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玻璃纤维/环氧树脂纺织复合材料水分散法制备 被引量:1
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作者 陈洁 易长海 +1 位作者 邹汉涛 王罗新 《武汉科技学院学报》 2008年第12期5-7,共3页
本文初步探索了玻璃布增强环氧树脂复合材料的水分散法制备工艺,研究了玻璃布的浸渍工艺,并通过对材料力学性能的测试,探索了最佳模压成型工艺参数。结果表明:浸渍液浓度应较高,浸渍时间为40秒左右,浸渍次数为4~5次;复合材料制... 本文初步探索了玻璃布增强环氧树脂复合材料的水分散法制备工艺,研究了玻璃布的浸渍工艺,并通过对材料力学性能的测试,探索了最佳模压成型工艺参数。结果表明:浸渍液浓度应较高,浸渍时间为40秒左右,浸渍次数为4~5次;复合材料制备较佳的工艺参数为模压压力12MPa、模压时间6min和模压温度190℃。 展开更多
关键词 环氧树脂 玻璃纤维 纺织复合材料 水分散法 制备工艺
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水分散法制备3D打印用聚丙烯粉末的性能 被引量:2
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作者 杨旭生 汪艳 严光旺 《工程塑料应用》 CAS CSCD 北大核心 2018年第4期103-107,117,共6页
采用一种新颖的方法——水分散法制备选择性激光烧结(SLS)用聚丙烯(PP)粉末,采用分样筛、粒度分析仪、扫描电子显微镜、表观密度分析仪、力学性能测试及差示扫描量热(DSC)仪对该PP粉末进行了一系列表征并同溶剂沉淀法制备的PP粉末性能... 采用一种新颖的方法——水分散法制备选择性激光烧结(SLS)用聚丙烯(PP)粉末,采用分样筛、粒度分析仪、扫描电子显微镜、表观密度分析仪、力学性能测试及差示扫描量热(DSC)仪对该PP粉末进行了一系列表征并同溶剂沉淀法制备的PP粉末性能进行了比较。结果表明,两种方法制备的PP粉末粒径均集中在74~150μm,可以用于SLS工艺;水分散法PP粉末与溶剂沉淀法PP粉末粒径分布范围分别为20~158μm和25~105μm,水分散法PP粉末粒径分布更为分散,平均粒径相对较大;与溶剂沉淀法PP粉末相比,水分散法PP粉末微粒表面更光滑、致密度更高;水分散法PP粉末与溶剂沉淀法PP粉末表观密度分别为0.523,0.322 g/cm^3;水分散法PP粉末注塑试样的拉伸强度、弯曲强度、弯曲弹性模量较PP原料注塑试样有所降低、但缺口冲击强度提升1倍,溶剂沉淀法PP粉末注塑试样的力学性能与PP原料相近;DSC测试表明,水分散法PP粉末与溶剂沉淀法PP粉末的SLS加工温度范围分别为126.1~159.25℃和128.64~156.74℃,水分散法PP粉末有更宽的SLS加工温度范围。 展开更多
关键词 水分散法 溶剂沉淀 聚丙烯粉末 3D打印 选择性激光烧结 性能
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水分散法制备3D打印用PP粉末的可行性 被引量:1
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作者 杨旭生 汪艳 冯丽 《工程塑料应用》 CAS CSCD 北大核心 2018年第3期50-55,共6页
采用水分散法制备选择性激光烧结用聚丙烯(PP)粉末,使用普朗尼克(F108)作为表面活性剂,成功验证了水分散法的可行性。对PP在水中分散效果的若干因素进行了研究,包括表面活性剂的添加量、PP的添加量、成核剂的添加量、PP的熔体流动速率... 采用水分散法制备选择性激光烧结用聚丙烯(PP)粉末,使用普朗尼克(F108)作为表面活性剂,成功验证了水分散法的可行性。对PP在水中分散效果的若干因素进行了研究,包括表面活性剂的添加量、PP的添加量、成核剂的添加量、PP的熔体流动速率等原料配比因素以及温度、搅拌转速等反应条件的影响。表面活性剂添加量少于10 g则无法得到PP粉末,在表面活性剂添加量为10~60 g范围内,表面活性剂添加量与PP成粉率成正比,表面活性剂添加量为60 g以上时,PP的成粉率变化不大;PP的添加量达到10 g以上时,PP的成粉质量在7 g左右;白炭黑作为成核剂对PP的分散效果影响很大,并且PP的成粉率在白炭黑添加量为0.15 g时达到最大值,为57.6%;PP的熔体流动速率(MFR)与其成粉率成正比,PP的MFR由20 g/(10 min)增加到41.3 g/(10 min)时,PP的成粉率由48.6%增加到56.4%。改变加热温度、降温方式对PP成粉率的影响不大,而搅拌转速对PP分散效果的影响显著,搅拌转速与PP的成粉率成正比,在搅拌转速为1 500 r/min时,PP的成粉率达到最大值,为72.5%。水分散法制备的PP粉末球形度高、表面光滑、流动性好。 展开更多
关键词 水分散法 高分子粉末 聚丙烯 选择性激光烧结 制备
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水分散法制备EVA粉末 被引量:2
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作者 彭哲 顾东民 《化学世界》 CAS CSCD 1989年第12期546-548,共3页
本文论述了以烷基苯磺酸钠代替国外Pluconics F-108表面活性剂,在水分散体系中制备乙烯-醋酸乙烯共聚物(EVA)粉末的方法。结果表明:EVA颗粒在水分散体系中以无机碱类和无机盐类作为助分散剂,使用国产普通烷基苯磺酸钠,在高速搅拌状态下... 本文论述了以烷基苯磺酸钠代替国外Pluconics F-108表面活性剂,在水分散体系中制备乙烯-醋酸乙烯共聚物(EVA)粉末的方法。结果表明:EVA颗粒在水分散体系中以无机碱类和无机盐类作为助分散剂,使用国产普通烷基苯磺酸钠,在高速搅拌状态下,可以制得粒度分布范围较窄,粒径在40~200目的球状粉末。该粉末与深冷法加工的粉末相比,具有外形呈球状,粒度均匀的特点,因此更适合于热熔粘合衬芯布的加工上。 展开更多
关键词 EVA粉末 制备 水分散法
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水介质分散法制备EVA热熔胶粉末 被引量:1
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作者 任小明 李伟博 蒋涛 《湖北大学学报(自然科学版)》 CAS 北大核心 2010年第4期422-424,433,共4页
讨论水介质分散法制备EVA热熔胶粉末工艺中,温度、转速、表面活性剂用量、料水比等因素对粉末产率、产物形状和生产效率的影响.结果表明,当反应温度为170℃,转速为400r/min,表面活性剂用量为2.7%,料水比在1∶4~1∶5之间时制备的粉末产... 讨论水介质分散法制备EVA热熔胶粉末工艺中,温度、转速、表面活性剂用量、料水比等因素对粉末产率、产物形状和生产效率的影响.结果表明,当反应温度为170℃,转速为400r/min,表面活性剂用量为2.7%,料水比在1∶4~1∶5之间时制备的粉末产率较高.符合生产要求的粉末(粒径为425~250μm)产率高达80.3%. 展开更多
关键词 水分散法 EVA 表面活性剂
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水分散直接衍生/高效液相色谱法测定烟用胶中的醛酮 被引量:8
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作者 游金清 陈嘉彬 +3 位作者 倪建彬 林建南 洪梨梨 张艳 《中国胶粘剂》 CAS 北大核心 2014年第5期18-22,共5页
建立了同时测定烟用胶中8种醛酮(甲醛、乙醛、丙酮、丙烯醛、丙醛、巴豆醛、2-丁酮和丁醛)的水分散直接衍生,高效液相色谱(HPLC)方法。研究结果表明:目标分析物采用该法可在18min内完全分离,并在23min内完成分析全过程;8种醛酮... 建立了同时测定烟用胶中8种醛酮(甲醛、乙醛、丙酮、丙烯醛、丙醛、巴豆醛、2-丁酮和丁醛)的水分散直接衍生,高效液相色谱(HPLC)方法。研究结果表明:目标分析物采用该法可在18min内完全分离,并在23min内完成分析全过程;8种醛酮的检出限为0.4*0.7μg/L,定量限为1.4-2.3μg,L,回收率为89.1%~97.5%,平均RSD(相对标准偏差)〈5.7%。 展开更多
关键词 分散直接衍生 烟用胶 醛酮 高效液相色谱
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醇/水分散聚合法制备单分散微米级交联聚甲基丙烯酸甲酯微球 被引量:4
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作者 余响林 袁小亚 +1 位作者 黄锦霞 匡毅 《湖北大学学报(自然科学版)》 CAS 2003年第2期137-140,171,共5页
在乙醇 水介质中通过分散聚合方法合成了单分散性好,交联度高,粒径在3~5μm的聚甲基丙烯酸甲酯微球,考察了单体、引发剂、稳定剂、交联剂浓度和介质配比对粒子粒径及其分布的影响.研究结果表明,交联剂、引发剂浓度增大,聚合速率增大,... 在乙醇 水介质中通过分散聚合方法合成了单分散性好,交联度高,粒径在3~5μm的聚甲基丙烯酸甲酯微球,考察了单体、引发剂、稳定剂、交联剂浓度和介质配比对粒子粒径及其分布的影响.研究结果表明,交联剂、引发剂浓度增大,聚合速率增大,粒径呈增加趋势;稳定剂浓度增大,粒径减小.粒径在单体浓度为100g·L-1时出现一个最小值.初步探讨了聚合方法对粒径、粒径分布及粒子形态的影响. 展开更多
关键词 聚甲基丙烯酸甲酯 醇/分散聚合 制备 分散 微米级 粒径分布 粒子形态
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Preparation and Characterization of M-Type Barium Ferrite Fibers via Aqueous Sol-Gel Process 被引量:1
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作者 龚彩荣 范国樑 +1 位作者 宋崇林 吕刚 《Transactions of Tianjin University》 EI CAS 2007年第2期117-120,共4页
BaFe12O19 fibers was prepared via an aqueous sol-gel process using Fe(OH)(HCOO)2 synthesized in laboratory and Ba(CH3COO)2 as the original materials and citrate as the chelate. The rheological behaviour of spinn... BaFe12O19 fibers was prepared via an aqueous sol-gel process using Fe(OH)(HCOO)2 synthesized in laboratory and Ba(CH3COO)2 as the original materials and citrate as the chelate. The rheological behaviour of spinnable sol was characterized on rheometer, and the development of gel fibers to barium ferrite fibers was studied by IR, TG and XRD. Morphology observation of the fibers was given on SEM, and the diameter of the obtained fibers was between 5 and 10 um corresponding to different additives. The additives affected the surface tension of the precursor sol which had close relation to the microstructure of fibers. Sucrose and hydroxyethylic cellulose could improve the surface tension while diethanolamine and hexadecylamine reduce that of the decylamine as an additive, well-structured BaFe12O19 precursor sol. And using diethanolamine or hexafibers could be obtained. 展开更多
关键词 barium ferrite FIBER ADDITIVE MICROSTRUCTURE SOL-GEL synthesis
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Quasi-Periodic Structures Based on Symmetrical Lucas Function of (2+1)-Dimensional Modified Dispersive Water-Wave System
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作者 Emad A-B.ABDEL-SALAM 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第12期1004-1012,共9页
By introducing the Lucas-Riccati method and a linear variable separation method, new variable separation solutions with arbitrary functions are derived for a (2+1)-dimensional modified dispersive water-wave system.... By introducing the Lucas-Riccati method and a linear variable separation method, new variable separation solutions with arbitrary functions are derived for a (2+1)-dimensional modified dispersive water-wave system. The main idea of this method is to express the solutions of this system as polynomials in the solution of the Riecati equation that the symmetrical Lucas functions satisfy. From the variable separation sohition and by selecting appropriate functions, some novel Jacobian elliptic wave structure with variable modulus and their interactions with dromions and peakons are investigated. 展开更多
关键词 Lucas functions quasi-periodic structure variable separation excitations modified dispersive water-wave system
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Discretization Approach in Integrated Hydrologic Model for Surface and Groundwater Interaction 被引量:3
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作者 ZHANG Jing Mark A ROSS Jeffery GEURINK 《Chinese Geographical Science》 SCIE CSCD 2012年第6期659-672,共14页
The commonly used discretization approaches for distributed hydrological models can be broadly categorized into four types,based on the nature of the discrete components:Regular Mesh,Triangular Irregular Networks(TINs... The commonly used discretization approaches for distributed hydrological models can be broadly categorized into four types,based on the nature of the discrete components:Regular Mesh,Triangular Irregular Networks(TINs),Representative Elementary Watershed(REWs) and Hydrologic Response Units(HRUs).In this paper,a new discretization approach for landforms that have similar hydrologic properties is developed and discussed here for the Integrated Hydrologic Model(IHM),a combining simulation of surface and groundwater processes,accounting for the interaction between the systems.The approach used in the IHM is to disaggregate basin parameters into discrete landforms that have similar hydrologic properties.These landforms may be impervious areas,related areas,areas with high or low clay or organic fractions,areas with significantly different depths-to-water-table,and areas with different types of land cover or different land uses.Incorporating discrete landforms within basins allows significant distributed parameter analysis,but requires an efficient computational structure.The IHM integration represents a new approach interpreting fluxes across the model interface and storages near the interface for transfer to the appropriate model component,accounting for the disparate discretization while rigidly maintaining mass conservation.The discretization approaches employed in IHM will provide some ideas and insights which are helpful to those researchers who have been working on the integrated models for surface-groundwater interaction. 展开更多
关键词 DISCRETIZATION distributed hydrological model Integrated Hydrologic Model(IHM) INTERACTION
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Effects of Gamma Irradiation for Sterilization on Aqueous Dispersions of Length Sorted Carbon Nanotubes
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作者 Jeffrey A. Fagan Nancy J. Lin +1 位作者 Rolf Zeisler Angela R. Hight Walker 《Nano Research》 SCIE EI CAS CSCD 2011年第4期393-404,共12页
There is currently great interest in the potential use of carbon nanotubes as delivery vessels for nanotherapeutics and other medical applications. However, no data are available on the effects of sterilization method... There is currently great interest in the potential use of carbon nanotubes as delivery vessels for nanotherapeutics and other medical applications. However, no data are available on the effects of sterilization methods on the properties of nanotube dispersions, the form in which most medical applications will be processed. Here we show the effects of gamma irradiation from a 60Co source on the dispersion and optical properties of single-wall carbon nanotubes in aqueous dispersion. Samples of different length-refined populations were sealed in ampoules and exposed to a dose of approximately 28 kGy, a level sufficient to ensure sterility of the dispersions. In contrast to literature results for solid-phase nanotube samples, the effects of gamma irradiation on the dispersion and optical properties of the nanotube samples were found to be minimal. Based on these results, gamma irradiation appears sufficiently non-destructive to be industrially useful for the sterilization of nanotube dispersions. 展开更多
关键词 NANOTUBE single-wall nanotube (SWNT) single-wall carbon nanotube (SWCNT) gamma irradiation STERILIZATION dispersion
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