The molar dissolution enthalpy of the reactants and the products of the coordination reaction of Samarium Chloride with Glycine have been measured by isoperibol solution calorimetry, the calorimetric solvent is 2mol. ...The molar dissolution enthalpy of the reactants and the products of the coordination reaction of Samarium Chloride with Glycine have been measured by isoperibol solution calorimetry, the calorimetric solvent is 2mol. L-l HCI solution. The standard molar reaction enthalpy (298. 2K) is -7. 3381kJ· mol - 1. From the results and other auxiliary quantities, the standard molar enthalpy of formation of the new coordination compound has been calculated to be (Sm(Cly)3C13. 3H2O, s, 298. ZK) = - 3631. 74kJ · mol- 1.展开更多
文摘The molar dissolution enthalpy of the reactants and the products of the coordination reaction of Samarium Chloride with Glycine have been measured by isoperibol solution calorimetry, the calorimetric solvent is 2mol. L-l HCI solution. The standard molar reaction enthalpy (298. 2K) is -7. 3381kJ· mol - 1. From the results and other auxiliary quantities, the standard molar enthalpy of formation of the new coordination compound has been calculated to be (Sm(Cly)3C13. 3H2O, s, 298. ZK) = - 3631. 74kJ · mol- 1.