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悬浮聚合法合成纳米级单分散交联聚苯乙烯微球 被引量:10
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作者 李红 关燕霞 +2 位作者 薛新民 郭荣 黄承亚 《石油化工》 CAS CSCD 北大核心 2004年第6期560-562,共3页
以玉米淀粉/水为分散介质,不添加任何稳定剂,用悬浮聚合法成功地合成了纳米级单分散交联聚苯乙烯微球.考察了淀粉、苯乙烯、二乙烯基苯和偶氮二异丁腈用量对交联聚苯乙烯微球粒径大小及分布的影响.实验表明,最佳的聚合条件为玉米淀粉与... 以玉米淀粉/水为分散介质,不添加任何稳定剂,用悬浮聚合法成功地合成了纳米级单分散交联聚苯乙烯微球.考察了淀粉、苯乙烯、二乙烯基苯和偶氮二异丁腈用量对交联聚苯乙烯微球粒径大小及分布的影响.实验表明,最佳的聚合条件为玉米淀粉与水的质量比0.03~0.05,苯乙烯质量分数3.5%~7.0%,二乙烯苯质量分数1%,偶氮二异丁腈质量分数1%,反应温度85℃,反应时间13 h.在此条件下制备的交联聚苯乙烯微球粒径为110~125 nm,分散系数为0.03~0.04.SEM照片表明,该方法合成的纳米微球形状好、表面无杂质. 展开更多
关键词 悬浮聚合 玉米淀粉/水分散介质 交联聚苯乙烯微球 纳米级
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还原剂对AGET ATRP乳液体系制备含氟涂料性能的影响
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作者 苏文乾 杨兴兵 《涂料工业》 CAS CSCD 北大核心 2011年第6期7-9,共3页
利用电子活化再生原子转移自由基聚合(AGETATRP)法,在Tween-80乳化体系下合成了甲基丙烯酸甲酯(MMA)-丙烯酸丁酯(BA)-丙烯酸六氟丁酯(HFBA)的三元共聚物。由于AGETATRP反应体系中加入了还原剂来还原Cu2+,所以研究了还原剂的用量对聚合... 利用电子活化再生原子转移自由基聚合(AGETATRP)法,在Tween-80乳化体系下合成了甲基丙烯酸甲酯(MMA)-丙烯酸丁酯(BA)-丙烯酸六氟丁酯(HFBA)的三元共聚物。由于AGETATRP反应体系中加入了还原剂来还原Cu2+,所以研究了还原剂的用量对聚合反应可控性的影响以及对共聚物涂料性能的影响。研究发现增加还原剂用量,涂料的防水性、防油性、力学性能略有降低,但仍然表现出优异的防水性和良好的力学性能。 展开更多
关键词 AGET ATRP 水分散介质 含氟丙烯酸酯 力学性能
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Double-diffusive Fluxes of Salt and Heat in the Upper Layer of North Pacific Intermediate Water 被引量:2
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作者 YOUYuzhu 《Journal of Ocean University of China》 SCIE CAS 2005年第1期1-7,共7页
Almost half of the oceanic water columns exhibit double-diffusion. The importance of double-diffusion in global oceans’ salt and heat fluxes, water-mass formation and mixing, and circulation is increasingly recognize... Almost half of the oceanic water columns exhibit double-diffusion. The importance of double-diffusion in global oceans’ salt and heat fluxes, water-mass formation and mixing, and circulation is increasingly recognized. However, such an important physical process in the ocean has not been well studied. One of the reasons is the difficulty of parameterizing and quantifying the processes. The paper presented here attempts to quantify the double-diffusive fluxes of salt and heat in the ocean. Previous qualitative analysis by applying the water-mass Turner angle, mTu, to the North Pacific Intermediate Water (NPIW) layer showed a favorable condition for salt-fingering in the upper NPIW due to the overlying warm/salty water above the cold/fresh NPIW core, and a doubly-stable condition in the lower NPIW where potential temperature decreases with depth while salinity increases, inducing double stratification with respect to both potential temperature and salinity. The present study gives a quantitative estimate of double-diffusive fluxes of salt and heat contributed by salt-fingering in the upper NPIW layer. 展开更多
关键词 double-diffusion salt-fingering double-diffusive fluxes of heat and salt water-mass turner angle NPIW north pacific
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Size Reduction of Hydrophobically Modified Starch on Beads Mill: Effect of Dispersing Medium and Milling Time
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作者 Marcos Antonio Neves Petr Dejmek +1 位作者 Isao Kobayashi Mitsutoshi Nakajima 《Journal of Food Science and Engineering》 2015年第3期103-111,共9页
The primary interest to this study was to investigate the effect of milling parameters on the size of hydrophobically modified starch particles, aiming to produce small, uniformly sized modified starch microspheres. O... The primary interest to this study was to investigate the effect of milling parameters on the size of hydrophobically modified starch particles, aiming to produce small, uniformly sized modified starch microspheres. Octie, a commercial product originated from cornstarch modified using Octenyl Succinate Anhydride (OSA), was dispersed (3 wt%) using different media (water or ethanol) and subsequently wet-milled using a beads mill with zirconium beads at a rotation of 6,000 rpm up to 30 min. It was found that milling Octie in water dispersion for 3 min resulted in the smallest mean particle size (2.04 i 0.91 ktm), compared to unmilled modified starch granules (15.2 ~ 6.0 lam). Granular size and morphology changed considerably with further milling. For instance, very dense clusters with variable particle sizes (20.6 ~ 10.0 lam) were obtained after 30 min milling. As depicted by Scanning Electronic Microscopy, a large number of particles were apparently flattened during the milling process rather than broken, forming aggregates. Ultimately, within the range of experimental conditions tested, production of sub-micron modified starch particles was not possible. 展开更多
关键词 HYDROPHOBIC octenyl modified starch milling.
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