In this work the diffusion coefficients of Na+, K+, Ca2+, NO3- and Cl- ions were estimated in terms of measuring apparent direct current (DC) conductivities of latosol, red soil and yellow-brown earth containing, resp...In this work the diffusion coefficients of Na+, K+, Ca2+, NO3- and Cl- ions were estimated in terms of measuring apparent direct current (DC) conductivities of latosol, red soil and yellow-brown earth containing, respectively, NaNO3, KCI, and CaCl2 of different concentrations (0.005, 0.05, 0.10, and 0.15 mol / L) in the case of moisture contents ranging from wet to water saturation. The results showed that when bulk density, moisture content, and electrolyte concentration were constant, the diffusion coefficients of cations were in the order Na+> K+> Ca2+ except for Na+ and K+ in latosol, while the order for anions was NO3- > Cl-. The diffusion coefficients (Di) of cations and anions were linearly proportional to volumetric moisture content (θ) as electrolyte concentration and bulk density were unchanged. When moisture content and bulk density were constant, the diffusion coefficients of cations decreased, to varying extents, with the increase of electrolyte concentration, and the decrement in different soils followed the order yellow-brown earth > red soil > latosol, but the decrement order of different cations was Na+> K+ > Ca2+.展开更多
The adsorption characteristics of cationic polyelectrolyte poly dimethyl diallyl ammonium chloride （PDADMAC） and anionic polyelectrolyte poly （sodium-p-styrenesulfonate） （PSS） on benzoguanamine formal- dehyde （...The adsorption characteristics of cationic polyelectrolyte poly dimethyl diallyl ammonium chloride （PDADMAC） and anionic polyelectrolyte poly （sodium-p-styrenesulfonate） （PSS） on benzoguanamine formal- dehyde （BGF） particles are investigated. The charging characteristics of BGF particles are changed and con- trolled using electrostatic self-assembly method. A variety of PE,-BGF/SiO2 composite abrasives are obtained. The as-prepared samples are analyzed by zeta potential analysis, transmission electron microscope （TEM） and thermogravimetric （TG） analysis. The composite abrasive slurries are prepared for copper polishing. The poli- shing results indicate that it is SiO2 abrasives, not only coated SiO2 abrasive on polymer particles but also free SiO2 abrasive in slurry, that offer the polishing action. The material removal rates of copper polishing are 264 nm/min, 348 nm/min and 476 nm/min using single SiO2 abrasive slurry, PE0-BGF/SiO2 mixed abrasive slur- ry and PE3-BGF/SiO2 composite abrasive slurry, respectively. The surface roughness Ra of copper wafer （with 5μm×5μm district） is decreased from 0.166 μm to 3.7 nm, 2.6 nm and 1.5 nm, and the surface peak-valley values Rrv are less than 20 nm, 14 nm and 10 nm using these kinds of slurries, respectively. Key words ： chemico-mechanical polishing; polishing slurry; composite abrasives ; polyelectrolyte ; copper展开更多
High quality micro-Raman spectra of the LiClO4 droplet with mass of nanogram scale were obtained at various concentrations from dilute to supersaturated state. From component band analysis of the v1-ClO4^- band, four ...High quality micro-Raman spectra of the LiClO4 droplet with mass of nanogram scale were obtained at various concentrations from dilute to supersaturated state. From component band analysis of the v1-ClO4^- band, four peaks at 933.3, 936.8, 942.1 and 950.7 cm^-1 were identified and assigned to free solvated perchlorate anion, solvent-shared ion pair, contact ion pair and com- plex ion aggregates, respectively. As expected, the signature of free solvated CIO4 ion was observed to decrease in intensity with the increase in concentration. The intensity of the signature from solvent-shared ion pair was observed to rise with in- crease in concentration from 1.8 mol/kg to 5.0 mol/kg before decreasing as the concentration was further increased to 5.6 mol/kg. Signatures of contact ion pair and of complex ion aggregates were shown to increase as the concentration was enhanced. Based upon the Eigen mechanism, we show that three association equilibria can be used to describe the transfor- mations between free solvated perchlorate anion, solvent-shared ion pair, contact ion pair and complex ion aggregates. The overall association constant, K, and the stepwise association constants Ki （i = 1 to 3） in the Eigen mechanism were determined separately with values of 0.025 ± 0.003, 0.023 ± 0.002, 0.068 ± 0.033 and 0.686 ± 0.174. Based on these constants, the electronic performance can be reasonably predicted by the optimum choice of electrolyte concentrations.展开更多
文摘In this work the diffusion coefficients of Na+, K+, Ca2+, NO3- and Cl- ions were estimated in terms of measuring apparent direct current (DC) conductivities of latosol, red soil and yellow-brown earth containing, respectively, NaNO3, KCI, and CaCl2 of different concentrations (0.005, 0.05, 0.10, and 0.15 mol / L) in the case of moisture contents ranging from wet to water saturation. The results showed that when bulk density, moisture content, and electrolyte concentration were constant, the diffusion coefficients of cations were in the order Na+> K+> Ca2+ except for Na+ and K+ in latosol, while the order for anions was NO3- > Cl-. The diffusion coefficients (Di) of cations and anions were linearly proportional to volumetric moisture content (θ) as electrolyte concentration and bulk density were unchanged. When moisture content and bulk density were constant, the diffusion coefficients of cations decreased, to varying extents, with the increase of electrolyte concentration, and the decrement in different soils followed the order yellow-brown earth > red soil > latosol, but the decrement order of different cations was Na+> K+ > Ca2+.
基金Natural Science Foundation of Zhejiang Province(No.Z1080625)
文摘The adsorption characteristics of cationic polyelectrolyte poly dimethyl diallyl ammonium chloride （PDADMAC） and anionic polyelectrolyte poly （sodium-p-styrenesulfonate） （PSS） on benzoguanamine formal- dehyde （BGF） particles are investigated. The charging characteristics of BGF particles are changed and con- trolled using electrostatic self-assembly method. A variety of PE,-BGF/SiO2 composite abrasives are obtained. The as-prepared samples are analyzed by zeta potential analysis, transmission electron microscope （TEM） and thermogravimetric （TG） analysis. The composite abrasive slurries are prepared for copper polishing. The poli- shing results indicate that it is SiO2 abrasives, not only coated SiO2 abrasive on polymer particles but also free SiO2 abrasive in slurry, that offer the polishing action. The material removal rates of copper polishing are 264 nm/min, 348 nm/min and 476 nm/min using single SiO2 abrasive slurry, PE0-BGF/SiO2 mixed abrasive slur- ry and PE3-BGF/SiO2 composite abrasive slurry, respectively. The surface roughness Ra of copper wafer （with 5μm×5μm district） is decreased from 0.166 μm to 3.7 nm, 2.6 nm and 1.5 nm, and the surface peak-valley values Rrv are less than 20 nm, 14 nm and 10 nm using these kinds of slurries, respectively. Key words ： chemico-mechanical polishing; polishing slurry; composite abrasives ; polyelectrolyte ; copper
基金supported by the National Natural Science Foundation of (41175119 20933001 and 20873006)+3 种基金the National Key Program for Basic Research of China (2009CB220100) the 111 Project B07012the Trans-Century Training Program Foundation for the Talentsalso supported by a grant-in-aid for Youth Innovation Fund from Central South University of Forestry and Technology (104︱0261)
文摘High quality micro-Raman spectra of the LiClO4 droplet with mass of nanogram scale were obtained at various concentrations from dilute to supersaturated state. From component band analysis of the v1-ClO4^- band, four peaks at 933.3, 936.8, 942.1 and 950.7 cm^-1 were identified and assigned to free solvated perchlorate anion, solvent-shared ion pair, contact ion pair and com- plex ion aggregates, respectively. As expected, the signature of free solvated CIO4 ion was observed to decrease in intensity with the increase in concentration. The intensity of the signature from solvent-shared ion pair was observed to rise with in- crease in concentration from 1.8 mol/kg to 5.0 mol/kg before decreasing as the concentration was further increased to 5.6 mol/kg. Signatures of contact ion pair and of complex ion aggregates were shown to increase as the concentration was enhanced. Based upon the Eigen mechanism, we show that three association equilibria can be used to describe the transfor- mations between free solvated perchlorate anion, solvent-shared ion pair, contact ion pair and complex ion aggregates. The overall association constant, K, and the stepwise association constants Ki （i = 1 to 3） in the Eigen mechanism were determined separately with values of 0.025 ± 0.003, 0.023 ± 0.002, 0.068 ± 0.033 and 0.686 ± 0.174. Based on these constants, the electronic performance can be reasonably predicted by the optimum choice of electrolyte concentrations.
