Based on daily observation data of the Three Gorges Region(TGR)of the Yangtze River basin and global reanalysis data,the climate characteristics,climate events,and meteorological disasters of the TGR in 2022 and 2023 ...Based on daily observation data of the Three Gorges Region(TGR)of the Yangtze River basin and global reanalysis data,the climate characteristics,climate events,and meteorological disasters of the TGR in 2022 and 2023 were analyzed.For the TGR,the average annual temperature for 2022 and 2023 was 0.8℃ and 0.4℃ higher than normal,respectively,making them the two warmest years in the past decade.In 2022,the TGR experienced its warmest summer on record.The average air temperature was 2.4℃ higher than the average,and there were 24.8 days of above-average high temperature days during summer.Rainfall in the TGR varied significantly between 2022 and 2023.Annual rainfall was 18.4%below normal and drier than normal in most parts of the region.In contrast,the precipitation in 2023 was considerably higher than the long-term average,and above normal for almost the entire year.The average wind speed exhibited minimal variation between the two years.However,the number of foggy days and relative humidity increased in 2023 compared to 2022.In 2022–2023,the TGR mainly experienced meteorological disasters such as extreme high temperatures,regional heavy rain and flooding,overcast rain,and inverted spring chill.Analysis indicates that the abnormal western Pacific subtropical high and the abnormal persistence of the eastward-shifted South Asian high were the two important drivers of the durative enhancement of record-breaking high temperature in the summer of 2022.展开更多
The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past...The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past decades,researchers have reported a number of hydrogen evolution reaction(HER)electrocatalysts with activity comparable to that of commercial Pt/C,but most of them are tested within a small current density range,typically no more than 500 mA cm^(-2).To realize the industrial application of hydrogen production from water electrolysis,it is essential to develop high-efficiency HER electrocatalysts at high current density(HCD≥500 mA cm^(-2)).Nevertheless,it remains challenging and significant to rational design HCD electrocatalysts for HER.In this paper,the design strategy of HCD electrocatalysts is discussed,and some HCD electrocatalysts for HER are reviewed in seven categories(alloy,metal oxide,metal hydroxide,metal sulfide/selenide,metal nitride,metal phosphide and other derived electrocatalysts).At the end of this article,we also pro-pose some viewpoints and prospects for the future development and research directions of HCD electrocatalysts for HER.展开更多
Background,aim,and scope Stable isotope in water could respond sensitively to the variation of environment and be reserved in different geological archives,although they are scarce in the environment.And the methods d...Background,aim,and scope Stable isotope in water could respond sensitively to the variation of environment and be reserved in different geological archives,although they are scarce in the environment.And the methods derived from the stable isotope composition of water have been widely applied in researches on hydrometeorology,weather diagnosis,and paleoclimate reconstruction,which help well for understanding the water-cycle processes in one region.Here,it is aimed to explore the temporal changes of stable isotopes in precipitation from Adelaide,Australia and determine the influencing factors at different timescales.Materials and methods Based on the isotopic data of daily precipitation over four years collected in Adelaide,Australia,the variation characteristics of dailyδD,δ^(18)O,and dexcess in precipitation and its relationship with meteorological elements were analyzed.Results The results demonstrated the local meteoric water line(LMWL)in Adelaide,wasδD=6.38×δ^(18)O+6.68,with a gradient less than 8.There is a significant negative correlation between dailyδ^(18)O and precipitation amount or relative humidity at daily timescales in both the whole year and wither/summerhalf year(p<0.001),but a significant positive correlation between dailyδ^(18)O and temperature in the whole year and the winter half-year(p<0.001).Discussion The correlation coefficients betweenδ^(18)O and daily mean temperature didn’t show a significant positive correlation,which may be attributed to that the precipitation in Adelaide area in January was mainly influenced by strong convective weather,and the stable isotope values in precipitation were significantly negative.Furthermore,this propose was also evidenced by the results from dexcess of precipitation with larger value in the winter half-year than that in the summer half-year,which may be resulted from the precipitation events in winter are mostly influenced by oceanic water vapor,while the sources of water vapor in summer precipitation events are more complicated and influenced by strong convective weather.On the other hand,the slope and intercept of theδ^(18)O—P regression lines in the summer months(-0.41 and 0.50‰)are larger and smaller than those in the winter months(-0.22 and-2.15‰),respectively,indicating that the precipitation stable isotopes have a relatively stronger rainout effect in the summer months than in the winter months.Besides,the measured values ofδ^(18)O in daily precipitation have a good linear relationship with our simulated values ofδ^(18)O,demonstrating the established regression model could provide a reliable simulation for theδ^(18)O values in daily precipitation in Adelaide area.It’s worth noting that the precipitation events with low precipitation amount,low relative humidity and high temperature,usually had relatively small slope and intercept of MWL,implying that raindrops may be strongly affected by sub-cloud secondary evaporation in the falling process.Conclusions The variation ofδ^(18)O in daily precipitation from Adelaide region was controlled by different factors at different timescales.And the water vapor sources and the meteorological conditions of precipitation events(such as the degree of sub-cloud secondary evaporation)also played an important role on the variation ofδ^(18)O.Recommendations and perspectives Stable isotope in daily precipitation can provide more accurate information about water-cycle and atmosphere circulation,it is therefore necessary to continue to collect and analyze daily-scale precipitation data over a longer time span.The results of this study will provide the basis for the fields of hydrometeorology,meteorological diagnosis and paleoclimate reconstruction in Adelaide,Australia.展开更多
A novel composition of AlLi/NaBH4 mixture activated by common Ni powder in water for hydrogen generation was investigated. The composition presents good hydrogen generation performance and an optimized Al-10% Li-10% N...A novel composition of AlLi/NaBH4 mixture activated by common Ni powder in water for hydrogen generation was investigated. The composition presents good hydrogen generation performance and an optimized Al-10% Li-10% Ni/NaBH4 mixture （mass ratio of 3：1） generates 1540 mL/g hydrogen with 96% efficiency at 333 K. Ni powder exhibits dual catalytic effects on the hydrolysis of AlLi/NaBH4 mixture due to the formation of Ni2B in the hydrolysis process. The Ni2B deposited on aluminum surface could act as a cathode of a micro galvanic couple. Ni2B/Al（OH）3 also has a synergistic effect on NaBH4 hydrolysis. Good hydrogen generation performance with stable pH value of hydrolysis byproduct Al（OH）3/NaBO2-2H2O was obtained with successive additions of Al-Li-Ni /NaBH4 mixture into fixed water.展开更多
Mg-Al-Pb alloy is a good candidate for the anode material of magnesium seawater battery. For improving the low current utilization efficiency of Mg-Al-Pb alloy, the influence of Ce on the microstructures and electroch...Mg-Al-Pb alloy is a good candidate for the anode material of magnesium seawater battery. For improving the low current utilization efficiency of Mg-Al-Pb alloy, the influence of Ce on the microstructures and electrochemical corrosion properties in a 3.5% NaCl solution was investigated using scanning electron microscope and electrochemical measurements. The results indicate that Ce refines the grain structure of Mg-Al-Pb alloy. The formation of strip Al11Ce3 second phase promotes the uniform distribution of Mg17Al12 phase in Mg-Al-Pb-Ce alloy. The addition of cerium accelerates the discharge activity of Mg-Al-Pb alloy. Due to a large number of cathodic Al11Ce3 and MglyAla2 phases, Ce promotes the micro-galvanic corrosion and leads to larger corrosion current density and hydrogen evolution rate in Mg-Al-Pb-Ce alloy than those in Mg-Al-Pb alloy. However, Mg-Al-Pb alloy expresses smaller utilization efficiency than Mg-Al-Pb-Ce alloy because of grain detachment.展开更多
The temperature and salinity distributions, and the water mass structures in Northwest Pacific Ocean are studied using the temperature and salinity data obtained by Argo profiling floats. The T-S relation in this regi...The temperature and salinity distributions, and the water mass structures in Northwest Pacific Ocean are studied using the temperature and salinity data obtained by Argo profiling floats. The T-S relation in this region indicates there exist 8 water masses, they are the North Pacific Tropical Surface Water （NPTSW）, North P, acific Subsurface Water （NPSSW）, North Pacific Intermediate Water （NPIW）, North Pacific Subtropical Water （NPSTW）, North Pacific Deep Water （NPDW） and Equatorial Surface Water （ESW）, and the South Pacific Subsurface Water （SPSSW） and South Pacific Intermediate Water （SPIW）.展开更多
The single phase La2（CO3）3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2（CO3）3·3.4H2O from 30 to 1000 °C were characteri...The single phase La2（CO3）3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2（CO3）3·3.4H2O from 30 to 1000 °C were characterized by XRD, FTIR and DTA-TG. The kinetics of dehydration of La2（CO3）3·3.4H2O in the temperature range of 30-366 °C was investigated under non-isothermal conditions. Flynn-Wall-Ozawa and Friedman isoconversion methods were used to calculate the activation energy and analyze the reaction steps; multivariate non-linear regression program was applied to determine the most probable mechanism and the kinetic parameters. The results show that the thermal dehydration of La2（CO3）3·3.4H2O is a kind of three-step competitive reaction, and controlled by an n-order initial reaction followed by n-order competitive reaction（FnFnFn model）. The activation energy matching with the most probable model is close to value obtained by Friedman method. The fitting curves match the original TG-DTG curves very well.展开更多
This paper is based on the rainwater collection project in the retrofit of the Dongyi teaching block in Zhejiang University Xixi Campus.The analysis incorporates the local meteorological data, recycling water utilizat...This paper is based on the rainwater collection project in the retrofit of the Dongyi teaching block in Zhejiang University Xixi Campus.The analysis incorporates the local meteorological data, recycling water utilization, and precipitation adjustment.The rainwater collection system in this program also adds the condensation water from the heating, ventilation and air conditioning （ HVAC） system and the concentration from the reverse-osmosis system used for watering greens and supplying waterscapes.By calculating, the quantity of the HVAC condensation water in summer is 3.48 m3/d, and the quantity of the reverse-osmosis concentrated water is 198 to 396 L/d.This method solves the water shortage caused by high evaporation in summer and low precipitation in winter.Supported by empirical monitoring data, the proposed method significantly increases the economic efficiency of the system during the summer period.展开更多
基金supported by the National Key Research and Development Program of China[grant number 2023YFC3206001]the Three Gorges Project Comprehensive Monitoring Program for Operational Safety[grant number SK2023019]which funded by the Ministry of Water Resources of China.
文摘Based on daily observation data of the Three Gorges Region(TGR)of the Yangtze River basin and global reanalysis data,the climate characteristics,climate events,and meteorological disasters of the TGR in 2022 and 2023 were analyzed.For the TGR,the average annual temperature for 2022 and 2023 was 0.8℃ and 0.4℃ higher than normal,respectively,making them the two warmest years in the past decade.In 2022,the TGR experienced its warmest summer on record.The average air temperature was 2.4℃ higher than the average,and there were 24.8 days of above-average high temperature days during summer.Rainfall in the TGR varied significantly between 2022 and 2023.Annual rainfall was 18.4%below normal and drier than normal in most parts of the region.In contrast,the precipitation in 2023 was considerably higher than the long-term average,and above normal for almost the entire year.The average wind speed exhibited minimal variation between the two years.However,the number of foggy days and relative humidity increased in 2023 compared to 2022.In 2022–2023,the TGR mainly experienced meteorological disasters such as extreme high temperatures,regional heavy rain and flooding,overcast rain,and inverted spring chill.Analysis indicates that the abnormal western Pacific subtropical high and the abnormal persistence of the eastward-shifted South Asian high were the two important drivers of the durative enhancement of record-breaking high temperature in the summer of 2022.
文摘The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past decades,researchers have reported a number of hydrogen evolution reaction(HER)electrocatalysts with activity comparable to that of commercial Pt/C,but most of them are tested within a small current density range,typically no more than 500 mA cm^(-2).To realize the industrial application of hydrogen production from water electrolysis,it is essential to develop high-efficiency HER electrocatalysts at high current density(HCD≥500 mA cm^(-2)).Nevertheless,it remains challenging and significant to rational design HCD electrocatalysts for HER.In this paper,the design strategy of HCD electrocatalysts is discussed,and some HCD electrocatalysts for HER are reviewed in seven categories(alloy,metal oxide,metal hydroxide,metal sulfide/selenide,metal nitride,metal phosphide and other derived electrocatalysts).At the end of this article,we also pro-pose some viewpoints and prospects for the future development and research directions of HCD electrocatalysts for HER.
文摘Background,aim,and scope Stable isotope in water could respond sensitively to the variation of environment and be reserved in different geological archives,although they are scarce in the environment.And the methods derived from the stable isotope composition of water have been widely applied in researches on hydrometeorology,weather diagnosis,and paleoclimate reconstruction,which help well for understanding the water-cycle processes in one region.Here,it is aimed to explore the temporal changes of stable isotopes in precipitation from Adelaide,Australia and determine the influencing factors at different timescales.Materials and methods Based on the isotopic data of daily precipitation over four years collected in Adelaide,Australia,the variation characteristics of dailyδD,δ^(18)O,and dexcess in precipitation and its relationship with meteorological elements were analyzed.Results The results demonstrated the local meteoric water line(LMWL)in Adelaide,wasδD=6.38×δ^(18)O+6.68,with a gradient less than 8.There is a significant negative correlation between dailyδ^(18)O and precipitation amount or relative humidity at daily timescales in both the whole year and wither/summerhalf year(p<0.001),but a significant positive correlation between dailyδ^(18)O and temperature in the whole year and the winter half-year(p<0.001).Discussion The correlation coefficients betweenδ^(18)O and daily mean temperature didn’t show a significant positive correlation,which may be attributed to that the precipitation in Adelaide area in January was mainly influenced by strong convective weather,and the stable isotope values in precipitation were significantly negative.Furthermore,this propose was also evidenced by the results from dexcess of precipitation with larger value in the winter half-year than that in the summer half-year,which may be resulted from the precipitation events in winter are mostly influenced by oceanic water vapor,while the sources of water vapor in summer precipitation events are more complicated and influenced by strong convective weather.On the other hand,the slope and intercept of theδ^(18)O—P regression lines in the summer months(-0.41 and 0.50‰)are larger and smaller than those in the winter months(-0.22 and-2.15‰),respectively,indicating that the precipitation stable isotopes have a relatively stronger rainout effect in the summer months than in the winter months.Besides,the measured values ofδ^(18)O in daily precipitation have a good linear relationship with our simulated values ofδ^(18)O,demonstrating the established regression model could provide a reliable simulation for theδ^(18)O values in daily precipitation in Adelaide area.It’s worth noting that the precipitation events with low precipitation amount,low relative humidity and high temperature,usually had relatively small slope and intercept of MWL,implying that raindrops may be strongly affected by sub-cloud secondary evaporation in the falling process.Conclusions The variation ofδ^(18)O in daily precipitation from Adelaide region was controlled by different factors at different timescales.And the water vapor sources and the meteorological conditions of precipitation events(such as the degree of sub-cloud secondary evaporation)also played an important role on the variation ofδ^(18)O.Recommendations and perspectives Stable isotope in daily precipitation can provide more accurate information about water-cycle and atmosphere circulation,it is therefore necessary to continue to collect and analyze daily-scale precipitation data over a longer time span.The results of this study will provide the basis for the fields of hydrometeorology,meteorological diagnosis and paleoclimate reconstruction in Adelaide,Australia.
基金Projects (21003112, 21003111) supported by the National Natural Science Foundation of ChinaProject (Y4090507) supported by the Zhejiang Basic Research Program, China
文摘A novel composition of AlLi/NaBH4 mixture activated by common Ni powder in water for hydrogen generation was investigated. The composition presents good hydrogen generation performance and an optimized Al-10% Li-10% Ni/NaBH4 mixture （mass ratio of 3：1） generates 1540 mL/g hydrogen with 96% efficiency at 333 K. Ni powder exhibits dual catalytic effects on the hydrolysis of AlLi/NaBH4 mixture due to the formation of Ni2B in the hydrolysis process. The Ni2B deposited on aluminum surface could act as a cathode of a micro galvanic couple. Ni2B/Al（OH）3 also has a synergistic effect on NaBH4 hydrolysis. Good hydrogen generation performance with stable pH value of hydrolysis byproduct Al（OH）3/NaBO2-2H2O was obtained with successive additions of Al-Li-Ni /NaBH4 mixture into fixed water.
基金Project(2015JC3004)supported by Science and Technology Plan Projects of Hunan Province,ChinaProject(51401243)supported by the National Natural Science Foundation of China
文摘Mg-Al-Pb alloy is a good candidate for the anode material of magnesium seawater battery. For improving the low current utilization efficiency of Mg-Al-Pb alloy, the influence of Ce on the microstructures and electrochemical corrosion properties in a 3.5% NaCl solution was investigated using scanning electron microscope and electrochemical measurements. The results indicate that Ce refines the grain structure of Mg-Al-Pb alloy. The formation of strip Al11Ce3 second phase promotes the uniform distribution of Mg17Al12 phase in Mg-Al-Pb-Ce alloy. The addition of cerium accelerates the discharge activity of Mg-Al-Pb alloy. Due to a large number of cathodic Al11Ce3 and MglyAla2 phases, Ce promotes the micro-galvanic corrosion and leads to larger corrosion current density and hydrogen evolution rate in Mg-Al-Pb-Ce alloy than those in Mg-Al-Pb alloy. However, Mg-Al-Pb alloy expresses smaller utilization efficiency than Mg-Al-Pb-Ce alloy because of grain detachment.
基金the specical scientific research project for the welfare of the State Oceanic Administration for 2007.(No.200706022).
文摘The temperature and salinity distributions, and the water mass structures in Northwest Pacific Ocean are studied using the temperature and salinity data obtained by Argo profiling floats. The T-S relation in this region indicates there exist 8 water masses, they are the North Pacific Tropical Surface Water （NPTSW）, North P, acific Subsurface Water （NPSSW）, North Pacific Intermediate Water （NPIW）, North Pacific Subtropical Water （NPSTW）, North Pacific Deep Water （NPDW） and Equatorial Surface Water （ESW）, and the South Pacific Subsurface Water （SPSSW） and South Pacific Intermediate Water （SPIW）.
基金Project(201011005-5)supported by the National Land and Resources Public Welfare Scientific Research Project of ChinaProject(41030426)supported by the National Natural Science Foundation of China+1 种基金Project(20095122110015)supported by Specialized Research Fund for the Doctoral Program of Higher Education of ChinaProject(2010-32)supported by Scientific Research Foundation of the Education Ministry for Returned Chinese Scholars,China
文摘The single phase La2（CO3）3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2（CO3）3·3.4H2O from 30 to 1000 °C were characterized by XRD, FTIR and DTA-TG. The kinetics of dehydration of La2（CO3）3·3.4H2O in the temperature range of 30-366 °C was investigated under non-isothermal conditions. Flynn-Wall-Ozawa and Friedman isoconversion methods were used to calculate the activation energy and analyze the reaction steps; multivariate non-linear regression program was applied to determine the most probable mechanism and the kinetic parameters. The results show that the thermal dehydration of La2（CO3）3·3.4H2O is a kind of three-step competitive reaction, and controlled by an n-order initial reaction followed by n-order competitive reaction（FnFnFn model）. The activation energy matching with the most probable model is close to value obtained by Friedman method. The fitting curves match the original TG-DTG curves very well.
文摘This paper is based on the rainwater collection project in the retrofit of the Dongyi teaching block in Zhejiang University Xixi Campus.The analysis incorporates the local meteorological data, recycling water utilization, and precipitation adjustment.The rainwater collection system in this program also adds the condensation water from the heating, ventilation and air conditioning （ HVAC） system and the concentration from the reverse-osmosis system used for watering greens and supplying waterscapes.By calculating, the quantity of the HVAC condensation water in summer is 3.48 m3/d, and the quantity of the reverse-osmosis concentrated water is 198 to 396 L/d.This method solves the water shortage caused by high evaporation in summer and low precipitation in winter.Supported by empirical monitoring data, the proposed method significantly increases the economic efficiency of the system during the summer period.
