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γ-Al_2O_3固相微萃取涂层的制备及其在水体和气态基质中的应用 被引量:5
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作者 魏黎明 李菊白 +1 位作者 王国俊 欧庆瑜 《色谱》 CAS CSCD 北大核心 2004年第4期435-438,共4页
采用物理涂渍的方法制备了γ Al2 O3 固相微萃取涂层。通过γ Al2 O3 固相微萃取 (SPME) 气相色谱 (GC)联用技术 ,对水中痕量苯系物苯、甲苯、乙苯、二甲苯异构体 (BTEXs)进行萃取分析 ,结果表明该涂层具有热稳定性强 (最高使用温度可... 采用物理涂渍的方法制备了γ Al2 O3 固相微萃取涂层。通过γ Al2 O3 固相微萃取 (SPME) 气相色谱 (GC)联用技术 ,对水中痕量苯系物苯、甲苯、乙苯、二甲苯异构体 (BTEXs)进行萃取分析 ,结果表明该涂层具有热稳定性强 (最高使用温度可达 35 0℃ )、灵敏度高 (检测限为 1~ 10 μg/L)以及制备重复性好 (相对标准偏差为 8 3% )的特点 ;同时该涂层对气态基质中的污染物亦可进行萃取分析。 展开更多
关键词 固相微萃取 三氧化二铝涂层 水体基质 气态 挥发性有机物 痕量苯系物
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Application of Equilibrium Partitioning Approach to the Derivation of Sediment Quality Guidelines for Metals in Dianchi Lake 被引量:9
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作者 CHEN Yun-Zeng YANG Hao +3 位作者 ZHANG Zhen-Ke QIN Ming-Zhou JIN Feng LU Jun-Jie 《Pedosphere》 SCIE CAS CSCD 2007年第3期284-294,共11页
For the past 20 years, numerous studies have been carried out on the application of equilibrium partitioning approach (EqPA) for the derivation of sediment quality guidelines (SQGs). However, for metals, few Equil... For the past 20 years, numerous studies have been carried out on the application of equilibrium partitioning approach (EqPA) for the derivation of sediment quality guidelines (SQGs). However, for metals, few Equilibrium-partitioning- based numerical SQGs have been developed or are currently available because of the confounding factors mediating the bioavailability of metals. A study was conducted at Dianchi Lake, which is a heavily eutrophicated lake on the Yunnan- Guizhou Plateau, China with the focus on the measurement of partitioning coefficient (Kp) and SQGs derivation and normalization to acid volatile sulfide (AVS), fine material, and organic carbon. Using new normalization methods, SQGs were formulated for seven metals including copper, zinc, lead, cadmium, chromium, mercury, and arsenic in Dianchi Lake. In Dianchi Lake sediments, the fine material contributed 25.4%-36.0% to the SQG values, with the largest contribution to the SQG value of mercury; AVS contributed 2.9%-75.0% to the SQG values, with the largest contribution to the SQG value of cadmium. This indicated that the fine material and the AVS were the most important controlling factors to the bioavailability of mercury and caximium, respectively. The contribution of total organic carbon (TOC) to the SQG values of copper and leaxi was 3.8% and 7.1%, respectively, indicating that at relatively lower concentrations, the contribution of TOC was not significant. In addition to normalization methods, appropriate procedures for the application of EqPA including sample collection, storage, and analysis are also essential to improve the reliability of SQGs. The normalized Dianchi Lake SQGs were higher than most of the empirically based SQGs developed in North America, but lower than Hong Kong interim SQGs except for cadmium and arsenic. The differences could be attributed to the approaches used for derivation of SQGs and the water quality criteria adopted and the differences in the physical and chemical characteristics of the sediments. 展开更多
关键词 acid volatile sulfide fine material normalization method organic carbon sediment quality guidelines
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A Nucleus-encoded Topological Specificity Factor PpMinE in Physcomitrella patens has Conserved Function Similar to Its Chloroplast-encoded Ancestor
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作者 朱佳瑛 刘维仲 +2 位作者 周伟巍 胡勇 何奕昆 《Journal of Genetics and Genomics》 SCIE CAS CSCD 北大核心 2007年第3期229-238,共10页
A nucleus-encoded MinE gene, designated PpMinE, from Physcomitrella patens was identified using RT-PCR. The presence of both N- and C-terminal extensions in PpMinE protein suggested its cyanobacterial origin. The tran... A nucleus-encoded MinE gene, designated PpMinE, from Physcomitrella patens was identified using RT-PCR. The presence of both N- and C-terminal extensions in PpMinE protein suggested its cyanobacterial origin. The transient expression of PpMinE using green fluorescent protein fusion in tobacco (Nicotiana tabacum L.) indicated that the PpMinE was a chloroplast-targeted protein. Overexpression of PpMinE in Escherichia coli caused division site misplacement and minicell formation, suggesting evolutionary functional conservation of MinE during plant phylogenesis. According to the phylogenetic tree, PpMinE protein has a close relationship with the highland plants, which suggests that the transfer events of MinE gene from plastid to nucleus might have occurred before the origin of the land plants. 展开更多
关键词 Physcomitrella patens plastid division PpMinE lateral gene transfer (LGT) evolution transient expression
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Effects of Self-purification of River Water on Laundry Wastewater
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作者 Liya TAN Yili CHEN +4 位作者 Liuying CHEN Linghan ZENG Yujie CAI Bingbing FENG Hai WANG 《Agricultural Science & Technology》 CAS 2017年第6期1023-1028,共6页
[Objective] This study was conducted to investigate the effect of laundry wastewater on the quality of river water and the dilution purification effect of river water on laundry wastewater. [Method] The effects of lau... [Objective] This study was conducted to investigate the effect of laundry wastewater on the quality of river water and the dilution purification effect of river water on laundry wastewater. [Method] The effects of laundry wastewater on the contents of total nitrogen(TN), total phosphorus(TP), suspended solids(SS), chemical oxygen demand(COD) and linear alkylbenzene sulfonic acid(LAS) were studied in 7 rivers of Shaoxing City. [Result](1) The contents of TN, TP, SS, COD and LAS increased by 92%, 99%, 340%, 351% and 923%, respectively, at the discharging moment of laundry wastewater; and(2) the five pollutional indexes significantly decreased over time, and especially 2 h after the discharge of laundry wastewater, compared with former the discharge of laundry wastewater, the contents of TN, TP, COD and LAS increased by 6%, 11%, 9% and13%, respectively,while the contents of SS still increased by 76%, i.e., SS required a longer time to achieve self-purification. [Conclusion] Laundry wastewater has some influence on thequality of river water, and the self-purification function of river water could effectively remove pollutants. 展开更多
关键词 Laundry wastewater SELF-PURIFICATION Total nitrogen Total phosphorus Linear alkylbenzene sulphonic acid
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