流域水土环境污染跨介质治理策略

污染物在流域水土环境中存在复杂的源汇关系,在水土环境中的转化作用主要受控于各种水‒土界面过程,为此,水土环境污染治理需将水土环境作为一个整体,通过跨介质归因识别找到真正的污染源,然后进行跨介质治理。本文首先分析了污染物在流域水土环境中的跨水‒土介质迁移过程以及主要影响因素,在此基础上提出了流域水土环境跨介质调控原理及关键过程,主要包括流域水土环境污染跨介质归因识别和流域水土环境污染跨介质治理。同时,重点阐述了污染物在河道外的土壤‒水界面、坡面‒河道界面,河道内的水‒沉积物界面(包括河床潜流带和侧向岸边潜流带的水‒固界面)和水‒悬浮颗粒物界面过程在跨介质去除中的重要作用,并采用实际案例阐述了流域非点源污染物的跨介质控制、河流含氮化合物的跨介质去除以及湖泊氮磷的跨介质去除方法等。研究结果可为流域水土环境污染防治提供科学依据。

Analysis of heat pulse signals determination for sediment-water interface fluxes

The heat pulse signal is analyzed in a new way with the goals of clarifying the relationships between the variables in the heat transfer problem and simplifying the procedure for calculating sediment-water interface fluxes J. Only three parameters x0 λand pc l are needed to calculate J by the heat pulse data for this analysis method.The results show that there is a curvilinear relationship between the peak temperature arrival time and sediment-water interface fluxes and there exists a simple linear relationship between sediment-water interface fluxes and the natural log of the ratio of the temperature increase downstream from the line heat source to the temperature increase upstream from the heat source.The simplicity of this relationship makes the heat pulse sensors an attractive option for measuring soil water fluxes.

Phosphorus Behavior at Sediment-Water Interface in Coastal Wetland

[Objective] The aim was to explore the role of coastal wetlands in phosphorus fixation in the Yellow River Delta.[Method] The research analyzed phosphorus behavior at sediment-water interface by static water column test. [Result] The research concluded that phosphorus concentration was in the range of 0.051-0.322 mg/L in overlying water, and phosphorus was effectively removed by degradation and adsorption. The static water column test has demonstrated that phosphorus concentration of coastal wetlands plays the role of accumulation when phosphorus concentration is lower than 7 mg/L in overlying water of coastal wetlands. It is notable that substrates of overlying water all perform well in adsorption, and the adsorption reaches saturation if the concentration goes up to 10 mg/L. [Conclusion] Coastal wetlands would significantly adsorb and degrade phosphorus in overlying water, controlling phosphorus within a lower range.

In situ measurements of benthic oxygen fluxes in Hui-quan Bay of Qingdao by eddy correlation techniques:short term pattern variations in gravel beach

The oxygen fluxe across the sediment-water interface(SWI)in coastal region is a key measure to fully understand the regulation of biogeochemical cycles in an aquatic environment.However,studies on fluxes of dissolved oxygen in gravel beach are limited,because of the difficulty in sample collection and instrumentations deployment.In this study,benthic oxygen fluxes across rocky substratum in an intertidal zone of Huiquan Bay was estimated by using noninvasive eddy correlation techniques.A total of 10 burst measurements were analyzed.The oxygen flux fluctuated from-5.7888±2.6 to+49.3344±2.6 mmol O2 m-2/d were observed.The cospectra analysis showed that the oxygen flux at the frequency band between 0.093 and 0.279 Hz(at a period from 3.58 to 10.75 s)contributed 50.19%to the total spectrum on average.The results showed that the major contribution band moved to the high frequency region gradually and reached a steady state with increasing tidal flood.It is demonstrated that wave movement and wave breaking interaction resulted in the change of oxygen flux between gravel beach and shallow waters at the start and the end of a rising tide period,respectively.The eddy correlation techniques offer an efficient means for flux measurement over a gravel or mixed sand and gravel beaches.

Phosphorus Fractions in Water and Sediment and Their Correlations in Hengshui Lake, China

Sediment is a principal reservoir which accumulates and releases the pollutants. It is an important way of nutrients releasing from pore water of sediments to overlying water across the sediment-water interface. Five sampling sites were selected in the Hengshui Lake. Overlying water and sediments were collected in each of them. The phosphorus fractions and their relationships were analyzed. The results showed that the change of the total phosphorus （TP） in sediment was similar to that of the total dissolved phosphorus （TDP） and soluble orthophosphate （PO4^3-） in pore water. The concentrations of PO4^3- in pore water were higher than those in overlying water, reflecting a possible diffuse trend for PO4^3-P in the five zones of Hengshui Lake. It is indicated that phosphorus and other nutrients will be transferred from sediment to pore water and then to overlying water, which can lead to lake eutrophication.

The mechanisms of contaminants release due to incipient motion at sediment-water interface

Sediments in many rivers and lakes are subjected to resuspension due to a combination of hydrodynamics. However, the roles of contaminant-contained dissolved and particulate sediments during the resuspension release are rarely studied. This study focuses on the release quantity of contaminants in both water phase and solid phase. Conservative tracer （NaC1） and reactive tracer （Phosphorus） were respectively added to cohesive fine-grained sediments and non-cohesive coarse-grained sediments. A range of typical shear stress was conducted to characterize the time-depended release of contaminants in a laboratory flume. When the sediment started to move, the concentration of contaminant in the overlying water increased with the bed shear stress, but the dissolved contaminants responded faster than the particulate ones. The observed contaminant release process can be divided into three main stages： the initial two hours fast mixing： the release contribution of pore water could reach up to 75%; the middle 4-6 h adsorption： the partitioning coefficient of contaminant between water phase and solid phase decreased over the time, and the adsorption of contaminates from resuspended sediment dominated the negative release; the last equilibrium stage： the desorption and adsorption reached equilibrium, and the reactive contaminant made an impact on the water quality in the solid phase. The existing formulas to evaluate the release flux are far from practice meaning as the sediment contaminants undergo a very complex release process.