In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction in...In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction intensity under control. The reaction performances with respect to apparent kinetics and selectivity are determined to explore optimized reaction conditions and confirm potentials for enhancing productivity in one batch. The dissolution and liquid phase reaction mechanism and instant reaction assumption are proposed and verified through process analysis. A process design towards free additional water is schematically figured out to manipulate solid NaOH, by-product,and unreacted starting materials to realize a nearly closed circuit. This process allows high selectivity over 97% and complete DCP conversion at 323.2 K within a reaction time less than 20 min. Other advantages include near-zero wastewater emission, economically possible NaOH regeneration from NaCl, and robust operating condition window.展开更多
The demand for energy, water and food will continuously increase, as the prediction states that 2.5 billion people will be added to the world population by 2050, representing not only an increase in the consumption bu...The demand for energy, water and food will continuously increase, as the prediction states that 2.5 billion people will be added to the world population by 2050, representing not only an increase in the consumption but also more waste production, greenhouse gas （GHG） emissions and depletion of natural resources. Taking into account that renewable sources of energy can help to overcome these challenges and diversify the energy matrix in the countries, this paper aims at analyzing the biogas potential in Brazil and the United States, especially in the livestock sector, and its benefits in the environmental, social and economic aspects. Both countries are among the top five countries globally in terms of water availability, energy consumption and food production. Until 2050, the world consumption of meat will have a significant increase： 206% of poultry meat, 56% of pork meat and 47% of beef meat, augmenting the need for sustainable management of waste and manure. This scenario can become a sustainable opportunity for biogas implementation, which provides multiple economic, environmental and social benefits for farmers, businesses and communities, including production of electrical, thermal and vehicular energy, production of high-quality biofertilizer, reduction of ground and surface water pollution and reduction of GHG emissions, and foments new income for the farmers, among others. A new concept is presented in this article to make biogas systems feasible, i.e., biogas condominiums, as small and medium-scale farms by themselves usually would not be able to afford the investments. This arrangement can bring benefits for the whole biogas supply chain that includes farmers, agroindustry, providers and local community.展开更多
基金Supported by the National Natural Science Foundation of China(21176136,21422603)the National Science and Technology Support Program of China(2011BAC06B01)
文摘In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction intensity under control. The reaction performances with respect to apparent kinetics and selectivity are determined to explore optimized reaction conditions and confirm potentials for enhancing productivity in one batch. The dissolution and liquid phase reaction mechanism and instant reaction assumption are proposed and verified through process analysis. A process design towards free additional water is schematically figured out to manipulate solid NaOH, by-product,and unreacted starting materials to realize a nearly closed circuit. This process allows high selectivity over 97% and complete DCP conversion at 323.2 K within a reaction time less than 20 min. Other advantages include near-zero wastewater emission, economically possible NaOH regeneration from NaCl, and robust operating condition window.
文摘The demand for energy, water and food will continuously increase, as the prediction states that 2.5 billion people will be added to the world population by 2050, representing not only an increase in the consumption but also more waste production, greenhouse gas （GHG） emissions and depletion of natural resources. Taking into account that renewable sources of energy can help to overcome these challenges and diversify the energy matrix in the countries, this paper aims at analyzing the biogas potential in Brazil and the United States, especially in the livestock sector, and its benefits in the environmental, social and economic aspects. Both countries are among the top five countries globally in terms of water availability, energy consumption and food production. Until 2050, the world consumption of meat will have a significant increase： 206% of poultry meat, 56% of pork meat and 47% of beef meat, augmenting the need for sustainable management of waste and manure. This scenario can become a sustainable opportunity for biogas implementation, which provides multiple economic, environmental and social benefits for farmers, businesses and communities, including production of electrical, thermal and vehicular energy, production of high-quality biofertilizer, reduction of ground and surface water pollution and reduction of GHG emissions, and foments new income for the farmers, among others. A new concept is presented in this article to make biogas systems feasible, i.e., biogas condominiums, as small and medium-scale farms by themselves usually would not be able to afford the investments. This arrangement can bring benefits for the whole biogas supply chain that includes farmers, agroindustry, providers and local community.
