The reactivity of Na2B4O7·5HaO and Na2B4O7 in non-aqueous HCl-CH3OH solvent system was investigated. The effects of H2O, CH3OH/B mole ratio and reaction time on the reaction at room temperature were examined. Exp...The reactivity of Na2B4O7·5HaO and Na2B4O7 in non-aqueous HCl-CH3OH solvent system was investigated. The effects of H2O, CH3OH/B mole ratio and reaction time on the reaction at room temperature were examined. Experimental results show that when Na2B4O7·5H2O and Na2B4O7 are the reactants, the dissolved B203 contents are observed to be 98.2% and 99%, respectively, in 5min at the CH3OH/B mole ratio of 4. The decrease of water in the reaction medium was observed to increase the crystallization of NaCI in the order of Na2B4O7〉Na2B4O7·5H2O It was also observed that the boron solution obtained after the reaction could be hydrolyzed by the addition of H3BO3. The results show that HCl-CH3OH system is a more effective solvent compared to H2SO4-CH3OH both in the reactivity and the shortened reaction time.展开更多
Supercritical water has been focused on as an environmentally attractive reaction media, in which organic materials can be decomposed into smaller molecules. The reaction behavior of pyrrole as a simple model compound...Supercritical water has been focused on as an environmentally attractive reaction media, in which organic materials can be decomposed into smaller molecules. The reaction behavior of pyrrole as a simple model compound of nonbasic nitrogen compounds found in petroleum residua was studied in supercritical water with a batch type reactor. The reaction was carried out at temperatures of 698-748 K and at various pressures under an argon atmosphere. The chemical species in the aqueous products were identified by GCMS （gas chromatography mass spectrometry） and quantified using GC-FID （gas chromatography flame ionization detector）. The effect of temperature and reaction time on the conversion process of pyrrole is presented. Under supercritical water conditions, pyrrole underwent successful decomposition in water into its derived compounds. The conversion of pyrrole could approach 81.12 wt% at 723 K and 40 MPa within 240 min of reaction time. The decomposition process was accelerated with the existence of water at the same temperature. Ultimate analysis of solid products was also conducted using a CHN analyzer. The process investigated in this study may form the basis for an efficient method of nitrogen compound decomposition in future.展开更多
Compressed CO~ could promote the disproportionation reactions of aryl alcohols in water medium significantly. The control experiments indicated that the effect of CO2 on the properties of the reactant/water emulsions ...Compressed CO~ could promote the disproportionation reactions of aryl alcohols in water medium significantly. The control experiments indicated that the effect of CO2 on the properties of the reactant/water emulsions was the main reason for the ac- celeration of the reactions rate.展开更多
文摘The reactivity of Na2B4O7·5HaO and Na2B4O7 in non-aqueous HCl-CH3OH solvent system was investigated. The effects of H2O, CH3OH/B mole ratio and reaction time on the reaction at room temperature were examined. Experimental results show that when Na2B4O7·5H2O and Na2B4O7 are the reactants, the dissolved B203 contents are observed to be 98.2% and 99%, respectively, in 5min at the CH3OH/B mole ratio of 4. The decrease of water in the reaction medium was observed to increase the crystallization of NaCI in the order of Na2B4O7〉Na2B4O7·5H2O It was also observed that the boron solution obtained after the reaction could be hydrolyzed by the addition of H3BO3. The results show that HCl-CH3OH system is a more effective solvent compared to H2SO4-CH3OH both in the reactivity and the shortened reaction time.
文摘Supercritical water has been focused on as an environmentally attractive reaction media, in which organic materials can be decomposed into smaller molecules. The reaction behavior of pyrrole as a simple model compound of nonbasic nitrogen compounds found in petroleum residua was studied in supercritical water with a batch type reactor. The reaction was carried out at temperatures of 698-748 K and at various pressures under an argon atmosphere. The chemical species in the aqueous products were identified by GCMS （gas chromatography mass spectrometry） and quantified using GC-FID （gas chromatography flame ionization detector）. The effect of temperature and reaction time on the conversion process of pyrrole is presented. Under supercritical water conditions, pyrrole underwent successful decomposition in water into its derived compounds. The conversion of pyrrole could approach 81.12 wt% at 723 K and 40 MPa within 240 min of reaction time. The decomposition process was accelerated with the existence of water at the same temperature. Ultimate analysis of solid products was also conducted using a CHN analyzer. The process investigated in this study may form the basis for an efficient method of nitrogen compound decomposition in future.
基金National Natural Science Foundation of China(21003133,20932002,21021003)Chinese Academy of Sciences(KJCX2.YW.H30)
文摘Compressed CO~ could promote the disproportionation reactions of aryl alcohols in water medium significantly. The control experiments indicated that the effect of CO2 on the properties of the reactant/water emulsions was the main reason for the ac- celeration of the reactions rate.
