诸广-九嶷地区富铀矿的水成叠加作用初探

诸广—九在地区富铀矿床的典型沥青铀矿，明显地表现为低温浅成的晶胞参数、含氧系数等标型特征及矿石放射性同位素特征，表明富铀矿区的铀成矿作用是在原生热液成矿作用的基础上叠加有后生水成（淋积）作用。富铀矿区黑色岩系中过成熟及石墨化的有机（炭）质，为铀的水成（淋积）成矿提供了优越的环境。

不整合面型铀矿床的水成成矿作用及其预测判据

通过分析不整合面型铀矿床形成时期的古地理特点,指出在近地表水动力系统的决定作用下铀矿床形成的可能性。由此总结了在筛选不整合面型铀矿床普查区域必须考虑的各种因素。

黄河三角洲胜利Ⅰ号边滩的三维结构及其发育演化

黄河三角洲上边滩发育,但以胜利Ⅰ号边滩最为典型。胜利Ⅰ号边滩位于东营市垦利县胜利大桥南侧,长4 km左右,宽数十米到百余米。以粉砂为主,粘土次之,有少量泥砂砾及植屑,是一个典型的细粒边滩。胜利Ⅰ号边滩具有非常复杂的三维结构。首先从平面上来说,胜利Ⅰ号边滩由滩缘、滩脊、滩台、滩原、滩槽、滩沟。

Design Energy Efficient Water Utilization Systems Allowing Operation Split

This article deals with the design of energy efficient water utilization systems allowing operation split. Practical features such as operating flexibility and capital cost have made the number of sub operations an important parameter of the problem. By treating the direct and indirect heat transfers separately, target freshwater and energy consumption as well as the operation split conditions are first obtained. Subsequently, a mixed integer non-linear programming （MINLP） model is established for the design of water network and the heat exchanger network （HEN）. The proposed systematic approach is limited to a single contaminant. Example from literature is used to illustrate the applicability of the approach.

Soil Drainage as an Active Agent of Recent Soil Evolution: A Review

While research on pedogenesis mainly focuses on long-term soil formation and most often neglects recent soil evolution in response to human practices or climate changes, this article reviews the impact of artificial subsurface drainage on soil evolution. Artificial drainage is considered as an example of the impact of recent changes in water fluxes on soil evolution over time scales of decades to a century. Results from various classical studies on artificial drainage including hydrological and environmental studies are reviewed and collated with rare studies dealing explicitly with soil morphology changes, in response to artificial drainage. We deduce that soil should react to the perturbations associated with subsurface drainage over time scales that do not exceeding a few decades. Subsurface drainage decreases the intensity of erosion and must i) increase the intensity of the lixiviation and eluviation processes, ii) affect iron and manganese dynamics, and iii) induce heterogeneities in soil evolution at the ten meter scale. Such recent soil evolutions can no longer be neglected as they are mostly irreversible and will probably have unknown, but expectable, feedbacks on crucial soil functions such as the sequestration of soil organic matter or the water available capacity.

The effect of sex and performance level on pacing in cross-country skiers:Vasaloppet 2004-2017

Background： Pacing, defined as percentage changes of speed between successive splits, has been extensively studied in running and cycling endurance sports; however, less information about the trends in change of speed during cross-country （XC） ski racing is available. Therefore, the aim of the present study was to examine the effect of performance （quartiles of race time （Q）, with Q1 the fastest and Q4 the slowest） level on pacing in the Vasaloppet ski race, the largest XC skiing race in the world. Methods： For this purpose, we analyzed female （n = 19,465） and male （n = 164,454） finishers in the Vasaloppet ski race from 2004 to 2017 using a one-way （2 sexes） analysis of variance with repeated measures to examine percentage changes of speed between 2 successive splits. Overall, the race consisted of 8 splits. Results： The race speeds of Q1, Q2, Q3, and Q4 were 13.6 ± 1.8, 10.6 ± 0.5, 9.2 ± 0.3, and 8.1 ±- 0.4 km/h, respectively, among females and 16.7 ± 1.7, 13.1 ± 0.7, 10.9 ± 0.6, and 8.9 ± 0.7 km/h, respectively, among males. The overall pacing strategy of finishers was variable. A small sex × split interaction on speed was observed （η^2= 0.016, p 〈 0.001）, with speed difference between sexes ranging from 14.9% （Split 7） to 27.0% （Split 1） and larger changes in speed between 2 successive splits being shown for females （p 〈 0.001, η^2=0.004）. A large performance × split interaction on speed, with Q1 presenting the smallest changes of speed between splits, was shown for females （η^2= 0.149, p 〈 0.001） and males （η^2 = 0.169,p 〈 0.001）. Conclusion： Male and fast XC skiers are more even pacers. Coaches and athletes should develop tailored sex- and performance-level pacing strategies; for instance, they should advise fast XC skiers to start fast and maintain their speed, rather than starting slowly and trying to make up time by going faster at times during the race.2018 Published by Elsevier B.V. on behalf of Shanghai University of Sport. This is an open access article under the CC BY-NC-ND license. （http：//creativecommons.org/licenses/by-nc-nd/4.0/）.

Dealumination kinetics of composite ZSM-5/mordenite zeolite during steam treatment: An in-situ DRIFTS study

To get a better understanding of structural deactivation of ZSM-5/MOR during the catalytic cracking of n-heptane in the steam atmosphere, a comprehensive mechanism of hydrothermal dealumination was proposed through in-situ diffuse reflectance Fourier transform infrared spectroscopy(DRIFTS) in this work. The mechanism can be divided into two steps: firstly, the hydrolysis of four Al\\O bonds, and secondly, the self-healing of Si\\OH bonds accompanied with partial condensation of the extra-framework Al species. Accordingly, the kinetics of dealumination process has also been fully discussed. In the IR spectra, the range of 3450–3850 cm^(-1) could be deconvolved to distinguish the hydroxyl groups on the different position and calculate the consumption of each hydroxyl group during the reaction. Based on results from the in-situ DRIFTS, the kinetics of dealumination was hence developed and also in well agreement with the kinetics of deactivation of ZSM/MOR catalysts during the reaction in the presence of little coke deposits.

Hydrothermal synthesis and characterization of two novel inorganic-organic hybrid materials

By using different organic ligands, two 3D inorganic-organic hybrid compounds Co（C4H4N2）（VO3）2 1 and Co（C12H12N2）（VO3）2 2 were synthesized by hydrothermal reaction and characterized by X-ray crystallography. Crystal data： 1. crystal system orthorhombic, space group Pnna, a=1 0.188（2） A, b=1 1.497（2） A, c=7.3975（15） A, V=866.5（3） A^3, Z=4, Dcalcd= 2.705 g/cm^3; 2. crystal system triclinic, space group P1^- （No. 2）, a=8.3190（17） A, b=8.4764（17） A, c=1 1.183（2） A, a=95.48（3）°, β=92.03（3）°, γ=107.24（3）°,V=748.0（3） A^3, Z=2, Dcalcd= 1.958 g/cm^3. The framework of compound 1 contains both {Co（C4H4N2）} and infinite metavanadate chains. Crystal structure of compound 2 is constructed with inorganic {CoV2O6} layers across-linked by organic 1,2-bis（4-pyridyl） ethane ligands. The two compounds are thermally stable to approximately 410 ℃ and 350 ℃, respectively. Their optical band gaps are determined to be 2.13 eV and 2.12 eV by UV-VIS-NIR diffuse reflectance spectra, which revealed their nature of semiconductor and optical absorption features.

Study on Synergy Effect in Dimethyl Ether Synthesis from Syngas

Influence of reaction temperature, pressure and space velocity on the direct synthesis of dimethyl ether (DME) from syngas is studied in an isothermal fixed-bed reactor. The catalyst is a physical mixture of C301 copper-based methanol (MeOH) synthesis catalyst and ZSM-5 dehydration catalyst. The experimental results show that the chemical synergy between methanol synthesis reaction and methanol dehydration reaction is evident. The conversion of carbon monoxide is over 90%.

One-pot Synthesis of 6-Hydroxyhexanoic Acid from Cyclohexanone Catalyzed by Dealuminated HBEA Zeolite with Aqueous 30% H_2O_2 Solution

The one-pot synthesis of 6-hydroxyhexanoic acid from cyclohexanone via the integrated Baeyer-Villiger oxida-tion and ring opening reaction catalyzed by dealuminated HBEA zeolite has been developed. Under optimized conditions,the cyclohexanone conversion and 6-hydroxyhexanoic acid selectivity are over 95%, respectively. The excellent catalyticperformance is attributed to the activation of carbonyl group of cyclohexanone and the fast hydrolysis and ring opening ofs-caprolactone by both Lewis acid and Br0nsted acid sites under aqueous conditions.

Diagenesis of Paleogene sandstone from Kong 1 Member of Southern Kongdian in Huanghua depression

Huanghua depression is one of the richest areas in petroleum and natural gas in China. The Paleogene mainly consists of sandstone with facies of river, delta, fan delta and littoral-shallow lacustrine. Diagenesis played an important role in the properties of reservoir rocks. Applying X-ray diffraction, on the basis of analyz- ing many cores and thin sections, the authors studied diagenesis of Paleogene sandstone reservoir rocks in kongl Menber of southern Kongdian in Huanghua depression. Diagenetic complexity shows that the sandstone in this area underwent compaction, cementation, isolation, recrystallization during the burying of sediments, and the first three compose the major diagenesis. The compaction and cementation led to decreasing porosity, and the solution of unsteady minerals also results in increasing in porosity.

Particle Size Distribution of Kaolinite and Halloysite in Weathering Products of Granite and Its Implications for Pedogenesis

The kaolins collected from a profile of weathered granite at Yichun County, Jiangxi Province have been subjected to particle size fractionation by the conventional sedimentation method and examined by XRD,SEM and TEM. All of them exhibit a mixture phase of poorly crystallized kaolinites and halloysites (0.7 nm) occurring as the main clay minerals. Electron micrographs reveal that plate kaolinites are the principal constitution in the coarse fraction, and more tubular and curled halloysite (0.7 nm) in the fine fraction. Both of them show normal probability curves in particle size distributions. The ratios of kaolinite and halloysite (0.7 nm) in different size fractions are examined by X-ray diffraction with a series of X-ray patterns characterized by three main peaks at d(001), d(002) and d(020),varying in intensity. Therefore, an index Qhm, expressed as (Id(001) + Id(002))/(2×Id(020)), is designed to indicate relative ratios of the two clay minerals in a number of mixture phases. Because kaolinite and halloysite (0.7nm) commonly occurred, respectively, in low and medium leaching microenvironment, the index Qhm can be used to indicate weathering and pedogenic.conditions of a weathering crust.

Apatite Loss in Pothwar Loess Plain(Pakistan) Fits a Simple Linear Reservoir Model

Apatite is the dominant phosphorus(P) mineral in early stages of soil development, and its redistribution as labile forms under pedogenesis controls terrestrial bioavailability. Quantitative distribution of labile forms of P and apatite-P was examined in Pothwar Loess Plain, Pakistan where the degree of pedogenesis varied with relief. Four soil types, Typic Ustorthents(Rajar), Typic Calciustepts(Missa), Udic Calciustepts(Basal), and Udic Haplustalfs(Guliana), were sampled from three replicated locations at genetic horizon level. With the exception of total P value at surface, the mean total and apatite-P decreased towards the surface in Udic Haplustalfs and Udic Calciustepts where dicalcium and octacalcium phosphate increased toward surface. Iron(oxides and oxyhydroxides) adsorbed and occluded P forms were also in greater quantities in Udic Haplustalfs and increased toward the surface, whereas they were lowest and uniform in the Typic Ustorthents. Aluminum- and organic P correlated with soil organic matter. Apatite-P decreased exponentially with an increase in the sum of iron adsorbed and occluded P fractions, and fitted the equation M(x)= M0 [1- exp(-wx)] with r2= 0.996, where M(x)is the mean apatite-P concentration in solum, M0 is the apatite-P content in the loess sediments, x is the cumulative iron adsorbed and occluded P, and w is an empirical factor indicating the change rate of apatite-P in the loess. From the calculated apatite-P of 740 mg kg-1at the time of deposition, mean apatite-P loss was 60% in Udic Haplustalfs, 33% in Udic Calciustepts, 23% in Typic Calciustepts, and 8% in Typic Ustorthents. The transformation of soil P to labile forms was faster and deeper in level or slight depressions followed by gently sloping areas in wide plains, and was the least in the gullied land.

Cavitation Rates in Water with Dissolved Gas and Other Impurities

Our objective is a better understanding of the role of physical properties of real fluids in the thermodynamics of cavitation in impure water. An extension to the classical homogenous nucleation theory suitable for mixtures is presented in attempt to address the discrepancy between the theoretical predictions and practical observations of cavitation rates in water at normal temperatures. The extension takes into account the non-equilibrium (dissipative) effects involved in nuclei formation through a substance dependent correction coefficient to be determined experimentally. The theory of thermodynamic fluctuations is applied to derive the work of formation of a bubble nucleus. The value of the correction coefficient is estimated using preliminary experimental data from a convergent-divergent nozzle. An application of the results to the numerical prediction of the cavitation zones in a radial-flow water pump is shown.