钢中氧含量超标会直接影响钢的机械性能,为确保LNG储罐的使用安全,准确测定其制造用材料06Ni9DR中的氧含量就显得尤为重要。通过多次试验对仪器各项参数进行选择优化,确定了最合适的试验条件,以确保数据的准确性。试验表明:脱气功率为5 ...钢中氧含量超标会直接影响钢的机械性能,为确保LNG储罐的使用安全,准确测定其制造用材料06Ni9DR中的氧含量就显得尤为重要。通过多次试验对仪器各项参数进行选择优化,确定了最合适的试验条件,以确保数据的准确性。试验表明:脱气功率为5 k W、脱气时间为45 s、分析功率为4 k W、分析时间为30 s时06Ni9DR钢板氧元素能排除干扰完全释放得到准确值,并与标准样品进行比对验证分析结果可靠。展开更多
In order to reduce the hazard of coal spontaneous combustion,the cross-linking reaction between O-containing functional groups of coal should be inhibited.So the inhibitory effect of an ionic liquid(IL) on the cross-l...In order to reduce the hazard of coal spontaneous combustion,the cross-linking reaction between O-containing functional groups of coal should be inhibited.So the inhibitory effect of an ionic liquid(IL) on the cross-linking reaction was studied.The O-containing functional groups change the weight loss and H_2O,CO_2,CO yields of bituminous coal before and after[H0Emim][BF_4]and[Amim]Cl pre-treatment and were detected by Fourier Transform Infrared spectroscopy(FT1R) and Thermo Gravimetric(TC) analysis.The results show that | AmimjCI has a weaker ability to inhibit the cross-linking reaction of bituminous coal compared to[HOEmim][BF_4].Besides,based on Quantum Chemistry calculation,it was found that the different inhibiting effects of |H0Emim][BF_4]and[Amim]Cl are greatly related to their anions and the H linked with C2 atom on the imidazole ring.The H-donor ability of coal will be enhanced by[HOEmim][BF_4]leading to a weaker cross-linking reaction of coal.展开更多
Quantitative analysis of saccharin in preserved fruits was performed by High Performance Liquid Chromatography （HPLC）. The separation was observed on a reversed phase ODS C）8 column （4.6 × 250 mm）. Mobile ph...Quantitative analysis of saccharin in preserved fruits was performed by High Performance Liquid Chromatography （HPLC）. The separation was observed on a reversed phase ODS C）8 column （4.6 × 250 mm）. Mobile phase system consisted of ammonium acetate buffer： Methanol （60：40 v/v） at a flow rate of 1.0 mL.min^-1, and UV detector was set at 235 nm. The calibration curve of saccharin was linear in the concentration range between 1 to 100 mg·L^-1）, while the detection limit of saccharin was found to be 0.08 mg.L^-1. The mean value of recovery was 98.24% with standard deviation of0.32% （n=12）. The proposed method was successfully applied to determine the amount of saccharin in 12 preserved fruits, commercially available in Chiang Mai local markets. The results showed that the saccharin contents were found in the range of 6.22-78.60 mg.kg^-1.展开更多
文摘钢中氧含量超标会直接影响钢的机械性能,为确保LNG储罐的使用安全,准确测定其制造用材料06Ni9DR中的氧含量就显得尤为重要。通过多次试验对仪器各项参数进行选择优化,确定了最合适的试验条件,以确保数据的准确性。试验表明:脱气功率为5 k W、脱气时间为45 s、分析功率为4 k W、分析时间为30 s时06Ni9DR钢板氧元素能排除干扰完全释放得到准确值,并与标准样品进行比对验证分析结果可靠。
基金the support from the National Natural Science Foundation of China(Nos.51304073and 51304071)the Educational Commission of Henan Province(Nos.13A440324 and 12B440004)+1 种基金the Open Projects of State Key Laboratory of Coal Resources and Safe Mining,China University of Mining and Technology(No.12KF02)Henan Polytechnic University(Nos.B2012-068 and B2012-085)
文摘In order to reduce the hazard of coal spontaneous combustion,the cross-linking reaction between O-containing functional groups of coal should be inhibited.So the inhibitory effect of an ionic liquid(IL) on the cross-linking reaction was studied.The O-containing functional groups change the weight loss and H_2O,CO_2,CO yields of bituminous coal before and after[H0Emim][BF_4]and[Amim]Cl pre-treatment and were detected by Fourier Transform Infrared spectroscopy(FT1R) and Thermo Gravimetric(TC) analysis.The results show that | AmimjCI has a weaker ability to inhibit the cross-linking reaction of bituminous coal compared to[HOEmim][BF_4].Besides,based on Quantum Chemistry calculation,it was found that the different inhibiting effects of |H0Emim][BF_4]and[Amim]Cl are greatly related to their anions and the H linked with C2 atom on the imidazole ring.The H-donor ability of coal will be enhanced by[HOEmim][BF_4]leading to a weaker cross-linking reaction of coal.
文摘Quantitative analysis of saccharin in preserved fruits was performed by High Performance Liquid Chromatography （HPLC）. The separation was observed on a reversed phase ODS C）8 column （4.6 × 250 mm）. Mobile phase system consisted of ammonium acetate buffer： Methanol （60：40 v/v） at a flow rate of 1.0 mL.min^-1, and UV detector was set at 235 nm. The calibration curve of saccharin was linear in the concentration range between 1 to 100 mg·L^-1）, while the detection limit of saccharin was found to be 0.08 mg.L^-1. The mean value of recovery was 98.24% with standard deviation of0.32% （n=12）. The proposed method was successfully applied to determine the amount of saccharin in 12 preserved fruits, commercially available in Chiang Mai local markets. The results showed that the saccharin contents were found in the range of 6.22-78.60 mg.kg^-1.
