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基于水内标的HNO_(3)、H_(2)SO_(4)、HClO_(4)拉曼光谱定量分析研究 被引量:2
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作者 王淦麟 柳倩 +3 位作者 李定明 郝轩 朱礼洋 杨素亮 《广东化工》 CAS 2021年第15期220-222,共3页
研究了以水为内标,采用拉曼光谱法测量水溶液中HNO_(3)、H_(2)SO_(4)、HClO_(4)浓度的可行性。研究发现,酸的加入会使得水在2700~3900cm-1范围内的伸缩振动拉曼峰的形状发生变化并导致水的拉曼散射系数增大。但酸浓度较低时,在对水的浓... 研究了以水为内标,采用拉曼光谱法测量水溶液中HNO_(3)、H_(2)SO_(4)、HClO_(4)浓度的可行性。研究发现,酸的加入会使得水在2700~3900cm-1范围内的伸缩振动拉曼峰的形状发生变化并导致水的拉曼散射系数增大。但酸浓度较低时,在对水的浓度进行修正后,可以用溶液中水在2700~3900 cm^(-1)范围内的拉曼峰为内标对几种酸进行定量分析。通过数据拟合获得的HNO_(3)、 H_(2)SO_(4)、 HClO_(4)的工作曲线分别为c(HNO_(3))=39.9RS/(1+0.6RS)(R^(2)=0.9999)、c(H_(2)SO_(4))=44.3RS/(1+2.3RS)(R^(2)=0.9994)、c(HClO_(4))=29.4RS/(1+1.1RS)(R^(2)=0.9993),其中RS=A(酸)/A(H2O),A(酸)和A(H2O)分别为酸和水的拉曼峰面积。HNO_(3)、H_(2)SO_(4)、HClO_(4)工作曲线的应用浓度范围分别为0.1~4.8 mol/L、0.1~4.1 mol/L、0.1~6.5 mol/L,检出限分别为0.0056、0.0061、0.0086 mol/L。 展开更多
关键词 水内标 溶剂浓度校正 HNO_(3) H_(2)SO_(4) HClO_(4) 定量分析 拉曼光谱法
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基于水内标的NO^(-)_(3),SO^(2-)_(4),ClO^(-)_(4)拉曼光谱定量分析研究
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作者 王淦麟 柳倩 +2 位作者 李定明 杨素亮 田国新 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2022年第6期1855-1861,共7页
拉曼光谱由于重现性差,在进行定量分析时往往需要内标。在水溶液中,水在2700~3900 cm^(-1)范围伸缩振动拉曼峰很强,有作为内标的可能性,但水与溶质的相互作用会导致水伸缩振动拉曼峰形状发生变化,此外水的占比也会随着溶质浓度的变化而... 拉曼光谱由于重现性差,在进行定量分析时往往需要内标。在水溶液中,水在2700~3900 cm^(-1)范围伸缩振动拉曼峰很强,有作为内标的可能性,但水与溶质的相互作用会导致水伸缩振动拉曼峰形状发生变化,此外水的占比也会随着溶质浓度的变化而变化,当溶质浓度较高时需要对水的含量进行校正。将这两点因素考虑在内,研究了以水为内标,采用拉曼光谱法测量水溶液中NO^(-)_(3),SO^(2-)_(4)和ClO^(-)_(4)浓度的适用性。不同浓度NaNO_(3),Na_(2)SO_(4)和NaClO_(4)溶液的拉曼光谱显示随着盐浓度的升高水在2700~3900 cm^(-1)范围内的拉曼峰呈现出左肩下降右肩上升的变化趋势。将三种盐溶液拉曼光谱中酸根离子拉曼峰面积(A_(盐))和水的拉曼峰面积(A H_(2)O)的比值(R^(S)=A_(盐)/A H_(2)O)与溶液中酸根离子和水的含量的比值(c_(盐)/c H_(2)O)作图,均呈现出良好的线性关系,拟合得到三条相关曲线的R^(2)分别为0.9991,0.9991和0.9994,说明酸根离子和水的拉曼散射系数均未发生变化或者在同比例变化。虽然水拉曼峰的形状发生了改变,但并不会影响水作为内标的可行性。在引入水的含量修正后,经理论推导c_(盐)与R^(S)符合关系式:c_(盐)=AR^(S)/(1+BR^(S))。在0.1 mol·L^(-1)到近饱和的宽浓度范围内,将R^(S)对c_(盐)作图,通过数据拟合获得的NaNO_(3),Na_(2)SO_(4)和NaClO_(4)的工作曲线分别为c NaNO_(3)=18.8 R^(S)/(1+0.6 R^(S))(R^(2)=0.9991),c Na_(2)SO_(4)=20.2 R^(S)/(1+1.0 R^(S))(R^(2)=0.9988),c NaClO_(4)=15.0 R^(S)/(1+0.7 R^(S))(R^(2)=0.9998)。NaNO_(3),Na_(2)SO_(4)和NaClO_(4)的检出限分别为0.0080,0.0052和0.0073 mol·L^(-1)。在水拉曼峰形状变化不影响其作内标可行性的基础上,当溶液中同时存在两种阴离子时,通过在水含量修正部分加入干扰离子对水含量的影响,可以在单盐溶液定量工作曲线中加入校正项来消除溶液中干扰离子对待测离子分析结果的干扰,但当干扰离子浓度较大而待测离子浓度较小时,干扰离子拉曼峰强度过大会影响到待测离子拉曼峰面积的准确性,从而使得校正的效果下降。 展开更多
关键词 水内标 拉曼光谱 NO^(-)_(3) SO^(2-)_(4) ClO^(-)_(4) 定量分析
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Calibration Method of Capacitive Soil Moisture Sensor 被引量:2
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作者 XIAO Lei JI Tianjian ZHANG Qingsong 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2020年第S01期109-114,共6页
Soil properties and water content vary from place to place. The calibration method based on capacitive soil moisture and humidity sensor is carried out. The sensor readings are compared with the mass water content mea... Soil properties and water content vary from place to place. The calibration method based on capacitive soil moisture and humidity sensor is carried out. The sensor readings are compared with the mass water content measured by the oven dried method,and the calibration formula of sensor reading and mass moisture content is established.Results show that the sensor reading has a good linear relationship with the mass water content measured by the oven dried method,and has high precision. It can calibrate the mass moisture content of the data obtained from the moisture migration test in the soil column. 展开更多
关键词 capacitive soil moisture sensor mass moisture content CALIBRATION laboratory tests
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Transpiration Rate and Leaf Water Potential as Indices for Cassava Yield in Inland Valley Ecology
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作者 M. T. Lahai I.J. Ekanayake 《Journal of Agricultural Science and Technology》 2010年第6期34-44,共11页
Differences in transpiration and leaf water potential (LWP) in relation to cassava yield were investigated along inland valley toposequence in a 4×4 Latin square design. The landrace with the highest transpirat... Differences in transpiration and leaf water potential (LWP) in relation to cassava yield were investigated along inland valley toposequence in a 4×4 Latin square design. The landrace with the highest transpiration rate and lowest LWP yielded the lowest, while TMS 91/02324 and TMS 91/02327 with intermediate rate and highest LWP yielded the highest, indicating that high transpiration rate associated with low LWP reduced yield. Transpiration was lower in the fringe with deeper water table than valley bottom at deep water table site, while at shallow water table, it was higher in the fringe than valley bottom, suggesting that drought and excess moisture reduced transpiration. LWP and water table depth correlated negatively indicating that shallow water table reduced transpiration by reducing LWP. Transpiration increased and LWP decreased as radiation, leaf temperature and vapour pressure deficit increased and differences in these microclimatic conditions caused differences in the two processes between sites, years and time of day. Under mild water stress, transpiration and LWP were higher in the afternoon than the morning, but the reverse occurred under severe stress. TMS 91/02324 and TMS 91/02327 had the highest LWP under severe stress, indicating their higher drought tolerance than the other cultivars. 展开更多
关键词 Transpiration rate leaf water potential root yield cassava cultivars water table depth weather condition inland valley ecology.
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