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基于氧化铁模板原位制备Ni/Fe-LDHs/Fe薄膜及其性能研究
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作者 杜宝中 陆宁 +1 位作者 张倩岚 王妙娟 《功能材料》 EI CAS CSCD 北大核心 2019年第5期5160-5165,共6页
采用模版原位生长技术,以NH_3·H_2O调节Ni(NO_3)_2-NH_4NO_3反应溶液pH值,形成镍氨配离子达到缓慢释放Ni^(2+),实现了在阳极氧化铁模板(AFO/Fe)上制备Ni/Fe-NO_3-LDHs/Fe薄膜前驱体;然后,通过离子交换反应将磺基水杨酸阴离子(SSA)... 采用模版原位生长技术,以NH_3·H_2O调节Ni(NO_3)_2-NH_4NO_3反应溶液pH值,形成镍氨配离子达到缓慢释放Ni^(2+),实现了在阳极氧化铁模板(AFO/Fe)上制备Ni/Fe-NO_3-LDHs/Fe薄膜前驱体;然后,通过离子交换反应将磺基水杨酸阴离子(SSA)插层制备了Ni/Fe-SSA-LDHs/Fe复合薄膜。借助XRD、FT-IR、SEM、UV-Vis、TG/DTA及电化学测试等手段对LDHs薄膜结构及性能进行了表征与分析。结果显示,SSA阴离子插入LDHs层间,插层距由0.9051 nm扩至1.1837 nm,水滑石晶片主要以c轴平行于氧化铁模版生长。该薄膜表现出优异的耐蚀性和紫外阻隔性能。 展开更多
关键词 氧化铁模板 LDHs薄膜 插层组装 缓蚀 紫外阻隔
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Preparation and Characterization of Fe Nanowire Arrays Embedded in Porous Anodic Aluminum Oxide Templates 被引量:1
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作者 迟广俊 姚素薇 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第2期315-318,共4页
Fe nanowire arrays are prepared by electrodeposition in porous anodic aluminum oxide template from a composite electrolyte solution. These nanowires have an uniform diameter of approximate 25 nm and a length in excess... Fe nanowire arrays are prepared by electrodeposition in porous anodic aluminum oxide template from a composite electrolyte solution. These nanowires have an uniform diameter of approximate 25 nm and a length in excess of 2.5 μm. The micrographs and crystal structures of Fe nanowires are studied by transmission electron microscopy (TEM), selected-area electron diffraction (SAED), and X-ray diffraction(XRD). It is found that each nanowire is essentially a single crystal and has a different orientation in each array. Hysteresis loops of Fe nanowire array show that its easy magnetization direction is perpendicular to the sample plane. 展开更多
关键词 ELECTRODEPOSITION NANOSTRUCTURE aluminum anodization
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