivity catalysts to electrocatalyze the oxygen reduction reaction(ORR)through a two-electron(2e^-)pathway is a very promising route to produce H2O2.In this work,we obtained partially oxidized multi-walled carbon nanotubes(MWCNTs)with controlled structure and composition by oxidation with concentrated sulfate and potassium permanganate at 40℃ for 1 h(O-CNTs-40-1).The outer layers of O-CNTs-40-1 are damaged with defects and oxygen-containing functional groups,while the inner layers are maintained intact.The optimized structure and composition of the partially oxidized MWCNTs ensure that O-CNTs-40-1 possesses both a sufficient number of catalytic sites and good conductivity.The results of rotating ring disk electrode measurements reveal that,among all oxidized MWCNTs,O-CNTs-40-1 shows the greatest improvement in hydrogen peroxide selectivity(from ~ 30% to ~ 50%)and electron transfer number(from ~ 3.4 to ~ 3.0)compared to those of the raw MWCNTs.The results of electrochemical impedance spectroscopy measurements indicate that both the charge-transfer and intrinsic resistances of O-CNTs-40-1 are lower than those of the raw MWCNTs and of the other oxidized MWCNTs.Finally,direct tests of the H2O2 production confirm the greatly improved catalytic activity of O-CNTs-40-1 relative to that of the raw MWCNTs.
文摘Co-integration theory has been employed in this paper and Granger causes are found between urbanization rate and GDP, between capital stock and GDP. Scenario analysis of GDP is performed using the GDP model established in the paper. The energy consumptions in Germany, Japan and other developed countries are analyzed and compared with the energy consumption in China. Environmental friendly scenario of energy demand and CO2 emissions for sustainable China has been formed based on the results of comparison. Under environmental friendly scenario, the primary energy consumption will be 4.31 billion ton coal equivalence (tee) and CO2 emissions will be 1.854 billion t-c in 2050; energy per capital will be 3.06 tee that is 1.8 times of energy consumed in 2005 in China and 51% of consumed energy per capital in Japan in 2003. In 2050, the energy requirement of unit GDP will be 20% lower than that of Germany in 2003, but will be still 37% higher than that in Japan in 2003. It is certain that to fulfill the environmental friendly Scenario of energy demand and CO2 emissions is a difficult task and it needs long term efforts of the whole society, not only in production sectors but also in service and household sectors,
基金the Iran Nanotechnology Initiative Council for the financial and other supports
文摘Vanadium oxide (VOx) nanostructures, synthesized by hydrothermal treatment using dodecylamine as template, were evaluated for the selective catalytic reduction of NOx with ammonia (NH3-SCR), The effect of solvent type in the reaction mixture (EtOH/(EtOH + H20)) and time of hydrolysis was studied. The obtained materials were characterized by XRD, SEM, TEM and BET, The VOx nanorods (80-120 nm diameter and 1-4 μm length) were synthesized in 25 vol% EtOH/(EtOH + H20) and the open-ended multiwalled VOx nanotube (50-100 nm inner diameter, 110-180 nm outer diameter and 0,5-2 pm length) synthesized in 50 vol% EtOH/(EtOH + H20). VOx nanotuhes performed the superior NH3-SCR activity under a gas hourly space velocity of 12,000 h-1 at low temperature of 250 ~C (NOx conversion of 893g & N2 selectivity of 100%), while most of the developed Vanadia base catalysts are active at high temperature (〉350 ℃). The superior NH3-SCR activity ofVOx nanotubes at low tem- perature is related to nanocrystalline structure, special nanotube morphology as well as high specific surface area.
文摘The Inohana Lake is a branch lake of the Hamana Lake. The Inohana Lake is an estuary rather than a brackish lake, and has suffered environmental problems such as eutrophication and bottom hypoxic water. In this study, the coupled hydrodynamic and ecological models (eco-hydrodynamic model) were used to construct the strategy for preventing the bottom hypoxic water and improving or recovering the water quality in the lake. Using the model input obtained from the summertime data over 1998-2002, the summer-average flow field and oxygen concentration and budget of the standard run were calculated. Remedial measures used in this study are divided into two parts: the biogeochemical and physical changes in the present situation. For the remedial measures including the biogeochemical changes in the present situation, the simulations considering the reductions of the nutrient inputs from the river, main lake (land) and bottom sediment, and the sediment oxygen demand (SOD) were carried out. For the remedial measures including the physical changes, the 50 and 100 m extensions of the inlet width were considered in the model runs. These simulated results were compared in terms of changes in the dissolved oxygen (DO) concentration and oxygen budget in the bottom layer in the Inohana Lake. There was no significant change in the DO concentration and oxygen stock in the simulations for the reduction of the nutrient inputs from the land and bottom sediment, however increases in those in the simulations for the reduction of SOD. When SOD was reduced by 50%, the bottom DO concentration increased by approximately 2 mg/L and the oxygen stock in the bottom layer increased by 47% comparing the present situation (the standard run) of the lake. The simulation results for inlet width extension showed that the extension of width makes the DO concentration and oxygen stock lower. The remedial measures for the sediment control were proposed to prevent the bottom hypoxia and manage the water quality.
文摘Wastewater treatment plants (WWTPs) can represent risks source for human health and environment, due to the use of chemicals and substances produced by the treatment process. In particular, considering a conventional urban wastewater treatment plant, two case studies have been considered in this paper: the phase of disinfection with Peracetic Acid (PAA), used as reactant and the sludge anaerobic digestion, generating biogas. The aim of the experience is to find out some management suggestions that could make safer these sections of a WWTP.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11004054,50825603,U1034004)the Fundamental Research Funds for the Central Universities
文摘Pool boiling of saturated water on a plain Ti surface and surfaces covered with vertically-oriented TiO2 nanotube arrays(NTAs) has been studied.The technique of potentiostatic anodization using non-aqueous electrolytes was adopted to fabricate three types of TiO2 NTAs distinguished by their anodization time.Compared to the bare Ti surface,the incipient boiling wall superheat on the TiO2 NTAs was decreased by 11 K.Both the critical heat flux and heat transfer coefficient of pool boiling on the TiO2 NTAs were higher than those from boiling on a bare Ti surface.The measured maximum critical heat flux and heat transfer coefficient values were 186.7 W/cm2 and 6.22 W/cm2K,respectively.Different performances for the enhancement of heat transfer by the three types of TiO2 NTAs were attributed to the different degrees of deformation in the nanostructure during boiling.Long-term performance of the nanomaterial-coated surfaces for enhanced pool boiling showed degradation of the TiO2 NTAs prepared with an anodization time of 3 hours.
基金financially supported by the National Natural Science Foundation of China(Grant No.51776108,No.51476092)
文摘A detailed three-dimensional mechanistic model of a large-scale solid oxide fuel cell(SOFC) unit running on partially pre-reformed methane is developed. The model considers the coupling effects of chemical and electrochemical reactions, mass transport, momentum and heat transfer in the SOFC unit. After model validation, parametric simulations are conducted to investigate how the methane pre-reforming ratio affects the transport and electrochemistry of the SOFC unit. It is found that the methane steam reforming reaction has a "smoothing effect", which can achieve more uniform distributions of gas compositions, current density and temperature among the cell plane. In the case of 1500 W/m^2 power density output, adding 20% methane absorbs 50% of internal heat production inside the cell, reduces the maximum temperature difference inside the cell from 70 K to 22 K and reduces the cathode air supply by 75%, compared to the condition of completely pre-reforming of methane. Under specific operating conditions, the pre-reforming ratio of methane has an optimal range for obtaining a good temperature distribution and good cell performance.
基金supported by the National Natural Science Foundation of China (Grant No. 51102246)the Knowledge Innovation Program of Institute of Metal Research, Chinese Academy of Sciences (Grant No.Y0N5A111A1)the Youth Innovation Promotion Association, Chinese Academy of Sciences (Grant No.Y2N5711171)
文摘Well crystallized niobium-doped TiO; nanotube arrays (TiNbO-NT) were successfully synthesized via the anodization of titanium/niobium alloy sheets, followed with a heat treatment at 550 ℃ for 2 h. Morphology analysis results demonstrated that both the titanium/niobium alloy microstructure and the dissolution strength of electrolyte played major roles in the formation of nanotube structure. A single-phase microstructure was more favorable to the formation of uniform nanotube arrays, while modulating the dissolution strength of electrolyte was required to obtain nanotube arrays from the alloys with multi-phase microstructures. X-ray diffraction (XRD) and X-ray photoelectron (XPS) analysis results clearly demonstrated that niobium dopants (Nb^5+) were successfully doped into TiO2 anatase lattice by substituting Ti^4+ in this approach.
文摘At elevated temperature regimes and abundant precipitation, mobilization and accretion of weathered iron oxides are promoted especially in a reduced environments in the tropics. This may lead to the formation of plinthite, which hardens irreversibly upon repeated wetting and drying to form petroplinthite. The need for this review stems from the seemingly dearth of information on the subject and a need to clarify different terms used in describing plinthite. We review various research works on plinthite and its associated pedogenic forms in the tropics. Furthermore, we proffer recommendations as to the most appropriate land use management practices that could help minimise the environmental and agronomic problems associated with plinthite and its related pedogenic forms. Parent material, temperature, seasonality and geomorphology are critical factors that influence soil water regime which in turn affect the pedogenesis of plinthite. Soil pH and mineralogy are additional factors that could also promote plinthite formation. Fossil plinthic soils are potential proxies for palaeoenvironmental reconstruction. Measures used in the management of plinthic soils include mechanically breaking the hardpans and the use of organic and inorganic amendments to modify the structure and chemistry of the soils. Avoidance of practices that would predispose soils to erosion would also prevent plinthization. We call for the relinquishment of the term "[aterite" which is a generM term for all forms of iron oxide-enriched earthy materials as used for plinthite. Plinthic horizon should also be incorporated into the United States Department of Agriculture Soil Taxonomy in view of its growing importance in soils.
文摘Editor's comments Formaldehyde (HCHO) emitted from chemical manufacturing plants including methanol-gasoline/diesel fuel vehicles and the construction and decoration materials is one of the major air pollutions, which induces photochemical pollution and hazards human health. Great efforts have been made for the reduction or control of the emission of HCHO to satisfy the stringent environmental regulations. Now, a new study supported by the National Natural Science Foundation of China reports mesoporous manganese oxide with novel nanostructures for the decomposition of HCHO. The obtained manganese oxide nanomaterials showed high catalytic activities for oxidative decomposition of HCHO at low temperatures. Complete conversion of HCHO to CO2 and H2O were achieved, and no harmful by- products were detected in effluent gases. The catalytic activities of these nanomaterials are significantly higher than those of previously reported manganese oxide octahedral molecular sieve (OMS-2) nanorods , MnO x powders, and alumnina-supported mangnaese-palladium oxide catalysts. These results provide a new route for the removal of HCHO and other air pollutions.
基金supported by the National Natural Science Foundation of China(Grant No.21161160447)
文摘The full solution-processed oxide thin-film-transistors(TFTs) have the advantages of transparency, ease of large-area fabrication, and low cost, offering great potential applications in switching and driving fields, and attracting extensive research interest. However, the performance of the solution-processed TFTs is generally lower than that of the vacuum-deposited ones. In this article, the full-solution processed TFTs with zinc-tin-oxide(ZTO) semiconductor and aluminium(Al_2O_3) dielectrics were fabricated, and their mobilities in the saturation region are high. Besides, the effect of the Al_2O_3 dielectrics' preparation technology on ZTO TFTs' performance was studied. Comparing the ZTO TFTs using the spin-coated Al_2O_3 dielectrics of 1–4 layers, the ZTO TFT with 3-layer Al_2O_3 dielectrics achieved the optimal performance as its field-effect carrier mobility in the saturation region is 112 cm^2/V s, its threshold voltage is 2.4 V, and its on-to-off current ratio is 2.8×105. This is also the highest reported carrier mobility of the solution-processed ZTO TFTs.