缸内直喷氢气对发动机燃烧及排放的影响

为探索氢发动机热效率提升及超低氮氧化物排放的技术路径,基于一台1.5 L缸内直喷氢气发动机,结合废气涡轮增压及电子增压复合技术,通过试验研究了氢气在稀薄燃烧及超稀薄燃烧模式下发动机燃烧和排放的变化规律。结果表明:在稀燃模式下,随着混合气稀释程度增大,缸内压力越来越高并前移,放热率峰值逐渐下降同时放热始点提前和放热时长变长,缸内燃烧温度下降,燃烧滞燃期和持续期逐渐变长,压升率下降;λ对NO_(x)排放的影响显著,λ=1.2时NO_(x)排放达到峰值,λ>2.5时,NO_(x)排放基本趋于0;在同样的负荷,较稀的混合气的热效率更高且NO_(x)排放更低,有效热效率达43%;全负荷时,随着λ趋向于1,扭矩逐渐升高,爆发压力和压升率也会明显上升。

直喷氢内燃机实现NO_(x)近零排放的试验研究

缸内混合气分布不均匀、燃烧温度高等原因,直喷氢内燃机的氮氧排放水平很高。为探索降低直喷氢内燃机NO_(x)排放的控制方法,该文基于一台2.0 L自然吸气直喷氢内燃机,通过试验研究了过量空气系数、转速、点火角和喷氢压力对NO_(x)排放的影响,并通过多参数的耦合调节,控制NO_(x)排放,得到了样机的最大动力性下,未经后处理就实现近零排放(NO_(x)≤20×10^(-6))工作边界。研究表明:通过稀燃和推迟点火角,可以在牺牲少量热效率和燃烧稳定性的同时大幅降低NO_(x)排放;近零排放工作区域的最大功率为21.5 kW,最高热效率为39%,在此区域内的所有工况点都可以实现近零排放。

切向燃煤锅炉新型低氮燃烧器的开发

在前墙燃烧锅炉中 ,通过高温还原火焰和火焰稳定技术已可使NOX 排放量降到很低的程度 ,并已在切向燃烧中得到了应用。该技术与燃尽风系统相结合可得到更高的脱氮效率 ,同时飞灰中未燃炭的含量仍然可以保持很低。这种低氮燃烧器的脱氮效率为 5 0 %～ 80 % ,在实际运行的锅炉上使用时NOX(以NO2 计 )排放量可降低到 5 0～70mg/MJ。该技术不仅用于燃烟煤的锅炉 。

先进再燃脱硝优化试验与机理分析

我国是世界上的煤炭生产大国,更是煤炭使用大国。在我国电力生产过程中,以火力发电为主。在火力发电发电所用的煤炭消耗量接近全国煤炭消耗量的50%。因此,煤炭的使用量的高居不下也导致了大量的废气的污染,本文就如何减少氮氧排放物为中心对先进再燃脱硝优化试验与机理分析。

关于降低1000MW机组低负荷段脱硝系统退出次数的研究

火电厂脱硝系统的正常稳定运行是控制氮氧排放的重要保证。针对脱硝装置采用选择性催化还原技术(SCR)的两台1000MW机组在低负荷段时脱硝系统频繁退出的现状,结合脱硝系统设备和运行管理,并配合相关专业分析得出脱硝系统频繁退出的主要原因是SCR入口烟温低,且导致该现象主要原因为动力场分布不均、磨煤机运行方式不匹配、再热器挡板开度小和制粉系统设备可靠性差。创新提出了"调偏、提火、开挡板、监视参数,规范值班"有效解决方案,减少脱硝系统误退次数。通过观察方案实施后脱硝系统误退次数大幅降低,有效减少了氮氧化物的排放。

Analysis of Prese nt Operating Situati on of Large Size Coal-F ired Utility Boilers

Large size utility boilers develop rapidly in China, both their reliability and economics have reached better level. The operating situations of various existing boilers on the basis of different coals are analyzed, it is held that, the notable energy imbalance of furnace exit, ever existing in the tangential firing boilers has been solved, with comparatively lower NOX emission concentration of gained. The higher NOX emission concentration and furnace slagging etc. problems existing in wall firing boilers are notable. The comprehensive analysis shows that, it is appropriate to choose lower furnace volume heat release rate and higher flame height in the type selection design of boilers, and sufficient margin should be kept in the selection of coal pulverizing mills.

Advances in Greenhouse Gases Emission in Farmland Soils

[Objective] The aim was to overview the emission of greenhouse gases in farmland. [Method] Based on domestic and foreign references, production mechanism, discharging characters and major influential factors of CO2, CH4 and N2O in soils of farmland were overviewed. [Result] Production and discharge of CO2, CH. and N2O played an important role in circulation of carbon and nitrogen in terrestrial ecosystem and constituted a key method for carbon and nitrogen output. It is significant to conduct research on reduction of greenhouse gas and increase of absorption. [Conclusion] The research is beneficial for exploration on discharge rule and influential factors of greenhouse gases, providing theoretical references for reduction of greenhouse gases and study on climate change.

Operational Options for Green Ships

Environmental issues and rising fuel prices necessitate better energy-etlicwncy in all sectors, The shipping industry is one of the major stakeholders, responsible for 3% of global CO2 emissions, 14%-15% of global NOx emissions, and 16% of global SOx emissions. In addition, continuously rising fuel prices are also an incentive to focus on new ways for better energy-effectiveness. The green ship concept requires exploring and implementing technology on ships to increase energy-efficiency and reduce emissions. Ship operation is an important topic with large potential to increase cost-and-energy-effectiveness. This paper provided a comprehensive review of basic concepts, principles, and potential of operational options for green ships. The key challenges pertaining to ship crew i.e. academic qualifications prior to induction, in-service training and motivation were discussed. The author also deliberated on remedies to these challenges.

N Cycle, N Flow Trends in Japan, and Strategies for Reducing N_2O Emission and NO_3^- Pollution

To feed an increasing population, large amounts of chemical nitrogen fertilizer have been used to produce much of our food, feed and fiber thereby increasing nitrogen levels in soils, natural waters, crop residues, livestock wastes,and municipal and agricultural wastes, with national and international concern about its potential adverse effects on environmental quality and public health. To understand these phenomena and problems, first the nitrogen cycle and the environment are described. Then recent trends for nitrogen cycling through the food and feed system, N2O emissions from fertilized upland and paddy soils, and NO-3 pollution in ground water in Japan are reported. Finally, mitigation strategies in Japan for reducing N2O emission and NO-3 pollution are proposed, including nitrification inhibitors, controlled release fertilizers, utilization of plant species that could suppress nitrification, utilizing the toposequence, government policy, and appropriate agricultural practices. Of all the technologies presented, use of nitrification inhibitors and controlled release fertilizers are deemed the most important with further development of these aspects of technologies being expected. These practices, if employed worldwide, could help reduce the load, or environmental deterioration, on the Earth's biosphere.

Anthropogenic Direct Radiative Forcing of Tropospheric Ozone and Aerosols in 1850 and 2000 Estimated with IPCC AR5 Emissions Inventories

This study estimates direct radiative forcing by tropospheric ozone and all aerosols between the years 1850 and 2000, using the new IPCC AR5 （the Intergovernmental Panel on Climate Change Fifth Assessment Report） emissions inventories and a fully coupled chemistry-aerosol general circulation model. As compared to the previous Global Emissions Inventory Activity （GEIA） data, that have been commonly used for forcing estimates since 1990, the IPCC AR5 emissions inventories report lower anthropogenic emissions of organic carbon and black carbon aerosols and higher sulfur and NOx emissions. The simulated global and annual mean burdens of sulfate, nitrate, black carbon （BC）, primary organic aerosol （POA）, secondary organic aerosol （SOA）, and ozone were 0.79, 0.35, 0.05, 0.49, 0.34, and 269 Tg, respectively, in the year 1850, and 1.90, 0.90, 0.11, 0.71, 0.32, and 377 Tg, respectively, in the year 2000. The estimated annual mean top of the atmosphere （TOA） direct radiative forcing of all anthropogenic aerosols based on the AR5 emissions inventories is -0.60 W m^-2 on a global mean basis from 1850 to 2000. However, this is -2.40 W m-2 when forcing values are averaged over eastern China （18-45°N and 95-125°E）. The value for tropospheric ozone is 0.17 W m^-1 on a global mean basis and 0.24 W m^-2 over eastern China. Forcing values indicate that the climatic effect of aerosols over eastern China is much more significant than the globally averaged effect.

Nitric Oxide Emission Following Wetting of Dry Soils in Subtropical Humid Forests

Information about soil nitric oxide （NO） emissions from subtropical forests is quite limited, and even less is known about the pulse emission of NO when wetting soils after a long period of dryness. In this study, we measured NO fluxes following wetting of dry soft in a broadleaf forest and a pine forest in subtropical China. Large pulses of NO fluxes were observed after soil wetting in both forests. NO fluxes increased significantly within 0.5 h following wetting in both forests and reached peak 1 and 4 h after soil wetting in the pine forest and the broadleaf forest, respectively. In the broadleaf forest, averaged peak flux of NO pulses was 157 ng N m^-2 s^-1, which was 8 times the flux value before wetting, and in the pine forest, the averaged peak flux was 135 ng N m-2 s 1, which was 15.5 times the flux value before wetting. The total pulses-induced NO emissions during the dry season were roughly estimated to be 29.4 mg N m^-2 in the broadleaf forest and 22.2 mg N m^-2 in the pine forest or made up a proportion of 4.6% of the annual NO emission in the broadleaf forest and 5.3% in the pine forest.

Biomass gasification and Polish coal-fired boilers for process of reburning in small boilers

Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out using an integrated system consisting of the boiler and a fixed-bed 60 kW (GazEla) gasification reactor.The process gas was continuously introduced above the coal burner of the boiler.The process parameters of the boiler and the gasifier were also measured and compared with the other units.Characteristic NOx emissions from automatic and manually operated boilers were also presented.

The correlation between nitrogen species in coke and NO_x formation during regeneration

Nitrogen oxides （NOx） emission during the regeneration ofcoked fluid catalytic cracking （FCC） catalysts is an en- vironmental issue. In order to identify the correlations between nitrogen species in coke and different nitrogen- containing products in tail gas, three coked catalysts with multilayer structural coke molecules were prepared in a fixed bed with model compounds （o-xylene and quinoline） at first. A series of characterization methods were used to analyze coke, including elemental analysis, FT-IR, XPS, and TG-MS. XPS characterization indicates all coked catalysts present two types of nitrogen species and the type with a higher binding energy is related with the inner part nitrogen atoms interacting with acid sites. Due to the stronger adsorption ability on acid sites for basic nitrogen compounds, the multilayer structural coke has unbalanced distribution of carbon and ni- trogen atoms between the inner part and the outer edge, which strongly affects gas product formation. At the early stage of regeneration, oxidation starts from the outer edge and the product NO can be reduced to N2 in high CO concentration. At the later stage, the inner part rich in nitrogen begins to be exposed to 02. At this period, the formation of CO decreases due to lack of carbon atoms, which is not beneficial to the reduction of NO. There- fore, nitrogen species in the inner part of multilayer structural coke contributes more to NOx formation. Based on the multilayer structure model of coke molecule and its oxidation behavior, a possible strategy to control NOx emission was discussed merely from concept.

Effect of exhaust gas recirculation and intake pre-heating on performance and emission characteristics of dual fuel engines at part loads

Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an experimental investigation conducted on a dual fuel(diesel-natural gas) engine to examine the simultaneous effect of inlet air pre-heating and exhaust gas recirculation(EGR) ratio on performance and emission characteristics at part loads.The use of EGR at high levels seems to be unable to improve the engine performance at part loads.However,it is shown that EGR combined with pre-heating of inlet air can slightly increase thermal efficiency,resulting in reduced levels of both unburned hydrocarbon and NOx emissions.CO and UHC emissions are reduced by 24% and 31%,respectively,The NOx emissions decrease by 21% because of the lower combustion temperature due to the much inert gas brought by EGR and decreased oxygen concentration in the cylinder.

Applicability of an eddy covariance system based on a close-path quantum cascade laser spectrometer for measuring nitrous oxide fluxes from subtropical vegetable fields

The soil of subtropical vegetable fields is an important source of the atmospheric greenhouse gas nitrous oxide（N2O）. In a field study in subtropical China, the authors used an eddy covariance（EC）system based on a close-path quantum cascade laser（QCL） spectrometer to measure N2O fluxes from a vegetable field. During the experimental period from 9 October 2014 to 18 February 2015,the observed half-hourly N2O fluxes ranged from.10.7 to 1077.4 μg N m^-2h^-1, with a mean value of99.3 μg N m^-2h^-1. The detection limit（95% confidence level） of the EC system for half-hourly fluxes was estimated at 18.5 μg N m^-2h^-1, i.e. smaller than 97.5% of all measured fluxes, and within the range of the lower limit of reported N2O emissions from subtropical vegetable fields. The random uncertainties in the half-hourly fluxes were estimated at 60% on average, of which 62% was due to stochastic variations caused by turbulence and 38% by instrumental noise. The flux systematic uncertainties were estimated at.18% on average, mainly due to the spectral attenuation; however,this negative bias had already been corrected for by calculating half-hourly fluxes. In conclusion,the close-path QCL-based EC technique is capable of measuring the N2O fluxes from the subtropical vegetable fields of China with high reliability and accuracy.

Thermo economic evaluation of oxy fuel combustion cycle in Kazeroon power plant considering enhanced oil recovery revenues

Oxy fuel combustion and conventional cycle(currently working cycle) in Kazeroon plant are modeled using commercial thermodynamic modeling software. Economic evaluation of the two models regarding the resources of transport and injection of carbon dioxide into oil fields at Gachsaran for enhanced oil recovery in the various oil price indices is conducted and indices net present value(NPV) and internal rate of return on investment(IRR) are calculated. The results of the two models reveal that gross efficiency of the oxy fuel cycle is more than reference cycle(62% compared to 49.03%), but the net efficiency is less(41.85% compared to 47.92%) because of the high-energy consumption of the components, particularly air separation unit(ASU) in the oxy fuel cycle. In this model, pure carbon dioxide with pressure of 20×105 Pa and purity of 96.84% was captured. NOX emissions also decrease by 4289.7 tons per year due to separation of nitrogen in ASU. In this model, none of the components of oxy fuel cycle is a major engineering challenge. With increasing oil price, economic justification of oxy fuel combustion model increases. With the price of oil at $ 80 per barrel in mind and $ 31 per ton fines for emissions of carbon dioxide in the atmosphere, IRR is the same for both models.

Response of N_2O Emissions of Farmland Ecosystem on Temperature Rising

[Objective] The aim was to study on response of N2O emissions of farm- land ecosystem on temperature rising. [Methed] In farmland ecosystem in Huaibei City in Anhui Province, N2O emission by twelve varieties of crop on temperature was researched with DeNitrification-DeComposition （NDC）. [Result] Response of dry- land crop on temperature rising can be divided into three categories, as follows： The first category, N2O emission of crop changed little during the temperature increasing, for example, from 0 to 3 %;, the emissions by potatoes, cotton, maize and rapeseed increased little and decreased little when temperature changed from 1.5 to 3 ℃. Crops of the second category declined with temperature increasing in N2O emission, for example, N2O emission decreased by 8.1% with temperature increasing from 0 to 3 ℃, including sugar cane, tobacco, wheat, soybean and pea. In third category, N2O emission of crop grew with temperature increasing, for example, the emission of rice, vegetables and fruit trees increased by 22.8% when the temperature grew from 0 to 3 ℃. [Conclusion] The research indicated that N2O emission in ecosystem of drv farmland increased little with temoerature risina.

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice

The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing＇the decomposition＇of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level.Thus the zero release ofnitrogen ox!de waste gas can be achieved without using any absorption process.

Projected Changes in NO_x Emissions from Lightning as a Result of 2000–2050 Climate Change

Lightning is one of the most important natural sources of atmospheric NOx.The authors investigate the2000–2050 changes in NOx emissions from lightning using the global three-dimensional Goddard Earth Observing System chemical transport model(GEOS-Chem)driven by meteorological fields from the Goddard Institute for Space Studies(GISS)general circulation model(GCM)3.Projected changes in climate over 2000–2050are based on the Intergovernmental Panel on Climate Change(IPCC)A1B scenario.The global NOx emission from lightning is simulated to be 4.8 Tg N in present day and to increase by about 16.7%over 2000–2050 as a result of the future climate change.The largest present-day emissions and climate-induced changes are found in the upper troposphere in the tropics.Regionally in eastern China(20–55 N,98–125 E),NOx emissions from lighting is simulated to be 0.3 Tg N(6.3%of the global total emission)in present day and to increase by 26.7%over2000–2050.The simulated changes in NOx from lightening correspond well with the projected future changes in convective precipitation.

Conceptual Design of a Butyl-levulinate Reactive Distillation Process by Incremental Refinement

Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butanol and levulinic acid, which themselves are platform chemicals in a biorenewables-based chemical supply chain. Since the equilibrium of esterification limits the conversion in a conventional reactor, reactive distillation can be applied to overcome this limitation. The presence of the high-boiling catalyst sulfuric acid requires a further separation step downstream of the reactive distillation column to recover the catalyst for recycle. Optimal design specifications and an optimal operating point are determined using rigorous flowsheet optimization. The challenging optimization problem is solved by a favorable initialization strategy and continuous reformulation. The design identified has the potential to produce a renewable transportation fuel at reasonable cost.