To investigate the effects of salt concentration and freeze-thaw (FT) on the first hydration shell of Zn2+ ions in Zn(NO_3)_2 aqueous solutions, extended X-ray absorption fine structure (EXAFS) spectroscopy was used t...To investigate the effects of salt concentration and freeze-thaw (FT) on the first hydration shell of Zn2+ ions in Zn(NO_3)_2 aqueous solutions, extended X-ray absorption fine structure (EXAFS) spectroscopy was used to examine Zn K-edge EXAFS spectra of Zn(NO_3)_2 aqueous solutions with various concentrations before and after FT treatment. The influences of salt concentration and freeze-thaw on the structural parameters of the first hydration shell of Zn2+ ions, including hydration number, Zn-O distance and thermal disorder, were analyzed. The results show that Zn2+ ions have 3.2―6.8 nearest oxygen neighbors with the Zn-O distance being 0.202―0.207 nm. In highly concen-trated solutions, Zn2+ ions are hydrated with four water molecules in a tetrahedral form. The dilution of Zn(NO_3)_2 aqueous solutions increases the number of water molecules in the first hydration shell of Zn2+ ions to six with their octahedral arrangement. Both the hydration number in the first hydration shell of Zn2+ ions and the degree of thermal disorder increase when the FT treatment is operated in Zn(NO_3)_2 aqueous solutions.展开更多
The present study is an investigation of the properties of poly(vinyl alcohol),which would be a better contact lens mate- rial than conventional HEMA in some ways.A transparent PVA hydrogel was prepared from a PVA sol...The present study is an investigation of the properties of poly(vinyl alcohol),which would be a better contact lens mate- rial than conventional HEMA in some ways.A transparent PVA hydrogel was prepared from a PVA solution in a mixed solvent consisting of water and a water-miscible organic solvent,DMSO,by the freezing-thawing method.The water content,visible light transmittance,mechanical and swelling properties of the hydrogels were evaluated as a function of PVA concentration and number of freeze-thaw cycles.The results show that the properties of PVA hydrogels depend on the polymer concentration,the number of freeze-thaw cycles and the addition of the organic solvent.展开更多
The Tibetan Plateau serves an important shelter function for the ecological security of Asia, and especially China. Here, we proposed and improved indicators and methods for assessing the ecological sensitivity and vu...The Tibetan Plateau serves an important shelter function for the ecological security of Asia, and especially China. Here, we proposed and improved indicators and methods for assessing the ecological sensitivity and vulnerability of the terrestrial alpine Plateau ecosystems and assessed the freeze-thaw erosion, land desertification, water-caused soil loss, and land salinization sensitivity, together with ecological vulnerability, from the overall ecological sensitivity, ecological pressure, and elasticity aspects in Tibet. The results indicate that the terrestrial ecosystem of Tibet is quite sensitive to freeze-thaw erosion, land desertification and water-caused soil loss. Extremely and highly sensitive regions account for 9.62% and 83.69%, respectively, of the total area of the Tibet Autonomous Region. Extremely and highly vulnerable areas account for 0.09% and 52.61%, respectively, primarily distributed in the Himalayan and Gangdise mountain regions in west Tibet; the Nyainqentanglha, Tanggula, Hoh Xil, and Kunlun mountain regions; and the northwest and northern regions of the Changtang Plateau. The results will aid the development of customized protection schedules according to different ecological issues in each region.展开更多
基金Supported by National Natural Science Foundation of China(No. 20776096)National Synchrotron Radiation Laboratory, China(No. 20081005G)
文摘To investigate the effects of salt concentration and freeze-thaw (FT) on the first hydration shell of Zn2+ ions in Zn(NO_3)_2 aqueous solutions, extended X-ray absorption fine structure (EXAFS) spectroscopy was used to examine Zn K-edge EXAFS spectra of Zn(NO_3)_2 aqueous solutions with various concentrations before and after FT treatment. The influences of salt concentration and freeze-thaw on the structural parameters of the first hydration shell of Zn2+ ions, including hydration number, Zn-O distance and thermal disorder, were analyzed. The results show that Zn2+ ions have 3.2―6.8 nearest oxygen neighbors with the Zn-O distance being 0.202―0.207 nm. In highly concen-trated solutions, Zn2+ ions are hydrated with four water molecules in a tetrahedral form. The dilution of Zn(NO_3)_2 aqueous solutions increases the number of water molecules in the first hydration shell of Zn2+ ions to six with their octahedral arrangement. Both the hydration number in the first hydration shell of Zn2+ ions and the degree of thermal disorder increase when the FT treatment is operated in Zn(NO_3)_2 aqueous solutions.
基金Projects 50575106 supported by the National Natural Science Foundation of ChinaBG2007046 by the High Technology Project of Jiangsu Province
文摘The present study is an investigation of the properties of poly(vinyl alcohol),which would be a better contact lens mate- rial than conventional HEMA in some ways.A transparent PVA hydrogel was prepared from a PVA solution in a mixed solvent consisting of water and a water-miscible organic solvent,DMSO,by the freezing-thawing method.The water content,visible light transmittance,mechanical and swelling properties of the hydrogels were evaluated as a function of PVA concentration and number of freeze-thaw cycles.The results show that the properties of PVA hydrogels depend on the polymer concentration,the number of freeze-thaw cycles and the addition of the organic solvent.
基金National Natural Science Foundation of China(41601458,41771141)Natural Science Foundation of Jiangsu Province of China(BK 20170272)
文摘The Tibetan Plateau serves an important shelter function for the ecological security of Asia, and especially China. Here, we proposed and improved indicators and methods for assessing the ecological sensitivity and vulnerability of the terrestrial alpine Plateau ecosystems and assessed the freeze-thaw erosion, land desertification, water-caused soil loss, and land salinization sensitivity, together with ecological vulnerability, from the overall ecological sensitivity, ecological pressure, and elasticity aspects in Tibet. The results indicate that the terrestrial ecosystem of Tibet is quite sensitive to freeze-thaw erosion, land desertification and water-caused soil loss. Extremely and highly sensitive regions account for 9.62% and 83.69%, respectively, of the total area of the Tibet Autonomous Region. Extremely and highly vulnerable areas account for 0.09% and 52.61%, respectively, primarily distributed in the Himalayan and Gangdise mountain regions in west Tibet; the Nyainqentanglha, Tanggula, Hoh Xil, and Kunlun mountain regions; and the northwest and northern regions of the Changtang Plateau. The results will aid the development of customized protection schedules according to different ecological issues in each region.
