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钾盐对超临界水中水气转换反应的影响
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作者 丁启忠 张军 +1 位作者 赵亮 陆柒安 《发电设备》 2020年第2期81-86,共6页
讨论了生物质中钾盐对水气转换反应过程的影响,研究了不同工艺条件下单一钾盐或混合钾盐对超临界水中水气转换的影响。结果表明:超临界水中水气转换的气体产物为H2、CO和CO2;所研究的钾盐均能显著提高H2产率,且KHCO3的影响程度最强;提... 讨论了生物质中钾盐对水气转换反应过程的影响,研究了不同工艺条件下单一钾盐或混合钾盐对超临界水中水气转换的影响。结果表明:超临界水中水气转换的气体产物为H2、CO和CO2;所研究的钾盐均能显著提高H2产率,且KHCO3的影响程度最强;提高反应温度、延长反应停留时间均能促进H2的生成,增大反应压力和增加K+浓度对H2产率的影响则比较复杂;钾盐对水气转换的影响可能是通过以草酸氢盐和甲酸盐为中间产物的机理进行。 展开更多
关键词 钾盐 水气转换 超临界水
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用于煤液化的新型水气转换催化剂
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《化学工业与工程技术》 CAS 2005年第3期40-40,共1页
由于煤中的氢比碳含量少(氢小于5%,碳>60%,均为体积分数),因此,基本上转换反应的目的是获得氢量的增加,若需要原料气具有高的H2/CO比时情况尤甚。因此转换反应的效率对经济效益影响非常大。
关键词 水气转换催化剂 煤液化 氢量 制备方法
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镍基催化剂对CO-超临界水制氢固碳反应的影响
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作者 田冲 赵永椿 +3 位作者 张军营 晏恒 吕涛涛 郑楚光 《动力工程学报》 CAS CSCD 北大核心 2011年第11期869-874,共6页
利用水热法制备镍基催化剂Ni/ZrO2-CeO2-Al2O3,并采用X-射线衍射仪和X-射线荧光能谱仪对其组分进行表征.在高温高压反应釜中,同时添加镍基催化剂和固碳剂(硅灰石)的条件下进行CO-超临界水气转化(WGS)试验,分别考察温度、压力等因素对CO... 利用水热法制备镍基催化剂Ni/ZrO2-CeO2-Al2O3,并采用X-射线衍射仪和X-射线荧光能谱仪对其组分进行表征.在高温高压反应釜中,同时添加镍基催化剂和固碳剂(硅灰石)的条件下进行CO-超临界水气转化(WGS)试验,分别考察温度、压力等因素对CO-超临界水气化反应的影响及探究制氢固碳的可行性.结果表明:添加催化剂Ni/ZrO2-CeO2-Al2O3能同时提高制氢效率和矿化效率,相同工况下添加催化剂时制氢效率最大可提高8%,矿化效率最大可提高8.2%;CO初压为4 MPa、温度为420℃时,添加1 g催化剂和10 g硅灰石,制氢效率可达到16.8%;CO初压为6 MPa、温度为400℃时,添加相同样品的工况下,CO2矿化效率达到38.1%;在存在催化剂Ni/ZrO2-CeO2-Al2O3的WGS反应中,CO初压对CO2矿化影响较大,而温度对制氢效率的影响较大. 展开更多
关键词 Ni/ZrO2-CeO2-Al2O3 制氢固碳 水气转换 CO-超临界水 硅灰石
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Sediment Movement in Periodic Alternating Current 被引量:11
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作者 CAOZude KONGLingshuang LIUDefu 《Journal of Ocean University of Qingdao》 2002年第2期201-205,共5页
The present paper summarizes the results of previous studies, including the structure and principle of the rotary ring flume for researching the fine sediment movement, the mechanism of the flume, method of eliminatin... The present paper summarizes the results of previous studies, including the structure and principle of the rotary ring flume for researching the fine sediment movement, the mechanism of the flume, method of eliminating the influence of the centrifugal force and sediment movement experiments with periodic alternating current. Also included are the experiment-based relationship among sediment concentration, bed shear stress and silt carrying capacity, a proposed erosion-deposition function and bed erosion-deposition calculation together with the results of verification. 展开更多
关键词 rotary ring flume periodic alternating current hydraulic characteristics of sediment erosion-deposition function
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New insight into hydroxyl-mediated NH_3 formation on the Rh-CeO_2 catalyst surface during catalytic reduction of NO by CO 被引量:9
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作者 Chengxiong Wang Wenzheng Xia Yunkun Zhao 《Chinese Journal of Catalysis》 CSCD 北大核心 2017年第8期1399-1405,共7页
Vibrational IR spectra and light‐off investigations show that NH3forms via the“hydrogen down”reaction of adsorbed CO and NO with hydroxyl groups on a CeO2support during the catalytic reduction of NO by CO.The prese... Vibrational IR spectra and light‐off investigations show that NH3forms via the“hydrogen down”reaction of adsorbed CO and NO with hydroxyl groups on a CeO2support during the catalytic reduction of NO by CO.The presence of water in the reaction stream results in a significant increase in NH3selectivity.This result is due to water‐induced hydroxylation promoting NH3formation and the competitive adsorption of H2O and NO at the same sites,which inhibits the reactivity of NO reduction by NH3. 展开更多
关键词 NH3 formation NO reduction CO oxidation In‐situ DRIFTS Water gas shift
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荒煤气回收利用技术研究进展综述 被引量:1
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作者 王一祖 王泽华 张俊霞 《榆林科技》 2019年第2期6-10,共5页
煤化工领域荒煤气回收利用是工业节能环保的重要研究内容。本文综述了焦炉荒煤的回收利用方法及原理,重点提出了荒煤气制氢、荒煤气生产还原铁、荒煤气发电、荒煤气余热回收和荒煤气脱硫的利用方向,并且介绍了其他荒煤气回收利用方向,... 煤化工领域荒煤气回收利用是工业节能环保的重要研究内容。本文综述了焦炉荒煤的回收利用方法及原理,重点提出了荒煤气制氢、荒煤气生产还原铁、荒煤气发电、荒煤气余热回收和荒煤气脱硫的利用方向,并且介绍了其他荒煤气回收利用方向,本文就处于研发试验阶段的几种典型的焦炉荒煤气余热回收技术进行了论述。目前,这几种荒煤气利用技术推动了焦化行业余热余能回收利用水平的提高,促进了焦化行业节能减排的发展,具有明显的环境效益和经济效益。 展开更多
关键词 回收技术 焦化炉 重整制氢 吸附强化 链条锅炉 上升管 重整反应 煤气脱硫 回收利用技术 甲烷水蒸气重整 煤气初冷器 水气转换反应
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Pneumatic Performance of Staggered Impulse Turbine for OWC Wave Energy Convertor 被引量:1
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作者 CUI Ying LIU Zhen Beom-Soo Hyun 《Journal of Thermal Science》 SCIE EI CAS CSCD 2015年第5期403-409,共7页
A staggered impulse turbine is proposed for asymmetric air flows in Oscillating Water Column wave energy plants, which is expected to enhance the pneumatic power output in a wave cycle. The setting angle of rotor blad... A staggered impulse turbine is proposed for asymmetric air flows in Oscillating Water Column wave energy plants, which is expected to enhance the pneumatic power output in a wave cycle. The setting angle of rotor blades is set as 5°. The 3D numerical simulations were conducted under steady conditions using MRF and Mixing Plane model based on CFD software Fluent 12.0. Its mean efficiencies under different velocity amplitude ratios are studied using quasi-steady analysis, which derive corresponding data from the numerical simulation. It is found that the staggered turbine shows better performance than the conventional one under the asymmetrical air flows. Furthermore, its mean efficiency and output-work in a wave period are compared with another unsymmetrical twin impulse turbine system. The results show that the staggered turbine shows better output-work performance than the twin turbine system over the high flow coefficient domain(φ>0.7), which provides more choices to future research on turbine's optimization. 展开更多
关键词 Wave Energy Oscillating Water Column Staggered Impulse Turbine Asymmetric Air Flows Nu-merical Simulation Quasi-steady Analysis
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Characteristic of Local Boiling Heat Transfer of Ammonia and Ammonia/Water Binary Mixture on the Plate Type Evaporator 被引量:2
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作者 Akio OKAMOTO Hirofumi ARIMA Yasuyuki IKEGAMI 《Journal of Thermal Science》 SCIE EI CAS CSCD 2011年第4期332-342,共11页
Power generation using small temperature difference such as ocean thermal energy conversion(OTEC)and discharged thermal energy conversion(DTEC)is expected to be the countermeasures against global warming problem.As am... Power generation using small temperature difference such as ocean thermal energy conversion(OTEC)and discharged thermal energy conversion(DTEC)is expected to be the countermeasures against global warming problem.As ammonia and ammonia/water are used in evaporators for OTEC and DTEC as working fluids,the research of their local boiling heat transfer is important for improvement of the power generation efficiency.Measurements of local boiling heat transfer coefficients were performed for ammonia/water mixture(z=0.9-1)on a vertical flat plate heat exchanger in a range of mass flux(7.5-15 kg/m2s),heat flux(15-23 kW/m 2),and pressure(0.7-0.9 MPa).The result shows that in the case of ammonia/water mixture,the local heat transfer coefficients increase with an increase of mass flux and composition of ammonia,and decrease with an increase of heat flux. 展开更多
关键词 Local Heat Transfer Ammonia/Water Mixture Plate Type Evaporator OTEC
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