A new high energetic density material,N-acetyl-3,3-dinitroazetidine(ADNAZ),was synthesized with advantages as low melting point,high density,insensitive to detonation on impact and forming a eutectic with TNAZ which c...A new high energetic density material,N-acetyl-3,3-dinitroazetidine(ADNAZ),was synthesized with advantages as low melting point,high density,insensitive to detonation on impact and forming a eutectic with TNAZ which can be shaped charge antitank weapons or be used energetic carrier for higher melting meaterial such as HMX and the like.ADNAZ was synthesized by a five-steps reaction,using nitromethane,paraformaldehyde and tert-butylamine etc.as starting materials,with overall yield of 42.8%.Some factors affecting yield of ADNAZ was also discussed.The structures of intermediates and ADNAZ were confirmed by IR,HNMR,CNMR and MS.展开更多
基金supported by the National Natural Science Foundation of China(20573098)Science and Technology Foundation of the National Defense Key Laboratory of Propellant and Explosive Combustion in China(9140C3501020901)~~
文摘A new high energetic density material,N-acetyl-3,3-dinitroazetidine(ADNAZ),was synthesized with advantages as low melting point,high density,insensitive to detonation on impact and forming a eutectic with TNAZ which can be shaped charge antitank weapons or be used energetic carrier for higher melting meaterial such as HMX and the like.ADNAZ was synthesized by a five-steps reaction,using nitromethane,paraformaldehyde and tert-butylamine etc.as starting materials,with overall yield of 42.8%.Some factors affecting yield of ADNAZ was also discussed.The structures of intermediates and ADNAZ were confirmed by IR,HNMR,CNMR and MS.
