Tungsten oxide （W18O49） nanorods were grown by directly heating tungsten foils covered with potassium bromide （KBr） in low-pressure wet oxygen. The approach featured such advantages as convenient manipulation, low...Tungsten oxide （W18O49） nanorods were grown by directly heating tungsten foils covered with potassium bromide （KBr） in low-pressure wet oxygen. The approach featured such advantages as convenient manipulation, low cost and rapid accessibility to high temperatures. A solid-liquid-solid （SLS） mechanism is believed to have dominated the growth process, in which the W18049 nanorods segregated from eutectic droplets of potassium tungstate and tungsten oxide. The ultraviolet photoelectron spectroscopy （UPS） analysis disclosed that the valence band maximum （VBM） of these nanorods was approximately 9 eV be- low the vacuum level. The feasibility of using the such-fabricated nanorods as field emitters was tested and the related mecha- nism was also discussed.展开更多
基金Research Foundation for Talented Scholars of Suqian College(SQCGJ2010002)Practice of College Students in Jiangsu Province Innovative Training Projects(2010SSJ02)
基金supported by the National Natural Science Foundation of China (Grant Nos. 61171023,61076057 and 61072025)
文摘Tungsten oxide （W18O49） nanorods were grown by directly heating tungsten foils covered with potassium bromide （KBr） in low-pressure wet oxygen. The approach featured such advantages as convenient manipulation, low cost and rapid accessibility to high temperatures. A solid-liquid-solid （SLS） mechanism is believed to have dominated the growth process, in which the W18049 nanorods segregated from eutectic droplets of potassium tungstate and tungsten oxide. The ultraviolet photoelectron spectroscopy （UPS） analysis disclosed that the valence band maximum （VBM） of these nanorods was approximately 9 eV be- low the vacuum level. The feasibility of using the such-fabricated nanorods as field emitters was tested and the related mecha- nism was also discussed.
