This work is concentrated on elucidating the mechanism of the electric field enhanced water dissociation. A simple model was established for the theoretical current-voltage characteristics in water dissociation proces...This work is concentrated on elucidating the mechanism of the electric field enhanced water dissociation. A simple model was established for the theoretical current-voltage characteristics in water dissociation process on a bipolar membrane based on the existence of a depletion layer and Onsager's theory. Particular attention was given to the influence of applied voltage on depletion thickness and the dissociation constant. The factors on the water splitting process, such as water diffusivity, water content, ion exchange capacity, temperature, relative permittivity, etc. Were adequately analysed based on the derived model equations and several suggestions were proposed for decreasing the applied voltage in practical operation. The water dissociation tests were conducted and compared with both the theoretical calculation and the measured current-voltage curves reported in the literature, which showed a very good prediction to practical current-voltage behavior of a bipolar membrane at high current densities when the splitting of water actually commenced.展开更多
To investigate the influence of wet conditions on vehicle braking behavior,a numerical-analytical method was proposed for the simulation of tire hydroplaning and frictional energy dissipation. First, a finite element ...To investigate the influence of wet conditions on vehicle braking behavior,a numerical-analytical method was proposed for the simulation of tire hydroplaning and frictional energy dissipation. First, a finite element model of tire hydroplaning was established using the coupled EulerianLagrangian method,including a pneumatic tire model and a textured asphalt pavement model. Then,the frictional force on the tire-pavement interface at different speeds was calculated by the model. Based on vehicle braking mechanism and frictional energy dissipation,a calculation method for braking distance was proposed based on a three-stage braking process. The proposed method was verified by comparing the calculated hydroplaning speed and braking distance with field test results.Then,vehicle braking distances and wet friction coefficients were calculated under different conditions. The results show that thinner water film,a more complex tread pattern and higher tire inflation pressure all contribute to the vehicle braking performance; moreover, the pavement texture has obvious influence on vehicle braking behavior,especially at a high speed. The proposed method shows great effectiveness in predicting vehicle braking behavior on wet asphalt pavements.展开更多
基金Supported by the National Natural Science Foundation of China (No. 29976040), the Natural Science Foundation of Anhui Province (No. 99045431) and Youth Foundation of USTC.
文摘This work is concentrated on elucidating the mechanism of the electric field enhanced water dissociation. A simple model was established for the theoretical current-voltage characteristics in water dissociation process on a bipolar membrane based on the existence of a depletion layer and Onsager's theory. Particular attention was given to the influence of applied voltage on depletion thickness and the dissociation constant. The factors on the water splitting process, such as water diffusivity, water content, ion exchange capacity, temperature, relative permittivity, etc. Were adequately analysed based on the derived model equations and several suggestions were proposed for decreasing the applied voltage in practical operation. The water dissociation tests were conducted and compared with both the theoretical calculation and the measured current-voltage curves reported in the literature, which showed a very good prediction to practical current-voltage behavior of a bipolar membrane at high current densities when the splitting of water actually commenced.
基金The National Natural Science Foundation of China(No.51378121,51778139)
文摘To investigate the influence of wet conditions on vehicle braking behavior,a numerical-analytical method was proposed for the simulation of tire hydroplaning and frictional energy dissipation. First, a finite element model of tire hydroplaning was established using the coupled EulerianLagrangian method,including a pneumatic tire model and a textured asphalt pavement model. Then,the frictional force on the tire-pavement interface at different speeds was calculated by the model. Based on vehicle braking mechanism and frictional energy dissipation,a calculation method for braking distance was proposed based on a three-stage braking process. The proposed method was verified by comparing the calculated hydroplaning speed and braking distance with field test results.Then,vehicle braking distances and wet friction coefficients were calculated under different conditions. The results show that thinner water film,a more complex tread pattern and higher tire inflation pressure all contribute to the vehicle braking performance; moreover, the pavement texture has obvious influence on vehicle braking behavior,especially at a high speed. The proposed method shows great effectiveness in predicting vehicle braking behavior on wet asphalt pavements.