Relationship between the activity for photocatalytic H_(2)O overall splitting(HOS)and the electron occupancy on d orbits of the active component in photocatalysts shows volcanic diagram,and specially the d^(10)electro...Relationship between the activity for photocatalytic H_(2)O overall splitting(HOS)and the electron occupancy on d orbits of the active component in photocatalysts shows volcanic diagram,and specially the d^(10)electronic configuration in valley bottom exhibits inert activity,which seriously fetters the development of catalytic materials with great potentials.Herein,In d^(10)electronic configuration of In_(2)O_(3)was activated by phosphorus atoms replacing its lattice oxygen to regulate the collocation of the ascended In 5p-band(Inɛ5p)and descended O 2p-band(Oɛ2p)centers as efficient active sites for chemisorption to*OH and*H during forward HOS,respectively,along with a declined In 4d-band center(Inɛ4d)to inhibit its backward reaction.A stable STH efficiency of 2.23%under AM 1.5 G irradiation at 65°C has been obtained over the activated d^(10)electronic configuration with a lowered activation energy for H_(2)evolution,verified by femtosecond transient absorption spectroscopy,in situ diffuse reflectance infrared Fourier transform spectroscopy and theoretical calculations of dynamics.These findings devote to activating d^(10)electronic configuration for resolving the reaction energy barrier and dynamical bottleneck of forward HOS,which expands the exploration of high-efficiency catalytic materials.展开更多
For the flow field in a d50 mm hydrocyclone, numerical studies based on computational fluid dynamics (CFD) simulation and experimental studies based on particle image velocimetry (PIV) measurement were carried out res...For the flow field in a d50 mm hydrocyclone, numerical studies based on computational fluid dynamics (CFD) simulation and experimental studies based on particle image velocimetry (PIV) measurement were carried out respectively. The results of two methods show that air core generally forms after 0.7 s, the similar characteristics of air core can be observed. Vortexes and axial velocity distributions obtained by numerical and experimental methods are also in good agreement. Studies of different parameters based on CFD simulation show that tangential velocity distribution inside the hydrocyclone can be regarded as a combined vortex. Axial and tangential velocities increase as the feed rate increases. The enlargement of cone angle and overflow outlet diameter can speed up the overflow discharge rate. The change of underflow outlet diameter has no significant effect on axial and tangential velocities.展开更多
With abundant wind resources and high pressure imposed on en-vironmental protection, wind power development has a promising future. Butdue to intermittent nature, wind power can bring into full play only if being con-...With abundant wind resources and high pressure imposed on en-vironmental protection, wind power development has a promising future. Butdue to intermittent nature, wind power can bring into full play only if being con-nected into power grid to ensure its supply reliability and continuity, aswell as operational economy. However, technical and market barriers haveprevented wind power from integrating into power grid. To foster wind powerdevelopment, these barriers should be removed by both government incentivepolicies and sophisticated technologies.展开更多
Confined water in the Ordovician limestone is one of the hidden troubles that threaten safe production of mines in north China. A numerical model of the key strata was developed. It included the structural characteris...Confined water in the Ordovician limestone is one of the hidden troubles that threaten safe production of mines in north China. A numerical model of the key strata was developed. It included the structural characteristics and mechanical properties of the floor rock at the working face of a particular coal mine. The model was used to predict failure modes and to help establish rules for safe mining above the aquifer. The distribution of deformation, failure and seepage was simulated by using Dilian Mechsoft's Real- istic Failure Process Analysis (RFPA2D) program. The stress distribution, the deformation and the flow vectors were also obtained. The results indicate that: 1) The original balance of the stress and seepage fields is disturbed due to coal mining; and 2) As the working face advances different deformation, or failure, appears in the surrounding rocks, the water-resisting strata in floor may be destroyed and the passage of water from the aquifer into the mine may occur. The combined action of mining stress and water pressure ultimately lead to water inrush from the floor.展开更多
Based on the theory of Canonical Correlation Analysis (CCA), the correlation between 500 hPa geopotential height (H) fields over the Northern Hemisphere (NH) and a 15-region rainfall (R) field of China in May is studi...Based on the theory of Canonical Correlation Analysis (CCA), the correlation between 500 hPa geopotential height (H) fields over the Northern Hemisphere (NH) and a 15-region rainfall (R) field of China in May is studied. The results indicate that: (1) there is a strong relationship between the H fields in January / May and the R field in China, (2) the variation of the general circulation over the whole NH (especially the 500 hPa H field over Europe and Asia) can affect the R in China, (3) in January and February the atmospheric general circulation can affect the R mainly by means of planetary waves, while in April and May the main control mechanism can be due to some teleconnections, and (4) the characteristic vectors for R in May and H from January to May have wave train structure, alternating sign from south to north.展开更多
A mathematical model of podded propulsors was established in order to investigate the influence of fins. The hydrodynamic performance of podded propulsors with and without fins was calculated, with interactions betwee...A mathematical model of podded propulsors was established in order to investigate the influence of fins. The hydrodynamic performance of podded propulsors with and without fins was calculated, with interactions between propellers and pods and fins derived by iterative calculation. The differential equation based on velocity potential was adopted and hyperboloidal panels were used to avoid gaps between surface panels. The Newton-Raphson iterative procedure was used on the trailing edge to meet the pressure Kutta condition. The velocity distribution was calculated with the Yanagizawa method to eliminate the singularity caused by use of the numerical differential. Comparisons of the performance of podded propulsors with different fins showed that the thrust of propeller in a podded propulsor with fins is greater. The resistance of the pod is also reduced because of the thrust of the fin. The hydrodynamic performance of a podded propulsor with two fins is found to be best, the performance of a podded propulsor with one fin is not as good as two fins, and the performance of the common type is the worst.展开更多
Based on the impact of the stress perturbation effect created by simultaneous propagation of multiple fractures in the process of simultaneous hydraulic fracturing, a thorough research on the mechanism and adaptation ...Based on the impact of the stress perturbation effect created by simultaneous propagation of multiple fractures in the process of simultaneous hydraulic fracturing, a thorough research on the mechanism and adaptation of simultaneous fracturing of double horizontal wells in ultra-low permeability sandstone reservoirs was conducted by taking two adjacent horizontal wells(well Yangping-1 and well Yangping-2 located in Longdong area of China Changqing Oilfield) as field test wells. And simultaneous fracturing optimal design of two adjacent horizontal wells was finished and employed in field test. Micro-seismic monitoring analysis of fracture propagation during the stimulation treatment shows that hydraulic fractures present a pattern of complicated network expansion, and the well test data after fracturing show that the daily production of well Yangping-1 and well Yangping-2 reach105.8 t/d and 87.6 t/d, which are approximately 9.4 times and 7.8 times the daily production of a fractured vertical well in the same area, respectively. Field test reflects that simultaneous hydraulic fracturing of two adjacent horizontal wells can enlarge the expansion area of hydraulic fractures to obtain a lager drainage area and realize the full stimulation of ultra-low permeability sandstone reservoirs in China Changqing oilfield. Therefore, simultaneous fracturing of two adjacent horizontal wells provides a good opportunity in stimulation techniques for the efficient development of ultra-low permeability reservoirs in China Changqing oilfield,and it has great popularization value and can provide a new avenue for the application of stimulation techniques in ultra-low permeability reservoirs in China.展开更多
By establishing a 3-dimensional hydrodynamic model of the Hongtang Bay and the validation tests,tidal currents of the area before and after the construction of the Sanya new airport project,which include two artificia...By establishing a 3-dimensional hydrodynamic model of the Hongtang Bay and the validation tests,tidal currents of the area before and after the construction of the Sanya new airport project,which include two artificial islands built respectively to accommodate the airport and its connected technology park,are simulated.The hydrodynamic impacts of the islands on the Hongtang Bay and surrounding waters were analyzed by comparing flow fields and velocities of tidal currents under the two conditions.展开更多
Caving of mine roofs from water inrush due to anomalous pressure is one of the major disasters and accidents that can occur in mines during production.Roof water inrush can trigger a wide range of roof collapse,causin...Caving of mine roofs from water inrush due to anomalous pressure is one of the major disasters and accidents that can occur in mines during production.Roof water inrush can trigger a wide range of roof collapse,causing major accidents from breaking roof supports while caving.These failures flood wells and do a great deal of damage to mines and endanger mine safety.Our objective is to analyze the anomalies of water inrush crushing the support at the #6301 working face in the Jisan Coal Mine of the Yanzhou Mining Group.Through information of water inrush to the roof,damage caused by tectonic movements,information on the damage caused by roof collapse and the theory about the distribution of pressure in mine abutments,we advice adjusting the length of the working face and the position of open-off cut relatively to the rich water area.In the case of anomalous roof pressure we should develop a state equation to estimate preventive measures with＂transferring rock beam＂theory.Simultaneously, we improve the capacity of drainage equipment and ensured adequate water retention at the storehouse. These are all major technologies to ensure the control and prevention against accidents caused by anomalous water inrush in roofs,thus ensuring safety in the production process of a coal mine.展开更多
In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hyd...In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hydro-mechanical （THM） processes in saturated and unsaturated porous media were extended and improved through introducing the percolation and migration equation, so that the code can be used for solving the temperature field, flow field, stress field and nuclide concentration field simultaneously. The states of temperatures, pore pressures and nuclide concentrations in the near field of a hypothetical nuclear waste repository were investigated. The influence of the half life of the radioactive nuclide on the temporal change of nuclide concentration was analyzed considering the thermo-hydro-mechanical-migratory coupling. The results show that, at the boundary of the vitrified waste, the concentration of radioactive nuclide with a half life of 10 a falls after a period of rising, with the maximum value of 0.182 mol/m3 and the minimum value of 0.181 mol/m^3 at the end of computation. For a half life of 1 000 a, the concentration of radioactive nuclide always increases with the increase of the time during the computation period; and the maximum value is 1.686 mol/m^3 at the end of the computation. Therefore, under the condition of THM coupling, the concentration of radioactive nuclide with a shorter half life will decrease more quickly with water flow; but for the radioactive nuclide with a longer half life, its concentration will keep at a higher level for a longer time in the migration process.展开更多
The elevated supersaturation of total dissolved gas （TDG） downstream of a high-dam spill has deleterious effects on fish in a large range. A one-dimensional （l-D） longitudinal model is optimal for the prediction o...The elevated supersaturation of total dissolved gas （TDG） downstream of a high-dam spill has deleterious effects on fish in a large range. A one-dimensional （l-D） longitudinal model is optimal for the prediction of supersaturated TDG dissipation over a long distance. The key issue of the model is to determine the dissipation coefficient accurately. In agreement with field observations and experiment data, dimensional analysis and regression were performed to propose a formula for estimating the dissipation coefficient of supersaturated TDG in various rivers and reservoirs, and it involves the effects of the turbulence intensity, the hydro-pressure and the solid-liquid interface. The friction velocity, water depth, hydraulic radius and Froude number are independent variables in the formula which are easy to determine in practical applications. The 1-D longitudinal model is implemented to calculate the dissipation of TDG in a reach of the Jinsha River. Good agreement is found between the calculated results and field data for both the dissipation coefficient and the dissipation process.展开更多
文摘Relationship between the activity for photocatalytic H_(2)O overall splitting(HOS)and the electron occupancy on d orbits of the active component in photocatalysts shows volcanic diagram,and specially the d^(10)electronic configuration in valley bottom exhibits inert activity,which seriously fetters the development of catalytic materials with great potentials.Herein,In d^(10)electronic configuration of In_(2)O_(3)was activated by phosphorus atoms replacing its lattice oxygen to regulate the collocation of the ascended In 5p-band(Inɛ5p)and descended O 2p-band(Oɛ2p)centers as efficient active sites for chemisorption to*OH and*H during forward HOS,respectively,along with a declined In 4d-band center(Inɛ4d)to inhibit its backward reaction.A stable STH efficiency of 2.23%under AM 1.5 G irradiation at 65°C has been obtained over the activated d^(10)electronic configuration with a lowered activation energy for H_(2)evolution,verified by femtosecond transient absorption spectroscopy,in situ diffuse reflectance infrared Fourier transform spectroscopy and theoretical calculations of dynamics.These findings devote to activating d^(10)electronic configuration for resolving the reaction energy barrier and dynamical bottleneck of forward HOS,which expands the exploration of high-efficiency catalytic materials.
基金Projects(50974033,51104035)supported by the National Natural Science Foundation of China
文摘For the flow field in a d50 mm hydrocyclone, numerical studies based on computational fluid dynamics (CFD) simulation and experimental studies based on particle image velocimetry (PIV) measurement were carried out respectively. The results of two methods show that air core generally forms after 0.7 s, the similar characteristics of air core can be observed. Vortexes and axial velocity distributions obtained by numerical and experimental methods are also in good agreement. Studies of different parameters based on CFD simulation show that tangential velocity distribution inside the hydrocyclone can be regarded as a combined vortex. Axial and tangential velocities increase as the feed rate increases. The enlargement of cone angle and overflow outlet diameter can speed up the overflow discharge rate. The change of underflow outlet diameter has no significant effect on axial and tangential velocities.
文摘With abundant wind resources and high pressure imposed on en-vironmental protection, wind power development has a promising future. Butdue to intermittent nature, wind power can bring into full play only if being con-nected into power grid to ensure its supply reliability and continuity, aswell as operational economy. However, technical and market barriers haveprevented wind power from integrating into power grid. To foster wind powerdevelopment, these barriers should be removed by both government incentivepolicies and sophisticated technologies.
基金Projects 504902750634050 supported by the National Natural Science Foundation of China+1 种基金2007CB209400 by the National Basic Research Programof China2006A038 by SR Foundation of China University of Mining & Technology
文摘Confined water in the Ordovician limestone is one of the hidden troubles that threaten safe production of mines in north China. A numerical model of the key strata was developed. It included the structural characteristics and mechanical properties of the floor rock at the working face of a particular coal mine. The model was used to predict failure modes and to help establish rules for safe mining above the aquifer. The distribution of deformation, failure and seepage was simulated by using Dilian Mechsoft's Real- istic Failure Process Analysis (RFPA2D) program. The stress distribution, the deformation and the flow vectors were also obtained. The results indicate that: 1) The original balance of the stress and seepage fields is disturbed due to coal mining; and 2) As the working face advances different deformation, or failure, appears in the surrounding rocks, the water-resisting strata in floor may be destroyed and the passage of water from the aquifer into the mine may occur. The combined action of mining stress and water pressure ultimately lead to water inrush from the floor.
基金Project "973" (G1998040905) a project of the Chinese Academy of Sciences (KZCX2-203) Natural Science Foundation of China (40065001)
文摘Based on the theory of Canonical Correlation Analysis (CCA), the correlation between 500 hPa geopotential height (H) fields over the Northern Hemisphere (NH) and a 15-region rainfall (R) field of China in May is studied. The results indicate that: (1) there is a strong relationship between the H fields in January / May and the R field in China, (2) the variation of the general circulation over the whole NH (especially the 500 hPa H field over Europe and Asia) can affect the R in China, (3) in January and February the atmospheric general circulation can affect the R mainly by means of planetary waves, while in April and May the main control mechanism can be due to some teleconnections, and (4) the characteristic vectors for R in May and H from January to May have wave train structure, alternating sign from south to north.
基金Supported by the National Natural Science Foundation of China under Grant No.10702016
文摘A mathematical model of podded propulsors was established in order to investigate the influence of fins. The hydrodynamic performance of podded propulsors with and without fins was calculated, with interactions between propellers and pods and fins derived by iterative calculation. The differential equation based on velocity potential was adopted and hyperboloidal panels were used to avoid gaps between surface panels. The Newton-Raphson iterative procedure was used on the trailing edge to meet the pressure Kutta condition. The velocity distribution was calculated with the Yanagizawa method to eliminate the singularity caused by use of the numerical differential. Comparisons of the performance of podded propulsors with different fins showed that the thrust of propeller in a podded propulsor with fins is greater. The resistance of the pod is also reduced because of the thrust of the fin. The hydrodynamic performance of a podded propulsor with two fins is found to be best, the performance of a podded propulsor with one fin is not as good as two fins, and the performance of the common type is the worst.
基金Project(51404204)supported by the National Natural Science Foundation of ChinaProject(20135121120002)supported by Specialized Research Fund for the Doctoral Program of Higher Education of ChinaProject(2014QHZ005)supported by Scientific Research Starting Projecting of SWPU,China
文摘Based on the impact of the stress perturbation effect created by simultaneous propagation of multiple fractures in the process of simultaneous hydraulic fracturing, a thorough research on the mechanism and adaptation of simultaneous fracturing of double horizontal wells in ultra-low permeability sandstone reservoirs was conducted by taking two adjacent horizontal wells(well Yangping-1 and well Yangping-2 located in Longdong area of China Changqing Oilfield) as field test wells. And simultaneous fracturing optimal design of two adjacent horizontal wells was finished and employed in field test. Micro-seismic monitoring analysis of fracture propagation during the stimulation treatment shows that hydraulic fractures present a pattern of complicated network expansion, and the well test data after fracturing show that the daily production of well Yangping-1 and well Yangping-2 reach105.8 t/d and 87.6 t/d, which are approximately 9.4 times and 7.8 times the daily production of a fractured vertical well in the same area, respectively. Field test reflects that simultaneous hydraulic fracturing of two adjacent horizontal wells can enlarge the expansion area of hydraulic fractures to obtain a lager drainage area and realize the full stimulation of ultra-low permeability sandstone reservoirs in China Changqing oilfield. Therefore, simultaneous fracturing of two adjacent horizontal wells provides a good opportunity in stimulation techniques for the efficient development of ultra-low permeability reservoirs in China Changqing oilfield,and it has great popularization value and can provide a new avenue for the application of stimulation techniques in ultra-low permeability reservoirs in China.
文摘By establishing a 3-dimensional hydrodynamic model of the Hongtang Bay and the validation tests,tidal currents of the area before and after the construction of the Sanya new airport project,which include two artificial islands built respectively to accommodate the airport and its connected technology park,are simulated.The hydrodynamic impacts of the islands on the Hongtang Bay and surrounding waters were analyzed by comparing flow fields and velocities of tidal currents under the two conditions.
基金sponsored by the National Natural Science Foundation of China(No.50874021 )the Program for New Century Excellent Talents in University(No.NCET-08-0833)the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT0656) of the Ministry of Education of China.
文摘Caving of mine roofs from water inrush due to anomalous pressure is one of the major disasters and accidents that can occur in mines during production.Roof water inrush can trigger a wide range of roof collapse,causing major accidents from breaking roof supports while caving.These failures flood wells and do a great deal of damage to mines and endanger mine safety.Our objective is to analyze the anomalies of water inrush crushing the support at the #6301 working face in the Jisan Coal Mine of the Yanzhou Mining Group.Through information of water inrush to the roof,damage caused by tectonic movements,information on the damage caused by roof collapse and the theory about the distribution of pressure in mine abutments,we advice adjusting the length of the working face and the position of open-off cut relatively to the rich water area.In the case of anomalous roof pressure we should develop a state equation to estimate preventive measures with＂transferring rock beam＂theory.Simultaneously, we improve the capacity of drainage equipment and ensured adequate water retention at the storehouse. These are all major technologies to ensure the control and prevention against accidents caused by anomalous water inrush in roofs,thus ensuring safety in the production process of a coal mine.
基金Project(2010CB732101) supported by the National Basic Research Program of China Project(SKLQ 008) supported by the Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering of China
文摘In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hydro-mechanical （THM） processes in saturated and unsaturated porous media were extended and improved through introducing the percolation and migration equation, so that the code can be used for solving the temperature field, flow field, stress field and nuclide concentration field simultaneously. The states of temperatures, pore pressures and nuclide concentrations in the near field of a hypothetical nuclear waste repository were investigated. The influence of the half life of the radioactive nuclide on the temporal change of nuclide concentration was analyzed considering the thermo-hydro-mechanical-migratory coupling. The results show that, at the boundary of the vitrified waste, the concentration of radioactive nuclide with a half life of 10 a falls after a period of rising, with the maximum value of 0.182 mol/m3 and the minimum value of 0.181 mol/m^3 at the end of computation. For a half life of 1 000 a, the concentration of radioactive nuclide always increases with the increase of the time during the computation period; and the maximum value is 1.686 mol/m^3 at the end of the computation. Therefore, under the condition of THM coupling, the concentration of radioactive nuclide with a shorter half life will decrease more quickly with water flow; but for the radioactive nuclide with a longer half life, its concentration will keep at a higher level for a longer time in the migration process.
基金Projects(51179111,51279115)supported by the National Natural Science Foundation of ChinaProject(20110181110073)supported by the Doctoral Programs Foundation of Ministry of Education of China
文摘The elevated supersaturation of total dissolved gas （TDG） downstream of a high-dam spill has deleterious effects on fish in a large range. A one-dimensional （l-D） longitudinal model is optimal for the prediction of supersaturated TDG dissipation over a long distance. The key issue of the model is to determine the dissipation coefficient accurately. In agreement with field observations and experiment data, dimensional analysis and regression were performed to propose a formula for estimating the dissipation coefficient of supersaturated TDG in various rivers and reservoirs, and it involves the effects of the turbulence intensity, the hydro-pressure and the solid-liquid interface. The friction velocity, water depth, hydraulic radius and Froude number are independent variables in the formula which are easy to determine in practical applications. The 1-D longitudinal model is implemented to calculate the dissipation of TDG in a reach of the Jinsha River. Good agreement is found between the calculated results and field data for both the dissipation coefficient and the dissipation process.
