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硫高温腐蚀及腐蚀产物氧化自燃性的研究 被引量:1
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作者 石振东 赵杉林 +3 位作者 李萍 翟玉春 李东胜 宋毅 《安全与环境学报》 CAS CSCD 2008年第6期100-103,共4页
随着炼制原油硫含量的增加,炼油装置的硫腐蚀问题也日益严重。针对硫高温腐蚀状况,用差热-热重分析仪研究硫与Fe(OH)3、Fe2O3和Fe3O4发生硫化腐蚀反应的初始温度,并采用X射线衍射仪鉴定了360℃高温无氧条件下硫化腐蚀产物的组成。结果表... 随着炼制原油硫含量的增加,炼油装置的硫腐蚀问题也日益严重。针对硫高温腐蚀状况,用差热-热重分析仪研究硫与Fe(OH)3、Fe2O3和Fe3O4发生硫化腐蚀反应的初始温度,并采用X射线衍射仪鉴定了360℃高温无氧条件下硫化腐蚀产物的组成。结果表明,硫与Fe(OH)3、Fe2O3和Fe3O4发生硫化反应的初始温度分别为287.67℃、233.34℃和308.47℃;高温硫化腐蚀产物主要是FeS2。对硫化产物FeS2进行氧化反应,氧化升温曲线和耗氧曲线表明,硫化腐蚀产物FeS2具有很高的氧化自燃性,在一定条件下能引发油品火灾和爆炸等事故。 展开更多
关键词 安全工程 高温腐蚀 氧化自燃性
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巷道煤体破碎程度的模糊综合评判 被引量:9
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作者 邓军 徐通模 +1 位作者 王华 陈晓坤 《煤炭学报》 EI CAS CSCD 北大核心 2003年第2期145-148,共4页
煤的破碎程度直接影响着煤的氧化自燃性,但实际条件下煤体的破碎程度难以定量确定.根据煤层地质构造、煤的硬度、压力参数、采煤方法和巷道参数等影响巷道煤体破碎程度的多种因素,采用专家给分的方法确定各影响因素权值,并采用多级模糊... 煤的破碎程度直接影响着煤的氧化自燃性,但实际条件下煤体的破碎程度难以定量确定.根据煤层地质构造、煤的硬度、压力参数、采煤方法和巷道参数等影响巷道煤体破碎程度的多种因素,采用专家给分的方法确定各影响因素权值,并采用多级模糊综合评判的方法对巷道煤体破碎程度进行综合评判,客观评价出其破碎等级,从而为巷道煤体自燃危险性预测和防灭火提供依据. 展开更多
关键词 巷道 破碎程度 氧化自燃性 地质构造 压力参数 采煤方法
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Experimental study on performance that carbon dioxide inhibits coal oxidation and spontaneous combustion 被引量:3
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作者 DENG Jun LI Shi-rong +2 位作者 ZHANG Yan-ni MU Ying ZHANG Yang 《Journal of Coal Science & Engineering(China)》 2011年第3期326-330,共5页
Adopting oil-bath temperature programming experiment and gas chromatography, CO2's inhibitory performance on spontaneous combustion of Tingnan Coal Mine sample was analyzed. Through temperature rise rate test experim... Adopting oil-bath temperature programming experiment and gas chromatography, CO2's inhibitory performance on spontaneous combustion of Tingnan Coal Mine sample was analyzed. Through temperature rise rate test experiment, the accuracy, stability and reliability of the improved oil-bath temperature programming system applied in this experiment was proved to be superior to the traditional system. Spontaneous combustion characters parameters test of coal sample in pure air was carried out with this system and offered comparison standard for research in next stage. Temperature programming to coal sample was further conducted in oil-bath with different concentration of CO2. Testing results are compared with parameters of concentration of CO, O2, temperature, CO generation rate and O2 consumption rate tested and calculated in previous experiment in pure air. Methods of proportioning between concentration of CO and O2, CO concentration and temperature, CO generation rate and O2 consumption rate were applied to eliminate obstructions from certain external factors such as inlet of CO2; meanwhile influences of CO2 of different concentrations to coal oxidation and spontaneous combustion were investigated. Also CO2 inhibition technique was used in spontaneous combustion prevention in workface No. 106 of Tingnan Coal Mine, data collected from which indicate that CO2 performs well in inhibiting coal oxidation and spontaneous combustion. 展开更多
关键词 carbon dioxide (CO2) coal spontaneous combustion fire disaster
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