An immobilized Cu2O/g-C3N4 heterojunction film was successfully made on an FTO substrate by electrophoretic deposition of g-C3N4 on a Cu2O thin film.The photoelectrochemical（PEC） performance for water splitting by t...An immobilized Cu2O/g-C3N4 heterojunction film was successfully made on an FTO substrate by electrophoretic deposition of g-C3N4 on a Cu2O thin film.The photoelectrochemical（PEC） performance for water splitting by the Cu2O/g-C3N4 film was better than pure g-C3N4 and pure Cu2O film.Under-0.4 V external bias and visible light irradiation,the photocurrent density and PEC hydrogen evolution efficiency of the optimized Cu2O/g-C3N4 film was-1.38 mA/cm^2 and 0.48 mL h^-1 cm^-2,respectively.The enhanced PEC performance of Cu2O/g-C3N4 was attributed to the synergistic effect of light coupling and a matching energy band structure between g-C3N4 and Cu2O as well as the external bias.展开更多
The authors studied the changes in the electrical properties of PANI （polyaniline） when exposed to the presence of N20 （nitrous oxide）. The techniques used to determine the adsorption of gas in the polymer were th...The authors studied the changes in the electrical properties of PANI （polyaniline） when exposed to the presence of N20 （nitrous oxide）. The techniques used to determine the adsorption of gas in the polymer were the electrochemical impedance, steps voltammetry and transmission electron microscopy. The objective of this work was to determine the ability of adsorption and desorption of PANI to be used as sensor in an open environment. Measurements were performed in a controlled atmosphere, temperature and flux. The gas was passed through a glass capsule in which an electrochemical cell was designed with copper electrodes and PANI as electrolyte. The change in electrical properties of the material is analyzed using a potentiostat/galvanostat in situ. Subsequently, the material was analyzed by TEM （Transmission Electron Microscopy） elemental analysis. The measurements were performed with difl^rent concentrations of N20 with a purity of 99%. As a result of measurements, it was found that the change in electrical resistance of PANI is caused by the physical interaction that occurs when in contact with NzO and even a change in the morphology of polymer, however, the binding is weak and sufficient to increase the temperature at which 25% PANI film regains its original properties.展开更多
基金supported by the National Natural Science Foundation of China (21173088)the Science and Technology Project of Guangdong Province (2014A030312007, 2015A050502012, 2016A010104013)+1 种基金the China Postdoctoral Science Foundation (2016M592493)the Open Research Fund of Hunan Key Laboratory of Applied Environmental Photocatalysis (CCSU-XT-06),Changsha University~~
文摘An immobilized Cu2O/g-C3N4 heterojunction film was successfully made on an FTO substrate by electrophoretic deposition of g-C3N4 on a Cu2O thin film.The photoelectrochemical（PEC） performance for water splitting by the Cu2O/g-C3N4 film was better than pure g-C3N4 and pure Cu2O film.Under-0.4 V external bias and visible light irradiation,the photocurrent density and PEC hydrogen evolution efficiency of the optimized Cu2O/g-C3N4 film was-1.38 mA/cm^2 and 0.48 mL h^-1 cm^-2,respectively.The enhanced PEC performance of Cu2O/g-C3N4 was attributed to the synergistic effect of light coupling and a matching energy band structure between g-C3N4 and Cu2O as well as the external bias.
文摘The authors studied the changes in the electrical properties of PANI （polyaniline） when exposed to the presence of N20 （nitrous oxide）. The techniques used to determine the adsorption of gas in the polymer were the electrochemical impedance, steps voltammetry and transmission electron microscopy. The objective of this work was to determine the ability of adsorption and desorption of PANI to be used as sensor in an open environment. Measurements were performed in a controlled atmosphere, temperature and flux. The gas was passed through a glass capsule in which an electrochemical cell was designed with copper electrodes and PANI as electrolyte. The change in electrical properties of the material is analyzed using a potentiostat/galvanostat in situ. Subsequently, the material was analyzed by TEM （Transmission Electron Microscopy） elemental analysis. The measurements were performed with difl^rent concentrations of N20 with a purity of 99%. As a result of measurements, it was found that the change in electrical resistance of PANI is caused by the physical interaction that occurs when in contact with NzO and even a change in the morphology of polymer, however, the binding is weak and sufficient to increase the temperature at which 25% PANI film regains its original properties.
