小流域水分行为、生态效应及其优化调控研究方面的若干问题

把小流域水文生态研究 ,分解为小流域水分行为、生态效应及其优化调控研究 3个方面。在分析国内外研究现状与问题的基础上 ,指出了其需要系统加以探讨的若干内容 ,认为由此可构建流域水文生态学的基本框架 ,进而发展流域水文生态学。

基于高温流化技术改良红小豆的蒸煮品质

以红小豆为原料,采用高温流化技术(流化温度215℃、流化处理时间55 s、进料速率62 kg/h)对其进行处理,通过分析红小豆籽粒结构、淀粉结构、糊化特性以及水分吸收、迁移和分布情况,探究高温流化技术改良红小豆蒸煮品质的机理。结果表明,红小豆经过高温流化处理后,籽粒致密结构变得疏松、子叶相邻细胞间毛细孔直径增大、部分淀粉颗粒结构破损。在98℃近沸水中蒸煮时,原料红小豆蒸煮60 min时的糊化度与高温流化红小豆蒸煮30 min时的糊化度相当;经过高温流化处理之后,红小豆的糊化黏度更低,回生趋势更小;蒸煮60 min时,高温流化红小豆吸水率为90.06%,比原料红小豆提高34.84%,吸水性能明显改善;高温流化红小豆颗粒内部的水分迁移速率明显加快且分布更均匀;高温流化红小豆煮饭的感官评分更高。综上,高温流化改良红小豆蒸煮品质的途径主要是通过拓宽籽粒水分进入的通道、破坏吸水屏障来提高吸水性能,从而使淀粉吸水更充分、糊化更彻底,同时也改善了其煮饭的口感风味。

高温流化改善青稞米蒸煮品质及机理研究

采用高温流化技术处理青稞米,改善其蒸煮品质。考察流化温度、进料速度、处理时间及补水量4个因素对青稞米蒸煮硬度的影响,正交实验得到最优工艺参数为:流化温度175℃、进料速度60 kg/h、流化时间80 s。当青稞米与大米同煮时,青稞米的蒸煮硬度为1409.75 g,与大米蒸煮硬度相近;淀粉糊化度升高了17.6%,高温流化青稞米与大米同煮能够同煮同熟,且其咀嚼性降低、黏着性增加,食味品质得到明显改善。高温流化使得青稞米淀粉颗粒间隙增大、结晶度下降、吸水率增加,吸水性能提升,这是青稞米蒸煮品质改善的主要原因。

椪柑果实的生长发育规律

为了摸清椪柑在贵州西南部地区的果实生长发育规律 ,通过生育期定期采样 ,研究了椪柑果实的鲜重、体积、水分、干物质的增长变化规律。结果表明 ,6月以前椪柑果实的鲜重和体积增长较慢 ,7月上旬至 9月中旬果实鲜重和体积增长加快 ,10～ 11月果实的鲜重和体积增长最快 ;幼果期果实干物质的增长慢 ,8月以后果实中干物质大量积累 ;7月以前果实中水分逐渐增长 ,8月果实中水分迅速增长 ,在 10月的前 2 0d内 ,果实水分的净增长率为成熟果实中水分总量的 4 4.2 3%～5 1 6 4% 。

酸溶性钛渣的干燥特性及其影响因素

以氯化法生产钛白粉的主要原料酸溶性钛渣中的水分为研究对象,对酸溶性钛渣的常规干燥特性及影响因素进行了研究。通过研究酸溶性钛渣在温度变化、样品质量变化、以及初始含水量变化的条件下,获得干燥过程中的水分迁移行为,从而揭示酸溶性钛渣干燥过程的基本规律,探明酸溶性钛渣内部的传质机理。通过实验研究和理论探讨,为干燥冶金、化工原料的工业化应用和推广提供实验依据和理论基础。

The Behavior of Amphiphile at Oil-Water Interface by Monte Carlo Simulation

A novel simple two-dimensional square-lattice model of amphiphile at oil-water interface is developed,in which oil and water act as solvent and occupy empty sites and amphiphile occupies chains of sites. In this model, the oil-water interface is fixed, And amphiphile molecules will be enriched at the oil-water interface. The interfacial concentration of amphiphile calculated by Monte Carlo method shows that it is easier for the hydrophilic-hydrophobic balanced amphiphile to stay at the interface. And the adsorption of amphiphile increases with the increase of amphiphile concentration and the decrease with temperature.

Stress-strain relationship of unsaturated cohesive soil

A moisture-content based constitutive model was proposed based on the hyperbolic model as an attempt to move towards the implementation of unsaturated soil mechanics into routine geotechnical engineering practice. The stress-strain behavior of in-situ soil at a depth of 5 m was investigated by conducting undrained triaxial compression tests using the remolded soil samples. The test results show that the stress-strain relationship of unsaturated cohesive soil is still hyperbolic. The values of parameters a and b given in the model decrease with increasing the confining pressure for soil samples with the same moisture content and increase with increasing the moisture content for soil samples under the same confining pressure. The relationships between parameters a, b and moisture content were studied for confining pressures of 100, 150, 200 and 250 kPa. The comparison between the measured and predicted stress-strain curves for an additional group of soil samples, having a moisture content of 25.4%, shows that the proposed moisture content-dependent hyperbolic model provides a good prediction of stress-strain behavior of unsaturated cohesive soil.

AN INVESTIGATION OF THE HYDROPHOBIC AGGLOMERATION CHARACTERISTICS OF EASY DEGRADATION COAL FINES IN WATER

The separation of ultrafine coal from three Chinese coal samples of easy degradation coal fines in water has been investigated by the application of a hydrophobic agglomeration process. In addition to yielding clean coal with high recovery, this process requires significantly less oil concentration for agglomeration (less than 0.4% in oil-water weight ratio) and produces stabler agglomerates than general oil agglomeration process, the cost of the oil would no longer be an important consideration for its commercial application. Neutral diesel oil was used to make oleophilic coal particles agglomerated with good rejection of clay minerals under little oil consumption and certain agitation speed at 2000 r/min. An important advantage of this process compared with other cleaning fine coal methods is that it can extremely reduce or eliminate the effects of coal degradation and some clay minerals on coal preparation.

Deactivation Behavior of Hollow Titanium Silicalite Zeolite in Aqueous Ammonia Solution under Simulated Industrial Cyclohexanone Ammoximation Conditions

For simulating the real deactivation of hollow titanium silicalite(HTS) zeolite in commercial ammoximation process, HTS was treated by 10% NH_3·H_2O solution at 120 ℃ in stirred autoclave. It is found that a part of HTS zeolite crystals dissolved in the hot NH_3·H_2O solution, and the specific surface area and pore volume continuously decreased with the increase in NH_3 hydrothermal treatment time. Meanwhile, the transformation of framework Ti species into extraframework Ti species was detected by the spectroscopic methods. However, the extraframework Ti species were still in a highly dispersed state after the hydrothermal and thermal treatments as shown by TEM images, while the formation of new acid sites was not detected. Upon combining the results of characterization with catalytic performance of HTS, the main deactivation reason for this material had been determined, which might be attributed to the reduction of specific surface area and active centers after basic treatment and calcination of HTS samples. And then the possible mechanism of simulated deactivation of HTS zeolite was proposed, which could describe the elemental reaction steps much more visually and directly.

Phase Separation Behavior of Cocamidopropyl Betaine/Water/Polyethylene Glycol System

Phase separation behavior of cocamidopropyl betaine/water/polyethylene glycol （PEG） system was studied. The effects of concentration and molecular weight of PEG on the phase separation behavior were investigated. Clouding occurred when the concentration of PEG was large enough in the betaine aqueous solution, and the concentration of PEG at cloud point decreased with the increase of PEG molecular weight for a constant betaine concentration. The bottom phase was the PEG-rich phase, and the upper phase was the betaine-rich phase. The volumetric ratio of PEG-rich phase to betaine-rich phase, at the same difference between the PEG concentration and the one at the cloud poim, △Ccp （0.1 g.ml^-1）, decreased as the PEG molecular weight increased and approached 1 for higher PEG molecular Weiglai （about 20000）, which was similar to the typicai-aqueous two-phase system. This volumetric ratio depended on the initial PEG concentration, but independent of PEG molecular weight. The concentration ratio of betaine to PEG in both phases depended on the △Ccp independent of PEG molecular weight.

Frictional Behavior of Sunflower Seed and its Kernel as a Function of Moisture Content, Variety and Size

The object of this study was to investigate the frictional properties （repose angles and friction coefficient） of Iranian sunflower seed and its kernel （Fandoghi, Azargol and Shahroodi） as a function of moisture content, size and variety. The static coefficient of friction were determined on five structural surfaces including aluminium, plywood, galvanized iron, polyethylene and rubber when moisture content varied between 3 and 14 % d.b. The obtained results showed that static coefficient of friction on five studied surfaces increase linearly as moisture content increase from 3 to 14% for both seed and kernel. Among the applied surfaces, rubber showed the highest value of friction coefficient for both sunflower seed and kernel followed by plywood, polyethylene, galvanized iron and aluminium. The obtained values of emptying and filling angles of repose increase linearly with an increase in moisture content. Furthermore, the values of empting and filling angles of repose for small sizes were higher than big sizes in all levels of moisture content for both seed and kernel. Also, the emptying angle of repose assumed higher values than the filling angle of repose for all varieties and categories.

Game Modeling and Strategic Behavior Analysis in Public Goods Provision： Evidence From Water Resources Management

The utility of public goods vary with the behaviors of stakeholders （players）, and it is appropriate to study effective supply and management of public goods with game modeling and analysis. The comparison effect is the key issue of public good provision both in theoretical analysis and in practice. One major contribution of the paper is the extension of Clarke-Groves mechanism, to achieve which strategic behavior analysis is applied through the analysis and the comparison effect among various stakeholders in different stages is created and highly emphasized. In the first section of this paper, the definition of integrated water resources management （IWRM）, the importance of stakeholder participation as well as some models and methods that have been applied are illustrated. Following this, the framework of analysis is elaborated, in which the scenario and aims are shown, and it is claimed that game theory is the main approach, which includes both cooperative games and non-cooperative games. To achieve the aims of the public project, five approaches from game theory are able to cover the entire process of the project, and the fourth approach on interest compensation mechanism is the highlight of the research. After this, the interest compensation mechanism is demonstrated in the model section, and is proved to be an incentive compatible mechanism that makes each stakeholder choose to behave in accordance with the interest of the entire project. The Clarke-Groves mechanism is applied and extended in establishing the model, and the utility change by the comparison among stakeholders （defined as the comparison effect） is involved. In the application section, a water project is analyzed in consideration of various stakeholders, and other possible applications are also indicated.

Prediction of Thermal Behavior of Pyrolyzed Wet Biomass by Means of Model with Inner Wood Structure

A simplified one-dimensional transient model for biomass pyrolysis in a fixed bed cylindrical reactor has been formulated and experiments have been carded out to verify the calculation results regarding temperature distribu- tion. The mathematical model accounts for mass, momentum and heat transfer, including moisture evaporation and convection of pyrolysis gases. Numerical simulation has allowed to predict temperature and heat flux distri- bution, and the dynamics of feedstock devolatilization. Special attention has been devoted to the analysis of the effect of biomass moisture content on the pyrolysis process. The model of moisture vaporization in biomass bed was proposed, which included structure of surface of biomass particles. Assuming that vaporization occurs on the border of the dry and wet areas of the bed, the flux of water vaporization depends on the specific surface area of the particles and overall heat flux.

Soil Wetting Patterns and Water Distribution as Affected by Irrigation for Uncropped Ridges and Furrows

The ridge-furrow tillage combined with furrow irrigation is being more widely applied and has been shown to be effective in the Loess Plateau of China. Accurate characterization of water infiltration behavior under ridge-furrow irrigation could provide guidelines and criteria for future irrigation system design and operation. Our objective was to investigate soil water behavior during ponding infiltration in a cross-sectional ridge-furrow configuration. Soil water movement within three different soil textures was tested by tracking the spatial and temporal soil water content(SWC) variations in a soil chamber. The two-dimensional transient flow initially transferred rapidly, but gradually decreased with elapsed infiltration time, approaching a stable flow after 90 min. A technical parameter equation incorporating the Philip equation was developed using the water balance method to accurately predict total applied water volume(TAWV). The wetting patterns moved outward in an elliptical shape. The wetted lateral and downward distances fitted using equations accounted for capillary and gravitational driving forces in variably wetted soil media. Increasing initial SWC resulted in an increase in wetted soil volume, which can also be caused by decreasing bulk density in a homogeneous soil. Higher water level produced greater wetted lateral distance and more irrigation uniformity. The wetted lateral distance was almost identical to the wetted depth in silty clay loam soil; hence ridge-furrow irrigation should be implemented in such finer-textured soils. The wetted soil volume differed markedly among different soil textures(hydraulic properties), demonstrating that these properties can largely determine soil water spreading patterns and distribution.

Effects of water content on the dissolution behavior of wool keratin using 1-ethyl-3-methylimidazolium dimethylphosphate

Ionic liquids(ILs) are eco-friend and recyclable solvents for dissolution of wool keratin, and water is often used as antisolvent to regenerate keratin from IL solution. To recycle the ILs, removing water is the necessary step. However, complete removal of the water is energy-intensive and costly. The water in ionic liquids would change the physicochemical properties and cluster structures of the IL and further affect its dissolution behavior on keratin. Here, 1-ethyl-3-methylimidazolium dimethylphosphate([Emim]DMP) was used for experiments due to its good performance on dissolving keratin. The experimental and simulation results showed that the dissolving capability of [Emim]DMP was decreased and the interactions between cation and anion became weaker with water concentration increasing. Furthermore, the dissolution time of wool keratin in [Emim]DMP increased with water content rising. At the same time, the effect of water in ILs on the secondary structure distribution and thermal stability of regenerated keratin was not obvious. In this work, by taking the structures of [Emim]DMP, keratin dissolution time and properties of the regenerated keratin into consideration, a balanced range of water content in [Emim]DMP was determined, which could not only reduce recycling cost but also not affect the dissolution behavior of the IL.

Influence of water content and shear rate on the mechanical behavior of soil-rock mixtures

Soil-rock mixtures(S-RMs) are widely distributed in the nature. The mesoscopic deformation and failure mechanisms as well as the macro-mechanical behaviors of the S-RMs depend largely upon the rate of deformation, water content and particle sizes. In this research, a series of large-scale direct shear tests with different water contents and different grain-size distributions were conducted to study the influence of the aforementioned factors on the mechanical properties of the S-RMs. Due to the effect of the rock blocks' breakage in the S-RMs, the relationship between the shear strength and the vertical stress of S-RM follows a power law instead of a linear one. It is found that there exists a threshold value for the vertical stress during the shearing process,below which the soil strength is mainly determined by the inter-locking of particles and the re-arrangement of meso-structure,and otherwise large-sized rock blocks are gradually broken into smaller fragments, resulting in a decrease in the soil strength.The shear rate can also significantly influence the degree of particle breakage and the meso-structural rearrangement of the SRMs, namely, under low shear rate, the particles of the samples are fully broken resulting in enhanced macro-strength. As a result, the lower the shear rate, the higher the macroscopic strength. So under unsaturated conditions, the water content will affect the strength of the S-RMs by reducing the strength of rock blocks. As the water content increases, the soil strength decreases gradually, and assumes a moderate value when the water content reaches 8%. At the same water content, the soil strength increases with the sizes of large rock blocks. For the occlusion, breakage and structure re-arrangement of the oversized rock blocks inside S-RM, which have a huge influence on the mechanical characteristics of the samples.

Analysis of the Water Film Behavior and its Breakup on Profile using Experimental and Numerical Methods

This paper deals with the description of water film behaviour on the airfoil NACA0012 using experimental and numerical methods. Properties of the water film on the profile and its breakup into droplets behind the profile are investigated in the aerodynamic tunnel and using CFD methods. The characteristic parameters of the water film, like its thickness and shape for different flow modes are described. Hereafter are described droplets drifted by the air, which water film is broken behind the profile.