In order to reduce the hazard of coal spontaneous combustion,the cross-linking reaction between O-containing functional groups of coal should be inhibited.So the inhibitory effect of an ionic liquid(IL) on the cross-l...In order to reduce the hazard of coal spontaneous combustion,the cross-linking reaction between O-containing functional groups of coal should be inhibited.So the inhibitory effect of an ionic liquid(IL) on the cross-linking reaction was studied.The O-containing functional groups change the weight loss and H_2O,CO_2,CO yields of bituminous coal before and after[H0Emim][BF_4]and[Amim]Cl pre-treatment and were detected by Fourier Transform Infrared spectroscopy(FT1R) and Thermo Gravimetric(TC) analysis.The results show that | AmimjCI has a weaker ability to inhibit the cross-linking reaction of bituminous coal compared to[HOEmim][BF_4].Besides,based on Quantum Chemistry calculation,it was found that the different inhibiting effects of |H0Emim][BF_4]and[Amim]Cl are greatly related to their anions and the H linked with C2 atom on the imidazole ring.The H-donor ability of coal will be enhanced by[HOEmim][BF_4]leading to a weaker cross-linking reaction of coal.展开更多
Factors contributing to ventilation quantity of the vehicle are ventilation modes, cabin characteristics and vehicle speeds. CO2 levels were investigated under different speeds and ventilation modes. Four modes were s...Factors contributing to ventilation quantity of the vehicle are ventilation modes, cabin characteristics and vehicle speeds. CO2 levels were investigated under different speeds and ventilation modes. Four modes were selected： A： vent closed and fan shut, B： vent closed and fan started, C： vent opened and fan shut, D： vent opened and fan started. In vent closed modes, CO2 levels reached several thousands of ppm in few minutes at any speeds. For mode C, CO2 levels exceeded the guideline at low speeds 50 km/h, while it reduced below one at higher speeds 80 km/h. Fan has no significant impact on ventilation during vent closed. The ventilation efficiency in each mode increased with the speed raising. To determine the ventilation rate of running vehicle, the experiment was implemented by using CO2 emitted from driver and passengers as tracer gas. Ventilation rate for the different modes and speeds were calculated.展开更多
基金the support from the National Natural Science Foundation of China(Nos.51304073and 51304071)the Educational Commission of Henan Province(Nos.13A440324 and 12B440004)+1 种基金the Open Projects of State Key Laboratory of Coal Resources and Safe Mining,China University of Mining and Technology(No.12KF02)Henan Polytechnic University(Nos.B2012-068 and B2012-085)
文摘In order to reduce the hazard of coal spontaneous combustion,the cross-linking reaction between O-containing functional groups of coal should be inhibited.So the inhibitory effect of an ionic liquid(IL) on the cross-linking reaction was studied.The O-containing functional groups change the weight loss and H_2O,CO_2,CO yields of bituminous coal before and after[H0Emim][BF_4]and[Amim]Cl pre-treatment and were detected by Fourier Transform Infrared spectroscopy(FT1R) and Thermo Gravimetric(TC) analysis.The results show that | AmimjCI has a weaker ability to inhibit the cross-linking reaction of bituminous coal compared to[HOEmim][BF_4].Besides,based on Quantum Chemistry calculation,it was found that the different inhibiting effects of |H0Emim][BF_4]and[Amim]Cl are greatly related to their anions and the H linked with C2 atom on the imidazole ring.The H-donor ability of coal will be enhanced by[HOEmim][BF_4]leading to a weaker cross-linking reaction of coal.
文摘Factors contributing to ventilation quantity of the vehicle are ventilation modes, cabin characteristics and vehicle speeds. CO2 levels were investigated under different speeds and ventilation modes. Four modes were selected： A： vent closed and fan shut, B： vent closed and fan started, C： vent opened and fan shut, D： vent opened and fan started. In vent closed modes, CO2 levels reached several thousands of ppm in few minutes at any speeds. For mode C, CO2 levels exceeded the guideline at low speeds 50 km/h, while it reduced below one at higher speeds 80 km/h. Fan has no significant impact on ventilation during vent closed. The ventilation efficiency in each mode increased with the speed raising. To determine the ventilation rate of running vehicle, the experiment was implemented by using CO2 emitted from driver and passengers as tracer gas. Ventilation rate for the different modes and speeds were calculated.
