The systematic experimental studies were performed on the hydrate formation kinetics and gas-hydrate equilibrium for a simulated catalytic cracking gas in the water-in-oil emulsion. The effect of temperature, pressure...The systematic experimental studies were performed on the hydrate formation kinetics and gas-hydrate equilibrium for a simulated catalytic cracking gas in the water-in-oil emulsion. The effect of temperature, pressure and initial gas-liquid ratio on the hydrate formation was studied, respectively. The data were obtained at pressures ranging from 3.5 to 5 MPa and temperatur.es from 274.15 to 277.15 K. The results showed that hydrogen and methane can be separated Irom the (~2+ ti'action by tOrming hydrate at around 273.15 K which is much higher temperature than that of the cryogenic separation method, and the hydrate formation rate can be enhanced in the wa- ter-in-oil emulsion compared to pure water. The experiments provided the basic data for designing the industrial process, and setting the suitable operational conditions. The measured data ot gas-hydrate equilibria were compared with the predictions by using the Chen-Guo hydrate thermodynamic model.展开更多
Oil-in-water (O/W) emulsions are widely used in metal working such as hot rolling and cutting. Three kinds of O/W emulsions with low oil concentration were prepared which include conventional emulsion (CE), miniem...Oil-in-water (O/W) emulsions are widely used in metal working such as hot rolling and cutting. Three kinds of O/W emulsions with low oil concentration were prepared which include conventional emulsion (CE), miniemulsion (MNE) and microemulsion (ME). The lubricating properties of O/W emulsions with low oil concentration were investigated using the tribological testers and the thin film interferometry based on the relative optical interference intensity method. The tribological test results under boundary lubrication show that the friction coefficient and the total losing weight can be clearly seen: CE 〈 MNE 〈 ME. The lubricating film thicknesses under elastohydrodynarnic lubrication and thin film lubrication show that a relationship of the film formation abilities: CE 〉 MNE 〉 ME. Competitive wetting behavior of water and oil on solid surface was confirmed to play an important role in the film formation and tribological behaviors of O/W emulsion.展开更多
The formation of oil-water emulsion often occurs when oil is spilled into the ocean. Oil weighting factor of oil-water emulsion is one of the most important parameters for emergent oil-spill microwave monitoring. A ne...The formation of oil-water emulsion often occurs when oil is spilled into the ocean. Oil weighting factor of oil-water emulsion is one of the most important parameters for emergent oil-spill microwave monitoring. A new method is proposed here to evaluate the oil weighting factor based on fractional Weierstrass scattering model. By using the proposed method, we analyze the Uninhabited Aerial Vehicle Synthetic Aperture Radar(UAVSAR) L-band fully polarimetric data acquired during 2010 Deepwater Horizon oil spill disaster event in the Gulf of Mexico. The result shows that our method performs well in evaluating oil weighting factor of oil-covered area.展开更多
基金Supported by the National iqatural Science Foundation of China (20925623, U1162205).
文摘The systematic experimental studies were performed on the hydrate formation kinetics and gas-hydrate equilibrium for a simulated catalytic cracking gas in the water-in-oil emulsion. The effect of temperature, pressure and initial gas-liquid ratio on the hydrate formation was studied, respectively. The data were obtained at pressures ranging from 3.5 to 5 MPa and temperatur.es from 274.15 to 277.15 K. The results showed that hydrogen and methane can be separated Irom the (~2+ ti'action by tOrming hydrate at around 273.15 K which is much higher temperature than that of the cryogenic separation method, and the hydrate formation rate can be enhanced in the wa- ter-in-oil emulsion compared to pure water. The experiments provided the basic data for designing the industrial process, and setting the suitable operational conditions. The measured data ot gas-hydrate equilibria were compared with the predictions by using the Chen-Guo hydrate thermodynamic model.
基金supported by the Ph.D. Programs Foundation of Ministry of Education of China (Grant No. 20100007120010)the Tribology Science Fund of State Key Laboratory of Tribology (Grant No. SKLTKF11A05)Science Foundation of China University of Petroleum,Beijing (GrantNo. KYJJ2012-04-17)
文摘Oil-in-water (O/W) emulsions are widely used in metal working such as hot rolling and cutting. Three kinds of O/W emulsions with low oil concentration were prepared which include conventional emulsion (CE), miniemulsion (MNE) and microemulsion (ME). The lubricating properties of O/W emulsions with low oil concentration were investigated using the tribological testers and the thin film interferometry based on the relative optical interference intensity method. The tribological test results under boundary lubrication show that the friction coefficient and the total losing weight can be clearly seen: CE 〈 MNE 〈 ME. The lubricating film thicknesses under elastohydrodynarnic lubrication and thin film lubrication show that a relationship of the film formation abilities: CE 〉 MNE 〉 ME. Competitive wetting behavior of water and oil on solid surface was confirmed to play an important role in the film formation and tribological behaviors of O/W emulsion.
基金supported by the National Natural Science Foundation of China (Grant No. 61331021)
文摘The formation of oil-water emulsion often occurs when oil is spilled into the ocean. Oil weighting factor of oil-water emulsion is one of the most important parameters for emergent oil-spill microwave monitoring. A new method is proposed here to evaluate the oil weighting factor based on fractional Weierstrass scattering model. By using the proposed method, we analyze the Uninhabited Aerial Vehicle Synthetic Aperture Radar(UAVSAR) L-band fully polarimetric data acquired during 2010 Deepwater Horizon oil spill disaster event in the Gulf of Mexico. The result shows that our method performs well in evaluating oil weighting factor of oil-covered area.