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石灰石粉对水泥水化性能的影响 被引量:2
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作者 唐光星 翁龙 +1 位作者 曾俊杰 范志宏 《水运工程》 北大核心 2017年第9期70-75,82,共7页
采用X射线衍射(XRD)和扫描电镜(SEM)等分析技术测试石灰石粉对水泥单矿水化过程的影响,并系统研究石灰石粉对水泥砂浆工作性能和力学性能的影响。结果表明:石灰石粉对C_3S的水化产物没有明显影响,与C_3A反应生成可稳定存在的单碳水化铝... 采用X射线衍射(XRD)和扫描电镜(SEM)等分析技术测试石灰石粉对水泥单矿水化过程的影响,并系统研究石灰石粉对水泥砂浆工作性能和力学性能的影响。结果表明:石灰石粉对C_3S的水化产物没有明显影响,与C_3A反应生成可稳定存在的单碳水化铝酸钙,提高石灰石粉细度和掺量有利于该反应的进行。石灰石粉对水泥胶砂的流动度影响较小,降低了水泥砂浆的抗压强度力学性能。 展开更多
关键词 石灰石粉 水泥水化性能 水泥砂浆性能
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淀粉基减水剂对水泥及混凝土性能的影响 被引量:2
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作者 苗方利 姚治会 张鼎 《硅酸盐通报》 CAS 北大核心 2021年第3期758-764,共7页
以玉米淀粉为生物基原材料,双氧水(H_(2)O_(2))为绿色氧化剂,阳离子季铵盐为醚化剂,通过氧化-醚化反应制备了一种新型绿色淀粉基减水剂(SWR)。为评价SWR对水泥水化性能的影响,利用红外光谱分析(FT-IR)SWR制备过程中官能团的变化;对比SW... 以玉米淀粉为生物基原材料,双氧水(H_(2)O_(2))为绿色氧化剂,阳离子季铵盐为醚化剂,通过氧化-醚化反应制备了一种新型绿色淀粉基减水剂(SWR)。为评价SWR对水泥水化性能的影响,利用红外光谱分析(FT-IR)SWR制备过程中官能团的变化;对比SWR、聚羧酸减水剂(PWR)、萘系减水剂(NWR)三种减水剂对水泥减水率、Zeta电位、净浆流动度、胶砂强度、混凝土抗压强度性能的影响。结果表明,SWR分子链上引入了羧基与醚键。随减水剂掺量的增加,SWR的减水率逐渐增大,且较PWR、NWR有更优异的减水效果,以水泥质量为基准,SWR折固掺量的质量分数为1.0%时,减水率可达33%。Zeta电位分析表明,三者具有相近的电位绝对值,但SWR具有最大的经时电位绝对值。当减水剂掺量的质量分数低于0.6%时,三者的水泥净浆流动度较为相近,但继续增加减水剂用量,NWR的水泥净浆流动度更为突出。SWR胶砂试件的7 d与28 d抗折强度、抗压强度基本介于PWR与NWR胶砂试件之间;SWR混凝土7 d抗压强度最低,28 d时抗压强度最高,达49.6 MPa,表明SWR起到缓凝作用。综合分析,SWR减水剂具有较好减水与缓凝作用,同时可保证混凝土的强度性能,推荐SWR折固掺量的质量分数为1.0%。 展开更多
关键词 淀粉基减水剂 氧化-醚化反应 水泥水化性能 混凝土性能 胶砂性能
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Study on anaerobic co-digestion with distillery wastewater to improve the dewatering property of the secondary sludge 被引量:1
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作者 TAI Ming-qing CHEN Jie-rong +1 位作者 CHANG Chein-chin GAO Jun-lin 《Journal of Life Sciences》 2007年第1期60-66,共7页
This paper presents the results obtained for the effluent dewatering properties of anaerobic digestion of secondary sludge (SS) and anaerobic co-digestion of mixture of this sludge with the distillery wastewater (D... This paper presents the results obtained for the effluent dewatering properties of anaerobic digestion of secondary sludge (SS) and anaerobic co-digestion of mixture of this sludge with the distillery wastewater (DW) under thermophilic (55±1 ℃), 5 L of working volume, three parallel lab-scale conditions. Its mixtures were prepared with a DW content of 25%and 50% and the C/N ratios of mixtures are 13.1 and 17.6, respectively. The effluent dewatering properties were evaluated under stable conditions which the biogas yield and the effluent pH were steady. The natural settleability, biogas yield, centrifugal dewatering, centrifugal supernatant turbidity and specific resistance filtration (SRF) were investigated. The results showed that the effluent dewatering properties of anaerobic co-digestion of mixtures between SS and DW were better than that of anaerobic digestion of SS alone. In the anaerobic digestion system with the feed were SS, mixture of SS and a DW content of 25%and 50% in order, the net biogas yield of secondary sludge in ADSA,ADSB and ADSC were 0.42 0.507 and 0.511 m3 biogass/kg.VS.d ; compared with the biogas yield in anaerobic digestion system A (ADSA), the biogas yield in anaerobic digestion system B (ADSB) and anaerobic digestion system C (ADSC) had been increased by more than 20% respectively; the SRF of three digested sludge are(were) from 6.8×10^13, 1. 1×10^13 to 5.1×10^12 m/Kg, natural settling rates of 12 h are 26, 37 and 56% and that of 24 h are 32%, 45% and 59% respectively; the centrifugal dewatering rate of 3 min at speed of 1000 rpm were 16%, 31% and 51% respectively; the turbidity of centrifugal supernatant were 804, 754 and 678FTU simultaneously. 展开更多
关键词 anaerobic co-digestion secondary sludge distillerywastewater dewatering property
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Hydration Properties of Calcined Clay Pozzolan and Limestone Mineral Admixtures in Binary and Ternary Cements
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作者 Eugene Atiemo Charles Kwame Kankam +1 位作者 Francis Momade Kwabena Appiah Boakye 《Journal of Physical Science and Application》 2014年第5期323-327,共5页
This paper investigates the properties of hydrated binary and ternary blended cements using limestone and calcined clay pozzolan as supplementary cementitious materials. The blended cements were hydrated and their pha... This paper investigates the properties of hydrated binary and ternary blended cements using limestone and calcined clay pozzolan as supplementary cementitious materials. The blended cements were hydrated and their phase compositions were evaluated by thermogravimetric and powder X-ray diffraction at 28 days. The morphology of the samples was also determined. The water demand, setting time, compressive and flexural strengths of mortar and concrete samples were determined up to 365 days. The study concluded that the portlandite [Ca(OH)2] content was considerably reduced whilst ettfingite formation were enhanced as a result of admixture reactions. The water demand and setting times of blended cements were lower than OPC with 5% admixture content but higher with increasing content. The mechanical test results also showed that Class 42.5N and 32.5R cements can be produced from the binary and ternary blends containing up to 10% and 20% admixtures, respectively. 展开更多
关键词 LIMESTONE calcined clay pozzolan supplementary cementitious materials ADMIXTURES portlandite ETTRINGITE strength.
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Hydration and Mechanical Properties of Portland Cement Blended with Low-CaO Steel Slag
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作者 Eugene Atiemo Kwabena Appiah Boakye James Sarfo-Ansah 《Journal of Physical Science and Application》 2014年第7期444-449,共6页
The hydration and mechanical properties of Portland cement blended with low-CaO steel slag were studied and reported. The steel slag was used to replace cement up to 30% and then blended cement powder, paste and morta... The hydration and mechanical properties of Portland cement blended with low-CaO steel slag were studied and reported. The steel slag was used to replace cement up to 30% and then blended cement powder, paste and mortar samples prepared for the experiment. The quantitative analysis of XRD shows that ettringite formation is greatly reduced by incorporation of steel slag but there was a relatively low reduction of portlandite. Thermal analysis by TG shows that slag injection reduced portlandite content in the cement by at least 50%. Generally, the slag cement pastes required less water to form a workable paste compared to the reference cement, reducing as the slag content was increased. However, the setting times were higher than the reference. The permeability of the blended cement samples were lower than the control. The incorporation of 5% slag could not have an effect on the compressive strength of the concrete. The results confirmed that whilst cements with up to 15% slag content satisfied the strength requirements of class 42.5 N and those containing 20%-30% produce Class 32.5R cement. 展开更多
关键词 HYDRATION cement low-CaO steel slag ETTRINGITE portlandite permeability.
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