佳木斯市区地下水水化学系统的探讨

众所周知,在地下水资源的评价、开发、管理中,系统方法被广泛运用。但都是单纯的地下水数量系统的模拟,而对地下水水化学系统的分析,却无人研究。以佳木斯市区为例,对此进行了探讨。

四平市浅层地下水系统研究

四平市浅层地下水系统研究主要包括地下水系统的划分和地下水系统特征两个方面。本文根据四平市水文地质条件,探讨了四平市地下水系统划分的原则,即拥有独立的含水层系统和完整的水循环系统。亚系统划分主要依据地下水分水岭和一级河流流域分水岭,子系1统则考虑了含水介质和水力条件。基于此,四平市地下水系统共划分为四个亚系统和九个子系统。此外,地下水系统特征主要从四个角度进行阐述:含水层系统特征;系统边界特征;水循环系统特征;水化学系统特征。

Spatiotemporal pattern of bacterioplankton in Donghu Lake

Bacterioplankton play key roles in the biogeochemical cycle and in organic contaminant degradation. The species richness and abundance of bacterial subgroups are generally distinct from each other, and this is attributed to their different functions in aquatic ecosystems. The spatiotemporal variations of eight phylogenetic subgroups （Actinobacteria, Bacteroidetes, Cyanobacteria, Firmicutes, Planctomycetes, alpha-, beta-, and gamma-Proteobacteria） derived from Donghu Lake were investigated using PCR-DGGE fingerprinting, to explore their responses to environmental factors. Results indicate that Actinobacteria and beta-Proteobacteria were the two largest bacterial subgroups detected. These two groups and Bacteroidetes showed clear seasonal patterns in composition of the operational taxonomic unit. Results also suggest that the bacterioplankton subgroups in Donghu Lake were significantly correlated with different environmental factors. In brief, the total nitrogen was one of the major factors regulating all the bacterioplankton except for Actinobacteria. However, total phosphorus, another important eutrophication factor, contributed to the two largest bacterial groups （Actinobacteria and beta-Proteobacteria）, as well as to the Cyanobacteria and Firmicutes. Therefore, the responses of bacterioplankton subgroups to environmental factors were different, and this should be attributed to the differences in the fimctions of different groups.

Real-solution stability diagrams for copper-ammonia-chloride-water system

A comprehensive thermodynamic model, which combined the Helgeson Kirkham-Flowers （HKF） equation of state for standard-state thermodynamic properties of all species with realistic activity coefficient model developed by BROMLEY, was used to calculate the thermodynamic equilibrium, and a graphical method was developed to construct predominance existence diagrams （PED） for copper-ammonia-chloride in the presence of realistically modeled aqueous solutions. The existence of the different predominant chemical species for Cu（lI） predicted by the diagrams was corroborated by spectrophotometrical studies and X-ray diffractometry. The simulated and experimental results indicate that the predominance of a given species in solution strongly depends on the pH value in this system. More quantitative information on real copper hydrometallurgy in the presence of ammonia and chloride can be obtained from these diagrams compared with the conventional predominance existence diagrams.

Quantity and Quality of Water in the River LermamLake Chapala Watershed, Mexico

Water overexploitation in the Lerma-Chapala Watershed, located in central Mexico, is linked to the development of a strong federal hydrocracy with the mission to capture as much water as possible in order to satisfy social and political demands through the construction of dams and irrigation systems. The reduction in freshwater quantity and the deterioration of water quality are the outcome of industrial inflows, agriculture and urban untreated wastewater. This study has been leaded to determine hydrological, water quality, seed bioassays and the lake fisheries＇ decreases throughout its historical tendencies （1980-2004） in relation to changes in water levels. Hydrological data and water samples for chemical analysis, inorganic nutrients and seed bioassay, were taken from 10 sites alongside the river and two sites from Lake Chapala in years 2005 and 2009, the WQINsF （National Sanitation Foundation Water Quality Index） was estimated. The dissolved oxygen along the river was from anoxic （0.4） to 7 mg/L and the lake had 6.75 mg/L to 7.36 mg/L; the river had highest nutrients variations, Ntot and Ptot 1 mg/L to 〉 10 mg/L. The lake had few physicochemical variations and the lowest nutrient concentrations; WQINsF （water quality index） in the river-lake system showed very bad-bad quality and contamination in river, bad quality-light contamination in lake. Seed bioassays showed inhibition of root elongation and declining fisheries when low water levels were presented. Chapala Lake had better physicochemical and limnological conditions because of the wind action and water column mixing; in contrast the river, high hidrological variations caused by water administration in middle basin.

Factors Impacting Water Quality of a Small Stream in a Mountain Forest

Recent improvements to sewerage systems have meant that the relative contribution of point sources of pollution to the overall pollutant loads of streams has decreased markedly. Consequently, the potential increase in non-point source pollution means that it may be necessary to focus more on pollution loads from non-point sources in the future. This study examined pollution loads from non-point sources in streams flowing through forested areas. In addition, the relationship between runoff and pollution loads was also clarified. The small streams in the Tohoku University Botanical Gardens, in Sendai city, Japan, were sampled during a dry weather period and their water quality parameters were characterized. Chemical Oxygen Demand （COD） concentration increased with distance downstream, possibly because the soils in downstream areas contained high amounts of organic matter. Conversely, the concentration of nitrate nitrogen （NO3-N） decreased with distance downstream, probably because upstream soils were generally in an oxidized state while those further downstream were reduced. COD concentration increased with air temperature, while NO3-N levels decreased with an increase in air temperatures.

Uniform design ray in the assessment of combined toxicities of multi-component mixtures

Multi-component mixture(MCM) is a complicated chemical system that contains a great deal of mixture rays with various mixture ratios, and each ray includes many mixtures with different concentration levels.Currently, in combined toxicity field, almost all studies on MCM focus on the mixtures designed by the equivalenteffect concentration ratio(EECR) procedure. However, the EECR mixtures cannot represent the whole mixture system because the EECR mixtures are located on one mixture ray in concentration space formed by multiple components. In our view, some optimal experimental design such as the uniform design(UD) should be used to effectively select many representative mixture rays from the MCM system,instead of single EECR ray. The uniform design ray(UDray) integrating UD idea with fixed-ratio ray design can systematically and comprehensively measure the combined toxicity changes in the MCM system. This review introduces the operation method, construction of uniform table and corresponding usable table, and some cases of application of the UD-ray to help readers easily use UD-ray in their MCM toxicity assessment.

The Challenging Topics and Future Directions of the Research in Limnology and Watershed Sciences

Based on reviewing the problems in limnology and watershed sciences in meeting the national demands and the development of theories and methodology, this paper proposed some challeng-ing topics to the sciences, covering the process of lake evolution and the quantitative analysis of hu-man impacts, in-lake nutrient cycling an biogeo-chemical process, the process and mechanisms of material flow in lake-watershed system, digital watershed and the modeling of the surface pro-cess of lake-watershed, and ecosystem health and scientific management of lake- watershed.

Effect of total phosphorous pollution on cavitation pressure characteristics of working water used in turbines

Many experiments have proven that with increasing silt and gas(out-of-phase media)content in water,the cavitation characteristics change and the cavitation pressure increases.Currently,many large reservoirs in China are polluted by total phosphorus(TP)and other chemical contaminants because of the use of phosphate fertilizer runoff from agriculture.However,research regarding how chemical pollutants(in the form of out-of-phase media)affect the cavitation pressure characteristics of water is sparse.In this paper,the Goupitan Hydropower Station,the largest hydropower reservoir on the Wujiang River,which is heavily polluted by TP,is taken as an example to evaluate the effects of chemical pollution on water cavitation pressure characteristics.In this study,the cavitation pressure characteristics of polluted and clean water are compared.The results show that the cavitation pressure of water polluted by chemicals is larger than that of clean water.In a hydraulic power generation system,cavitation and cavitation erosion are likely to occur earlier in runners when the fluid is polluted.These results are of great importance to further studies of cavitation theory and can directly influence the arrangement of turbines in practical engineering.

Photo-electrochemical water splitting system with three-layer n-type organic semiconductor film as photoanode under visible irradiation

A three-layer structure of n-type organic semiconductors （PTCDA/PTCDA：PCBM/PCBM） is successfully identified as pho- toanode for photoelectrochemical water oxidation during the overall splitting of water into hydrogen/oxygen in a nearly stoi- chiometric ratio （H2：O2 = 2：1） under visible irradiation （2 〉 420 nm）. A possible charge separation mechanism under visible light illumination was also proposed.