LaNiO_3薄膜热稳定性的研究

LaNiO3导电金属氧化物薄膜在现代应用科学研究中作为电极和过渡阻挡层倍受青睐,它具有很好的导电特性和稳定性。该文采用射频溅射法制备了具有(100)择优取向的赝立方结构LaNiO3-x薄膜,并进行了原位热处理。实验结果表明,在265°C的处理条件下,LaNiO3薄膜表现出不稳定性,晶格中的氧在2h内失去了2.7%。氧的损失对晶格结构没有明显影响,但薄膜的导电性能明显下降,折射率和消光系数也具有相同幅度的下降。对薄膜的应用具有一定的影响。该文从LaNiO3薄膜的导电机理方面对实验现象给出了分析和解释。

Role of Amorphous Manganese Oxide in Nitrogen Loss

Studies have been made, by 15N-tracer technique on nitrogen loss resulting from adding amorphous manganese oxide to NH4+-N medium under anaerobic conditions. The fact that the total nitrogen recovery was decreased and that 15NO2, 15N2O, 15N14NO, 15NO, 15N2and 15N14N were emitted has proved that, like amorphous iron oxide, amorphous manganese oxide can also act as an electron acceptor in the oxidation of NH4+-N under anaerobic conditions and give rise to nitrogen loss. This once again illustrates another mechanism by which the loss of ammonium nitrogen in paddy soils is brought about by amorphous iron and manganese oxides. The quantity of nitrogen loss by amorphous manganese oxide increased with an increase in the amount of amorphous manganese oxide added and lessened with time of its aging. The nitrogen loss resulting from amorphous manganese oxide was less than that from amorphous iron oxide. And the nitrogen loss by cooperation of amorphous manganese oxide and microorganisms (soil suspension ) was larger than that by amorphous manganese oxide alone. In the system, nitrogen loss was associated with the specific surface area and oxidation-reduction of amorphous manganese oxide. However, their quantitative relationship and the exact reaction processes of nitrogen loss induced by amorphous manganese oxide remain to be further studied.

What Is Important in Selecting Phlebiopsis gigantea Strain for Commercial Use？

Phlebiopsis gigantea strains registered in the European Union as biocontrol agents against root rot in forests （four from Great Britain and two from Finland） were compared using Ward＇s method with reference to： （l） similarity of DNA-random amplified microsatellite （RAMS） ladders, （2） cellulase and peroxidase production and （3） acceleration of dry mass wood loss in Norway spruce The activity of the enzymes was tested in the initial phase of wood decay （30 d after inoculation） and indicated as the most active isolates： VFI0 and FCl5 for cellulase and FC16 and VFI0 for peroxidase production. The assessment of loss of wood six months after inoculation indicated isolate FC 15 as the most active. P. gigantea isolates similar in terms of enzyme activity indicated different patterns ofDNA microsatellite loci. At the same time, DNA-RAMS revealed similarities in isolates with different abilities to produce enzymes. However, some similarities and differences between isolates according to wood decay were found. No plain relationships between molecular characteristics and enzyme activity of the strains tested were observed. The results differentiated activity of tested isolates and suggested benefits of selecting P. gigantea strains for commercial use basing mainly on the assessment of wood loss activity.

Thermal Analysis and Kinetics of Coal during Oxy-Fuel Combustion

The pyrolysis and oxy-fuel combustion characteristics of Polish bituminous coal were studied us/ng non- isothermal thermogravimetric analysis. Pyrolysis tests showed that the mass loss profiles were almost similar up to 870℃ ha both N2 and CO2 atmospheres, while further mass loss occurred ha CO2 atmosphere at higher temper- atures due to char-CO2 gasification. Replacement of N2 ha the combustion environment by CO2 delayed the com- bustion of bituminous coal. At elevated oxygen levels, TG/DTG profiles shifted through lower temperature zone, ignition and burnout temperatures decreased and mass loss rate significantly increased and complete combustion was achieved at lower temperatures and shorter times. Kinetic analysis for the tested coal was performed using Kissinger-Akahira-Sunose （KAS） method. The activation energies of bituminous coal combustion at the similar oxygen content in oxy-fuel with that of air were higher than that in air atmosphere. The results indicated that, with O2 concentration increasing, the activation energies decreased.

Field experiments on greenhouse gas emissions and nitrogen and phosphorus losses from rice paddy with efficient irrigation and drainage management

Greenhouse gas emissions,nitrogen and phosphorous losses through ammonia volatilization,leaching and surface drainage from rice paddy under efficient irrigation and drainage were analyzed based on field experimental data in order to reveal the eco-environmental impacts of efficient irrigation and drainage on rice paddy.The results showed that total methane emission from rice paddy under the controlled irrigation was reduced by more than 80% and total nitrous oxide emission increased by 15.9% compared with flooding irrigation.Seasonal comprehensive global warming potentials(GWP) of methane and nitrous oxide were 62.23 gCO2 m-2 for rice paddy under the controlled irrigation,reduced by 68.0% compared with flooding irrigation.Due to large reduction in seepage and surface drainages,nitrogen and phosphorous losses through leaching were reduced by 40.1% and 54.8%,nitrogen and phosphorous losses through surface drainage were reduced by 53.9% and 51.6% from rice paddy under efficient irrigation and drainage compared with traditional irrigation and drainage.Nitrogen loss through ammonia volatilization was reduced by 14.0%.Efficient irrigation and drainage management is helpful to mitigate greenhouse gases emission,nitrogen and phosphorus losses and their pollution on groundwater and surface water.

Dynamic observation of oxygen vacancies in hafnia layer by in situ transmission electron microscopy

The charge-trapping process, with HfO2 film as the charge-capturing layer, has been investigated by using in situ electron energy-loss spectroscopy and in situ energy-filter image under positive external bias. The results show that oxygen vacancies are non-uniformly distributed throughout the HfO2 trapping layer during the programming process. The distribution of the oxygen vacancies is not the same as that of the reported locations of the trapped electrons, implying that the trapping process is more complex. These bias-induced oxygen defects may affect the device performance characteristics such as the device lifetime. This phenomenon should be considered in the models of trapping processes.

E-beam-induced in situ structural transformation in one-dimensional nanomaterials

Electron beam （e-beam） irradiation is an inev- itable, but crucial issue for electron microscopy. Our investigation results show the e-beam-induced in situ structural transformations in silicon （Si） nanowires and zinc oxide （ZnO） nanowires （NWs）, respectively. Crystal to amorphous structure transition was revealed in Si NWs utilizing high resolution electron microscopy and electron energy loss spectroscopy. Reconstruction at the （1010） surface of ZnO NWs was also observed in the transmission electron microscope （TEM） using aberration-corrected electron microscopy. These e-beam-induced in situ struc- tural transformations prove that the electron beam irradi- ation effect is able to be used for the local modification of one-dimensional nanomaterials.