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利用不同的湿度调节方法研究醋酸镁气溶胶中水的传质过程(英文)
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作者 王娜 庞树峰 张韫宏 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2016年第5期1581-1584,共4页
利用一种自制的湿度调节设备与真空红外光谱仪相结合,提出了一种研究醋酸镁气溶胶的吸湿性和传质动力学的新方法。湿度调节装置通过改变纯水汽压力来调节样品室的相对湿度,这样可以实现湿度以不同的速度发生变化。与红外光谱手段相结合... 利用一种自制的湿度调节设备与真空红外光谱仪相结合,提出了一种研究醋酸镁气溶胶的吸湿性和传质动力学的新方法。湿度调节装置通过改变纯水汽压力来调节样品室的相对湿度,这样可以实现湿度以不同的速度发生变化。与红外光谱手段相结合,湿度缓慢变化,让气溶胶时刻处于准稳态过程,可以研究气溶胶在热力学稳态的吸湿性质。湿度脉冲式改变,可以研究气溶胶的动态吸湿性质以及传质动力学过程。红外光谱的扫描方式随着湿度的改变速度进行调节。由于实验中的相对湿度由纯水气提供,因此通过对红外方光谱中纯水气的特征吸收峰面积的定量计算获得与光谱同步的相对湿度值。研究发现,当湿度稳定在一个高湿度时,醋酸根和液态水的峰面积在持续下降。并且首次发现经过一个准稳态的湿度循环后(1.05×10~4 s),在80%RH条件下,水峰面积由1.5降低至1.1。通过改变实验方案并对其结果进行对比可知,在高湿度条件下,醋酸镁发生水解,生成的醋酸由于样品室内的负压而挥发,因此引起气溶胶含水量下降。采用脉冲发式快速改变样品室的湿度,一个湿度脉冲循环需要10s。计算脉冲循环过程中气溶胶的含水量发现,在湿度高于70%RH时,气溶胶含水量没有减少。但是加湿过程的水传输比去湿过程的水传输快。这些现象说明醋酸镁的水解速率小于湿度的脉冲改变速率。在湿度快速变化的过程中,气溶胶液滴表面难溶物的形成引起水传输发生受阻现象。 展开更多
关键词 醋酸镁气溶胶 水传质动力学 挥发
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Kinetic Mass Transfer Between Non-aqueous Phase Liquid and Gas During Soil Vapor Extraction 被引量:1
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作者 李鑫钢 黄国强 沈铁孟 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第5期610-613,共4页
The mass transfer between non-aqueous phase liquid(NAPL) phase and soil gas phase in soil vapor extraction(SVE) process has been investigated by one-dimensional venting experiments. During quasi-steady volatilization ... The mass transfer between non-aqueous phase liquid(NAPL) phase and soil gas phase in soil vapor extraction(SVE) process has been investigated by one-dimensional venting experiments. During quasi-steady volatilization of three single-component NAPLs in a sandy soil, constant initial lumped mass transfer coefficient (λgN,0) canbe obtained if the relative saturation (ξ) between NAPL phase and gas phase is higher than a critical value (ξc), andthe lumped mass transfer coefficient decreases with ξ when ξ<ξc. It is also shown that the lumped mass transfercoefficient can be increased by blending porous micro-particles into the sandy soil because of the increasing of theinterfacial area. 展开更多
关键词 kinetic mass transfer soil vapor extraction non-aqueous phase liquid soil remediation
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Influence of Osmotic Dehydration with High Electric Field on the Drying Kinetics and Mass Transfer of Green Apples
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作者 Baishali Dutta Ramesh Murugesan Vijaya G.S. Raghavan Valerie Orsat 《Journal of Agricultural Science and Technology(B)》 2012年第11期1138-1147,共10页
Traditional thermal methods of drying food have often led to loss of flavours, nutrients, vitamins, etc., which encourages non-thermal pretreatments such as osmotic dehydration (OD) and/or high electric field (HEF... Traditional thermal methods of drying food have often led to loss of flavours, nutrients, vitamins, etc., which encourages non-thermal pretreatments such as osmotic dehydration (OD) and/or high electric field (HEF) application to improve the overall product quality. The aim of this study was to evaluate the effect of osmotic dehydration (50% sucrose) with high electric field strengths of 0.5 and 1.0 kV/cm as pretreatments on the drying kinetics and mass transfer of green apples during convective drying at 65 ~C and microwave drying at 1 W/g. The added value of the OD and HEF on the drying kinetics, and the effective mass transfer coefficients of the subsequent drying methods were investigated through this research. The efficacy of these pre-treatments was assessed and compared using cell disintegration index, product texture and thus bring forth new correlations between these pre-treatments and the cell disintegration index using dielectric spectroscopy and its effect on the product texture. 展开更多
关键词 Osmotic dehydration high electric field drying kinetics mass transfer product quality.
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