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火焰原子吸收法测定水中铜的测量不确定度评定 被引量:1
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作者 赵越 《黑龙江科技信息》 2012年第24期10-10,共1页
根据火焰原子吸收法测定水中的铜,分析主要的测量不确定度来源,分别量化后合成铜的测量不确定度。
关键词 火焰原子吸收法 水中铜 不确定度
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石墨炉原子吸收分光光度法测定清洁水中铜铅镉的方法研究 被引量:3
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作者 辛瑞瑞 张普及 《甘肃科技》 2021年第16期37-39,共3页
建立了石墨炉原子吸收分光光度法测定清洁水中铜铅镉的分析方法,优化了仪器条件,通过检出限、精密度、准确度的测试,验证了该方法在分析清洁水中铜铅镉元素的准确性、适用性和有效性。
关键词 清洁水中铜铅镉 石墨炉 测定
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催化动力学法快速测定饮水中痕量铜
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作者 卜志辉 《浙江预防医学》 1995年第4期61-62,共2页
饮水中铜含量一般都在ppb级,所以用国标化学法难于测出,需用石墨炉原子吸收分光光度法,可测至0.5ppb,但仪器昂贵。本法利用铜(Ⅱ)在氨性条件下催化过氧化氢氧化亚甲蓝的褪色反应,测定范围0~25ppb,速度快,操作简单,可作为测定水中痕... 饮水中铜含量一般都在ppb级,所以用国标化学法难于测出,需用石墨炉原子吸收分光光度法,可测至0.5ppb,但仪器昂贵。本法利用铜(Ⅱ)在氨性条件下催化过氧化氢氧化亚甲蓝的褪色反应,测定范围0~25ppb,速度快,操作简单,可作为测定水中痕量铜的方法之一。 一、原理 在氨性介质中,铜(Ⅱ)离子存在,使过氧化氢氧化亚甲蓝的反应加快,褪色速度为: (dC亚)/(dt)=RC<sup>a</sup><sub>H<sub>2</sub>O<sub>2</sub></sub>C<sup>b</sup><sub>NH<sub>3</sub></sub>C<sup>o</sup>亚C<sup>d</sup><sub>ou</sub> (1)dt—反应速度 C—反应物浓度 t—反应时间R—反应速度常数 abcd—反应级数。 方法中过氧化氢和氨水过量,C<sup>a</sup><sub>H<sub>2</sub>O<sub>2</sub></sub>和C<sup>b</sup><sub>NH<sub>3</sub></sub> (dC亚)/(dt)=R'C亚C<sup>d</sup><sub>ou</sub> (2) 展开更多
关键词 催化动力学法 快速测定 催化反应 亚甲蓝溶液 水中痕量 过氧化氢溶液 反应速度常数 褪色反应 离子浓度的测定 H2O2
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Status of two Coreius species in the Three Gorges Reservoir,China 被引量:3
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作者 夏雨果 J.LLORET +6 位作者 李钟杰 张堂林 叶少文 李为 苑晶 H.A.C.C.PERERA 刘家寿 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2016年第1期19-33,共15页
Dam construction alters natural flow regimes which,in turn,cause significant changes in fish communities during and after impoundment. The construction of the Three Gorges Reservoir,from impoundment of the Changjiang(... Dam construction alters natural flow regimes which,in turn,cause significant changes in fish communities during and after impoundment. The construction of the Three Gorges Reservoir,from impoundment of the Changjiang(Yangtze) River,China,may have affected native fish species. Thus,the status of two lotic freshwater fish species,Coreius heterodon and C.guichenoti,were monitored in the Three Gorges Reservoir,including fish abundance,individual composition,growth,condition,and mortality. Data on both species were gathered from upstream,midstream and downstream areas of the reservoir and,where available,from studies published before and after dam construction. Lower abundance,slower growth,a less diversified age structure,poorer fish condition(indicated by hepatosomatic index) and higher mortalities were recorded in sites nearest the dam compared with upstream areas. Furthermore,after final impoundment,individual Coreius species inhabiting the area changed,with young individuals becoming more abundant,while upstream of the reservoir the two Coreius species became smaller at a given age. The results show that the status of the two Coreius species was subject to dramatic changes after impoundment. 展开更多
关键词 Three Gorges Reservoir Coreius species STATUS age profile GROWTH IMPOUNDMENT
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Recovery of Copper Ions from Wastewater by Hollow Fiber Supported Emulsion Liquid Membrane 被引量:3
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作者 郑辉东 陈晶晶 +1 位作者 王碧玉 赵素英 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第8期827-834,共8页
Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effect... Recovery of copper ions from wastewater using a hollow fiber supported emulsion liquid membrane (HFSELM) was studied with LIX984N as carrier, kerosene as diluents, and sulfuric acid solution as stripping phase. Effects of compositions of feed and emulsion liquid phase, flow rates on both sides of membrane, and hollow fiber module parameters were investigated. The stability of the emulsion liquid phase without surfactant and the effect of buffer in the feed phase on the extraction rate were also evaluated. It is found that the stability of the emulsion phase without surfactant is poor. Higher flow velocity gives shorter residence time for the emulsion liquid phase on the tube side, reducing the effect of particle coalescence on the separation process. The extraction rate increases with the increase of feed phase pH, carrier concentration, hydrogen ion concentration in the stripping phase, and ef- fective hollow fiber area. The phase ratio in the emulsion liquid phase has a negative effect on extraction rate. The flow rates on both sides have little influence on the extraction performance of the HFSELM, while buffer addition in the feed solution improves the extraction efficiency. 展开更多
关键词 copper ion supported emulsion liquid membrane extraction rate hollow fiber
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Slope stability analysis of Southern slope of Chengmenshan copper mine,China 被引量:5
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作者 Mohammed Mnzool Wan Ling Wei Zuo'an 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2015年第2期171-175,共5页
The engineering geology and hydrogeology in the southern slope of Chengmenshan copper mine are very complicated,because there is a soft-weak layer between two kinds of sandstones.Field investigations demonstrate that ... The engineering geology and hydrogeology in the southern slope of Chengmenshan copper mine are very complicated,because there is a soft-weak layer between two kinds of sandstones.Field investigations demonstrate that some instability problems might occur in the slope.In this research,the southern slope,which is divided into six sections(I-0,I-1,I-2,II-0,II-1 and II-2),is selected for slope stability analysis using limit equilibrium and numerical method.Stability results show that the values of factor of safety(FOS) of sections I-0,I-1 and I-2 are very low and slope failure is likely to happen.Therefore reinforcement subjected to seismic,water and weak layer according to sections were carried out to increase the factor of safety of the three sections,two methods were used;grouting with hydration of cement and water to increase the cohesion(c) and pre-stressed anchor.Results of reinforcement showed that factor of safety increased more than 1.15. 展开更多
关键词 Slope stability Limit equilibrium method Numerical method Slope reinforcement
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Kinetics of Specific and Non-Specific Copper Sorption on Aggregates of an Acidic Paddy Soil from the Taihu Lake Region in East China 被引量:2
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作者 LIU Pei-Ya WEN Qin-Liang +2 位作者 LI Yu-Jiao DONG Chang-Xun PAN Gen-Xing 《Pedosphere》 SCIE CAS CSCD 2015年第1期37-45,共9页
The Taihu Lake region in East China has become prone to soil acidification, which changes heavy metals such as copper(Cu) in soil into water-soluble species and increases the mobility and contamination risks of heavy ... The Taihu Lake region in East China has become prone to soil acidification, which changes heavy metals such as copper(Cu) in soil into water-soluble species and increases the mobility and contamination risks of heavy metals in the biological environment. In this study, the kinetics of Cu2+sorption by the bulk soil and the aggregate size fractions of an acidic paddy soil collected from the Taihu Lake region, the effects of temperature on Cu2+sorption, and the p H changes of the solution were investigated by static sorption and magnetic stirring. The aggregate size fractions were prepared by low-energy ultrasonic dispersing and freeze-drying. The total sorption amounts of the bulk soil and the aggregate size fractions for Cu2+followed a descending order of clay > coarse sand > bulk soil > silt> sand, corresponding to those of organic matter content, free iron oxide content, free aluminum oxide content, and cation exchange capacity. The kinetic sorption curves of Cu2+by the bulk soil and the aggregates, which were divided into two stages(rapid and slow sequentially), were well fitted by the first-order equation, the diffusion equation, and the Elovich equation, showing significant correlations(P < 0.05). Specific and non-specific sorption dominated in the fast and slow stages, respectively, and the former was predominant throughout the sorption process. The specific sorption accelerated and the non-specific sorption decelerated with rising temperature. The p H of the solution decreased significantly during the specific sorption and remained unchanged or increased slightly during the non-specific sorption. When the specific sorption terminated, the p H of the solution was minimized nearly simultaneously.The sorption progress of Cu2+by the bulk soil significantly preceded that by the aggregates. Therefore, heavy metal contamination may be another factor reducing soil p H and metal sorption forms should be taken into consideration in studies of mitigating soil heavy metal pollution or determining environmental capacity of heavy metal in soil. 展开更多
关键词 bulk soil contamination heavy metal kinetic equation p H soil acidification temperature
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