The crystal structure, morphology, dissolution kinetics and mechanism of gibbsitic bauxite and pure gibbsite in Na OH solution under atmospheric pressure were systematically investigated by XRD and SEM. The results sh...The crystal structure, morphology, dissolution kinetics and mechanism of gibbsitic bauxite and pure gibbsite in Na OH solution under atmospheric pressure were systematically investigated by XRD and SEM. The results show that the size of single crystal of gibbsite in gibbsitic bauxite is smaller than that in pure gibbsite, but the interplanar distance is larger than that of pure gibbsite, which result in more defects in the crystal and less energy needed to dissolve in alkaline solution for the gibbsitic bauxite. The dissolution kinetic equations of gibbsitic bauxite and pure gibbsite were established, and the corresponding activation energies were calculated to be 99.144 and 115.149 k J/mol, respectively.展开更多
The Taizhou Water Station Site is an ancient masonry structure ruin built in the Southern Song Dynasty. The main structure was severely damaged. In order to understand its current structural properties and provide a s...The Taizhou Water Station Site is an ancient masonry structure ruin built in the Southern Song Dynasty. The main structure was severely damaged. In order to understand its current structural properties and provide a scientific basis for protection design nonlinear finite element analysis and parameter analysis are carried out.The crack patterns deformations and stresses of the main structure under four load cases are analyzed by nonlinear finite element analysis and the effect of the backfill bulk density and modulus on the maximum principal tensile stress and maximum compressive stress are studied by parameter analysis.The results show that the most unfavorable condition for the foundation is the combination of weight＋backfill soil pressure＋additional load the most unfavorable load case to the main structure is weight ＋backfill soil pressure ＋water pressure＋additional heap load the maximum principal tensile stress of the main structure is very sensitive to the changes in the bulk density of the backfill soil.展开更多
基金Projects(5110404151174054+2 种基金51374065)supported by the National Natural Science Foundation of ChinaProject(N130402010)supported by the Fundamental Research Funds for the Central UniversitiesChina
文摘The crystal structure, morphology, dissolution kinetics and mechanism of gibbsitic bauxite and pure gibbsite in Na OH solution under atmospheric pressure were systematically investigated by XRD and SEM. The results show that the size of single crystal of gibbsite in gibbsitic bauxite is smaller than that in pure gibbsite, but the interplanar distance is larger than that of pure gibbsite, which result in more defects in the crystal and less energy needed to dissolve in alkaline solution for the gibbsitic bauxite. The dissolution kinetic equations of gibbsitic bauxite and pure gibbsite were established, and the corresponding activation energies were calculated to be 99.144 and 115.149 k J/mol, respectively.
基金The National Natural Science Foundation of China(No.51108238)
文摘The Taizhou Water Station Site is an ancient masonry structure ruin built in the Southern Song Dynasty. The main structure was severely damaged. In order to understand its current structural properties and provide a scientific basis for protection design nonlinear finite element analysis and parameter analysis are carried out.The crack patterns deformations and stresses of the main structure under four load cases are analyzed by nonlinear finite element analysis and the effect of the backfill bulk density and modulus on the maximum principal tensile stress and maximum compressive stress are studied by parameter analysis.The results show that the most unfavorable condition for the foundation is the combination of weight＋backfill soil pressure＋additional load the most unfavorable load case to the main structure is weight ＋backfill soil pressure ＋water pressure＋additional heap load the maximum principal tensile stress of the main structure is very sensitive to the changes in the bulk density of the backfill soil.
