[Objective] The aim was to analyze water and heat fluxes, CO2 fluxes and energy balance in wheat ecosystem in Luancheng County of Hebei Province. [Method] Based on data of water and heat flux, and CO2 fluxes, routine ...[Objective] The aim was to analyze water and heat fluxes, CO2 fluxes and energy balance in wheat ecosystem in Luancheng County of Hebei Province. [Method] Based on data of water and heat flux, and CO2 fluxes, routine meteorological and biomass data in Luancheng in 2008, water and heat fluxes, CO2 fluxes and energy balance in wheat ecosystem were explored. [Result] The results showed that latent and sensible heat and CO2 fluxes were of obvious daily and seasonal changes; latent and sensible heat fluxes shaped an inverted U in daily change, and CO2 fluxes were of a U-shape; daily flux peak differed significantly. Furthermore, the change of latent heat, sensible heat and CO2 fluxes were closely related to environ- mental factors. Detailedly, the three were sensitive to light intensity and net radiation, and correlation coefficients were 0.92, 0.66, 0.65 and 0.90, 0.69, 0.74, respectively. Besides, the fluxes, sensitive to temperature, proved better in sunny day, especially for latent flux which is more sensitive to water in soils after precipitation. In addition, closure degree of energy balance in wheat fields was 0.91 and non-closure, caused by measurement error and neglection of heat storage, was observed, too. What＇s more. closure degree differed in months and time periods within a day. [Conclusion] The research concluded water and heat fluxes, CO2 fluxes, transport mechanisms and concerning factors, providing scientific reference for revealing mechanism of evapo- ration and heat dissipation of canopy, relationship between photosynthesis and water use efficiencyand energy distribution mechanism.展开更多
The current irrational use of fossil fuels and the impact of greenhouse gases on the environment are driving research into renewable energy production from organic resources and waste. The global energy demand is high...The current irrational use of fossil fuels and the impact of greenhouse gases on the environment are driving research into renewable energy production from organic resources and waste. The global energy demand is high, and most of this energy is produced from fossil resources. Recent studies report that anaerobic di- gestion （AD） is an efficient alternative technology that combines biofuel production with sustainable waste management, and various technological trends exist in the biogas industry that enhance the production and quality of biogas. Further investments in AD are expected to meet with increasing success due to the low cost of available feedstocks and the wide range of uses for biogas （i.e., for heating, electricity, and fuel）. Bio- gas production is growing in the European energy market and offers an economical alternative for bioenergy production. The objective of this work is to provide an overview of biogas production from lignocellulosic waste, thus providing information toward crucial issues in the biogas economy.展开更多
Metal‐organic frameworks(MOFs)are a series of highly porous crystalline materials,which are built from inorganic metal nodes and organic linkers through coordination bonds.Their unique porous structural features(such...Metal‐organic frameworks(MOFs)are a series of highly porous crystalline materials,which are built from inorganic metal nodes and organic linkers through coordination bonds.Their unique porous structural features(such as high porosity,high surface areas,and highly ordered nanoporous structures)and designable structures and compositions have facilitated their use in gas capture,separation,catalysis,and energy storage and conversion.Recently,the design and synthesis of pure MOFs and their derivatives have opened new routes to develop highly efficient electrocatalysts toward oxygen reduction reactions(ORR)and oxygen evolution reactions(OER),which are the core electrode reactions in many energy storage and conversion techniques,such as metal‐air batteries and fuel cells.This review first discusses recent progress in the synthesis and the electrocatalytic applications of pure MOF‐based electrocatalysts toward ORR or OER,including pure MOFs,MOFs decorated with active species,and MOFs incorporated with conductive materials.The following section focuses on the advancements of the design and preparation of various MOF‐derived materials-such as inorganic nano‐(or micro‐)structures/porous carbon composites,pure porous carbons,pure inorganic nano‐(or micro‐)structured materials,and single‐atom electrocatalysts-and their applications in oxygen electrocatalysis.Finally,we present a conclusion and an outlook for some general design strategies and future research directions of MOF‐based oxygen electrocatalysts.展开更多
The Tibetan Plateau(TP)is an area sensitive to climate change,where the ozone distribution affects the atmospheric environment of the TP and its surrounding regions.The relatively low total column ozone over the TP in...The Tibetan Plateau(TP)is an area sensitive to climate change,where the ozone distribution affects the atmospheric environment of the TP and its surrounding regions.The relatively low total column ozone over the TP in boreal summer and its spatiotemporal variations have received extensive attention.In this study,five-year balloon-borne measurements of ozone over Lhasa in boreal summer are used to investigate the influences of the apparent heat source(Q1)on the ozone vertical structure over the plateau.The mechanisms for the above processes are also explored.The results show that the tropospheric ozone mixing ratio over Lhasa decreases when the total atmospheric Q1 in the troposphere over the TP is relatively high.Strengthened ascending motions are accompanied by enhanced Q1 over the main TP region.Consequently,the tropospheric ozone mixing ratio over Lhasa decreases when Q1 is higher in summer,which is attributed to the upward transport of the ozone-poor surface air.展开更多
Silica sources influence different aspects of Al-MCM-41 product. The crystallinity of nanosized Al-MCM-41 zeolites prepared crystallization and lead to change in the properties of the final from precursors mixtures co...Silica sources influence different aspects of Al-MCM-41 product. The crystallinity of nanosized Al-MCM-41 zeolites prepared crystallization and lead to change in the properties of the final from precursors mixtures containing different silica sources, e.g. tetraethylorthosilicate （TEOS）, colloidal silica （CS）, silicic acid （SA） and fumed silica （FS） have been studied. The produced samples are investigated using XRD, SEM, FT-IR, pyridine adsorption and N2 physisorption. XRD results show that the products obtained from different silica sources are in Al-MCM-41 phase. SEM results show that silica sources influence the produced Al-MCM-41 shape. Using silicic acid leads to formation of spherical crystals, TEOS gives cubical crystals, colloidal silica forms spherical crystals with smaller aggregated, and fumed silica gives rounded crystals. N2 physisorption results show that silica sources influence pore-diameter and pore-volume of the produced Al-MCM-41 ; the pore diameter of the produced Al-MCM-41 in case of colloidal silica, TEOS, fumed silica, and silicic acid are 12, 20, 15, and 17A respectively. Also, the pore volume of the produced AI-MCM-41 in case of colloidal silica, TEOS, fumed silica and silicic acid are 0.78, 0.71, 0.76, and 0.8 cm^3/gm, respectively.展开更多
Methane-rich fluids were recognized to be hosted in the reservoir volcanic rocks as primary inclusions. Samples were collected from core-drillings of volcanic gas reservoirs with reversed δ13C of alkane in the Xujiaw...Methane-rich fluids were recognized to be hosted in the reservoir volcanic rocks as primary inclusions. Samples were collected from core-drillings of volcanic gas reservoirs with reversed δ13C of alkane in the Xujiaweizi depression of the Songliao Basin. The volcanic rocks are rhyolite dominant being enriched in the more incompatible elements like Cs, Rb, Ba, Th, U and Th with relative high LREE, depleted HREE and negative anomalies of Ti and Nb, suggesting a melt involving both in mantle source and crustal assimilation. Primary fluids hosted in the volcanic rocks should have the same provenance with the magma. The authors concluded that the enclosed CH4 in the volcanics are mantle/magma-derived alkane and the reversed δ13C of alkane in the corresponding gas reservoirs is partly resulted from mixture between biogenic and abiogenic gases.展开更多
Since the nuclear disaster occurred from huge earthquake in Japan 2011, Japanese energy generation system has been expected to prioritize safety and trustworthiness. To meet this requirement, distributed power supply ...Since the nuclear disaster occurred from huge earthquake in Japan 2011, Japanese energy generation system has been expected to prioritize safety and trustworthiness. To meet this requirement, distributed power supply systems are considered to be one of solutions. In this study, we aimed to conserve energy and reduce carbon dioxide emission of supermarket which installed a novel environment-friendly dispersed power. We focused the energy used by refrigerated cabinets. We built small scale model of supermarket which was equipped with dispersed power. From this scale model, the energy conservation effect of supercooling is from 10% to 25% during the summertime and intermediate time. At last, we found that when outside temperature is about 14 ℃ or more, supercooling was effective. In addition, since energy consumption of refrigerated cabinet is influenced by inside enthalpy, we controlled the inside air temperature and humidity by installing desiccant system and examined its effect.展开更多
Surface ozone(O_(3))poses significant threats to public health,agricultural crops,and plants in natural ecosystems.Global warming is likely to increase future O_(3)mainly by altering atmospheric photochemical reaction...Surface ozone(O_(3))poses significant threats to public health,agricultural crops,and plants in natural ecosystems.Global warming is likely to increase future O_(3)mainly by altering atmospheric photochemical reactions and enhancing biogenic volatile organic compound(BVOC)emissions.To assess the impacts of the future 1.5 K climate target on O_(3)concentrations and ecological O_(3)exposure in China,numerical simulations were conducted using the CMAQ(Community Multiscale Air Quality)model during April-October 2018.Ecological O_(3)exposure was estimated using six indices(i.e.,M7,M24,N100,SUM60,W126,and AOT40f).The results show that the temperature rise increases the MDA8 O_(3)(maximum daily eight-hour average O_(3))concentrations by∼3 ppb and the number of O_(3)exceedance days by 10-20 days in the North China Plain(NCP),Yangtze River Delta(YRD),and Sichuan Basin(SCB)regions.All O_(3)exposure indices show substantial increases.M24 and M7 in eastern and southern China will rise by 1-3 ppb and 2-4 ppb,respectively.N100 increases by more than 120 h in the surrounding regions of Beijing.SUM60 increases by greater than 9 ppm h^(−1),W126 increases by greater than 15 ppm h^(−1)in Shaanxi and SCB,and AOT40f increases by 6 ppm h^(−1)in NCP and SCB.The temperature increase also promotes atmospheric oxidation capacity(AOC)levels,with the higher AOC contributed by OH radicals in southern China but by NO_(3)radicals in northern China.The change in the reaction rate caused by the temperature increase has a greater influence on O_(3)exposure and AOC than the change in BVOC emissions.展开更多
基金Supported by National Natural Science Foundation of China(31100359)A Project Funded by the Proiority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)~~
文摘[Objective] The aim was to analyze water and heat fluxes, CO2 fluxes and energy balance in wheat ecosystem in Luancheng County of Hebei Province. [Method] Based on data of water and heat flux, and CO2 fluxes, routine meteorological and biomass data in Luancheng in 2008, water and heat fluxes, CO2 fluxes and energy balance in wheat ecosystem were explored. [Result] The results showed that latent and sensible heat and CO2 fluxes were of obvious daily and seasonal changes; latent and sensible heat fluxes shaped an inverted U in daily change, and CO2 fluxes were of a U-shape; daily flux peak differed significantly. Furthermore, the change of latent heat, sensible heat and CO2 fluxes were closely related to environ- mental factors. Detailedly, the three were sensitive to light intensity and net radiation, and correlation coefficients were 0.92, 0.66, 0.65 and 0.90, 0.69, 0.74, respectively. Besides, the fluxes, sensitive to temperature, proved better in sunny day, especially for latent flux which is more sensitive to water in soils after precipitation. In addition, closure degree of energy balance in wheat fields was 0.91 and non-closure, caused by measurement error and neglection of heat storage, was observed, too. What＇s more. closure degree differed in months and time periods within a day. [Conclusion] The research concluded water and heat fluxes, CO2 fluxes, transport mechanisms and concerning factors, providing scientific reference for revealing mechanism of evapo- ration and heat dissipation of canopy, relationship between photosynthesis and water use efficiencyand energy distribution mechanism.
文摘The current irrational use of fossil fuels and the impact of greenhouse gases on the environment are driving research into renewable energy production from organic resources and waste. The global energy demand is high, and most of this energy is produced from fossil resources. Recent studies report that anaerobic di- gestion （AD） is an efficient alternative technology that combines biofuel production with sustainable waste management, and various technological trends exist in the biogas industry that enhance the production and quality of biogas. Further investments in AD are expected to meet with increasing success due to the low cost of available feedstocks and the wide range of uses for biogas （i.e., for heating, electricity, and fuel）. Bio- gas production is growing in the European energy market and offers an economical alternative for bioenergy production. The objective of this work is to provide an overview of biogas production from lignocellulosic waste, thus providing information toward crucial issues in the biogas economy.
文摘Metal‐organic frameworks(MOFs)are a series of highly porous crystalline materials,which are built from inorganic metal nodes and organic linkers through coordination bonds.Their unique porous structural features(such as high porosity,high surface areas,and highly ordered nanoporous structures)and designable structures and compositions have facilitated their use in gas capture,separation,catalysis,and energy storage and conversion.Recently,the design and synthesis of pure MOFs and their derivatives have opened new routes to develop highly efficient electrocatalysts toward oxygen reduction reactions(ORR)and oxygen evolution reactions(OER),which are the core electrode reactions in many energy storage and conversion techniques,such as metal‐air batteries and fuel cells.This review first discusses recent progress in the synthesis and the electrocatalytic applications of pure MOF‐based electrocatalysts toward ORR or OER,including pure MOFs,MOFs decorated with active species,and MOFs incorporated with conductive materials.The following section focuses on the advancements of the design and preparation of various MOF‐derived materials-such as inorganic nano‐(or micro‐)structures/porous carbon composites,pure porous carbons,pure inorganic nano‐(or micro‐)structured materials,and single‐atom electrocatalysts-and their applications in oxygen electrocatalysis.Finally,we present a conclusion and an outlook for some general design strategies and future research directions of MOF‐based oxygen electrocatalysts.
基金This research was supported by the second Tibetan Plateau Scientific Expedition and Research Program(STEP)[grant number 2019QZKK0604]the National Natural Science Foundation of China[grant numbers 91837311,41705025,and 41705021].
文摘The Tibetan Plateau(TP)is an area sensitive to climate change,where the ozone distribution affects the atmospheric environment of the TP and its surrounding regions.The relatively low total column ozone over the TP in boreal summer and its spatiotemporal variations have received extensive attention.In this study,five-year balloon-borne measurements of ozone over Lhasa in boreal summer are used to investigate the influences of the apparent heat source(Q1)on the ozone vertical structure over the plateau.The mechanisms for the above processes are also explored.The results show that the tropospheric ozone mixing ratio over Lhasa decreases when the total atmospheric Q1 in the troposphere over the TP is relatively high.Strengthened ascending motions are accompanied by enhanced Q1 over the main TP region.Consequently,the tropospheric ozone mixing ratio over Lhasa decreases when Q1 is higher in summer,which is attributed to the upward transport of the ozone-poor surface air.
文摘Silica sources influence different aspects of Al-MCM-41 product. The crystallinity of nanosized Al-MCM-41 zeolites prepared crystallization and lead to change in the properties of the final from precursors mixtures containing different silica sources, e.g. tetraethylorthosilicate （TEOS）, colloidal silica （CS）, silicic acid （SA） and fumed silica （FS） have been studied. The produced samples are investigated using XRD, SEM, FT-IR, pyridine adsorption and N2 physisorption. XRD results show that the products obtained from different silica sources are in Al-MCM-41 phase. SEM results show that silica sources influence the produced Al-MCM-41 shape. Using silicic acid leads to formation of spherical crystals, TEOS gives cubical crystals, colloidal silica forms spherical crystals with smaller aggregated, and fumed silica gives rounded crystals. N2 physisorption results show that silica sources influence pore-diameter and pore-volume of the produced Al-MCM-41 ; the pore diameter of the produced Al-MCM-41 in case of colloidal silica, TEOS, fumed silica, and silicic acid are 12, 20, 15, and 17A respectively. Also, the pore volume of the produced AI-MCM-41 in case of colloidal silica, TEOS, fumed silica and silicic acid are 0.78, 0.71, 0.76, and 0.8 cm^3/gm, respectively.
基金Supported by NSFC project No. 40372066 and SRFDP No. 20030183042
文摘Methane-rich fluids were recognized to be hosted in the reservoir volcanic rocks as primary inclusions. Samples were collected from core-drillings of volcanic gas reservoirs with reversed δ13C of alkane in the Xujiaweizi depression of the Songliao Basin. The volcanic rocks are rhyolite dominant being enriched in the more incompatible elements like Cs, Rb, Ba, Th, U and Th with relative high LREE, depleted HREE and negative anomalies of Ti and Nb, suggesting a melt involving both in mantle source and crustal assimilation. Primary fluids hosted in the volcanic rocks should have the same provenance with the magma. The authors concluded that the enclosed CH4 in the volcanics are mantle/magma-derived alkane and the reversed δ13C of alkane in the corresponding gas reservoirs is partly resulted from mixture between biogenic and abiogenic gases.
文摘Since the nuclear disaster occurred from huge earthquake in Japan 2011, Japanese energy generation system has been expected to prioritize safety and trustworthiness. To meet this requirement, distributed power supply systems are considered to be one of solutions. In this study, we aimed to conserve energy and reduce carbon dioxide emission of supermarket which installed a novel environment-friendly dispersed power. We focused the energy used by refrigerated cabinets. We built small scale model of supermarket which was equipped with dispersed power. From this scale model, the energy conservation effect of supercooling is from 10% to 25% during the summertime and intermediate time. At last, we found that when outside temperature is about 14 ℃ or more, supercooling was effective. In addition, since energy consumption of refrigerated cabinet is influenced by inside enthalpy, we controlled the inside air temperature and humidity by installing desiccant system and examined its effect.
基金supported by the National Natural Science Foundation of China[grant numbers 42277095 and 42021004].
文摘Surface ozone(O_(3))poses significant threats to public health,agricultural crops,and plants in natural ecosystems.Global warming is likely to increase future O_(3)mainly by altering atmospheric photochemical reactions and enhancing biogenic volatile organic compound(BVOC)emissions.To assess the impacts of the future 1.5 K climate target on O_(3)concentrations and ecological O_(3)exposure in China,numerical simulations were conducted using the CMAQ(Community Multiscale Air Quality)model during April-October 2018.Ecological O_(3)exposure was estimated using six indices(i.e.,M7,M24,N100,SUM60,W126,and AOT40f).The results show that the temperature rise increases the MDA8 O_(3)(maximum daily eight-hour average O_(3))concentrations by∼3 ppb and the number of O_(3)exceedance days by 10-20 days in the North China Plain(NCP),Yangtze River Delta(YRD),and Sichuan Basin(SCB)regions.All O_(3)exposure indices show substantial increases.M24 and M7 in eastern and southern China will rise by 1-3 ppb and 2-4 ppb,respectively.N100 increases by more than 120 h in the surrounding regions of Beijing.SUM60 increases by greater than 9 ppm h^(−1),W126 increases by greater than 15 ppm h^(−1)in Shaanxi and SCB,and AOT40f increases by 6 ppm h^(−1)in NCP and SCB.The temperature increase also promotes atmospheric oxidation capacity(AOC)levels,with the higher AOC contributed by OH radicals in southern China but by NO_(3)radicals in northern China.The change in the reaction rate caused by the temperature increase has a greater influence on O_(3)exposure and AOC than the change in BVOC emissions.
