Chemical compositions, mineral compositions and the activated mechanism of the coal-gangue were analyzed. And pozzolana activities of the coal-gangue were evaluated after activated. Moreover, hydration heat and hydrat...Chemical compositions, mineral compositions and the activated mechanism of the coal-gangue were analyzed. And pozzolana activities of the coal-gangue were evaluated after activated. Moreover, hydration heat and hydration compositions of activated coal-gangue-calcium oxide system, as well as hydration degree and hardened paste microstructures of activated coal-gangue-cement system were studied. Results show that pozzolana activities of the activated coal-gangue root in amorphous SiO2 and activated Al2O3. With the exciting of gypsum, the reaction of activated coal-gangue and Ca(OH) 2 would produce hydration products as ettringite, calcium silicate hydrate, and calcium aluminate. The relationship between the curing age and the content of Ca (OH)2 in coal-gangue-cement system was ascertained. Unhydrated particles in the coalogangue-cement paste were more than that in the neat cement paste at the same hydration periods, and even existed at the later stage of hydration. Furthermore, the activated coal-gangue could inhibit growth and gathering of the calcium oxide crystal, and improve the structure of hardened cement paste.展开更多
基金the National Basic Reasearch Program of China(Grant No.2001CB610704).
文摘Chemical compositions, mineral compositions and the activated mechanism of the coal-gangue were analyzed. And pozzolana activities of the coal-gangue were evaluated after activated. Moreover, hydration heat and hydration compositions of activated coal-gangue-calcium oxide system, as well as hydration degree and hardened paste microstructures of activated coal-gangue-cement system were studied. Results show that pozzolana activities of the activated coal-gangue root in amorphous SiO2 and activated Al2O3. With the exciting of gypsum, the reaction of activated coal-gangue and Ca(OH) 2 would produce hydration products as ettringite, calcium silicate hydrate, and calcium aluminate. The relationship between the curing age and the content of Ca (OH)2 in coal-gangue-cement system was ascertained. Unhydrated particles in the coalogangue-cement paste were more than that in the neat cement paste at the same hydration periods, and even existed at the later stage of hydration. Furthermore, the activated coal-gangue could inhibit growth and gathering of the calcium oxide crystal, and improve the structure of hardened cement paste.