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碳化作用对水泥净浆中游离氯离子浓度的影响 被引量:2
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作者 江乐鑫 杨梦娜 +1 位作者 柳俊哲 林楠 《水资源与水工程学报》 CSCD 2020年第2期190-195,共6页
以探究碳化作用对水泥净浆中游离氯离子浓度的影响为目标,并借助XRD衍射图谱、SEM扫描电镜图等微观手段,研究了碳化作用下水泥净浆内游离氯离子浓度的影响规律以及微观结构特征。结果表明:水灰比对碳化作用前游离氯离子浓度的影响变化... 以探究碳化作用对水泥净浆中游离氯离子浓度的影响为目标,并借助XRD衍射图谱、SEM扫描电镜图等微观手段,研究了碳化作用下水泥净浆内游离氯离子浓度的影响规律以及微观结构特征。结果表明:水灰比对碳化作用前游离氯离子浓度的影响变化受总氯离子浓度的影响,总氯离子浓度越高,水灰比对游离氯离子浓度的影响越大;碳化不利于氯离子的结合,一方面是因为碳化作用不利于Friendel盐的生成和稳定,减少了离子化学固化量。另一方面水化产物中的C-S-H凝胶的生成量也减少,大量的Ca^2+被消耗,Ca/Si比也减小,削弱了物理吸附作用,减少了离子物理吸附量,从而增大了水泥净浆中游离氯离子浓度;碳化能显著细化孔隙结构,减少孔隙率,有利于减弱游离氯离子的扩散与侵蚀。 展开更多
关键词 碳化 水泥净浆 水灰比 氯离子 水泥浆微观结构
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Performance of grouts for post-tensioned prestressed structures 被引量:1
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作者 田倩 孙伟 +1 位作者 刘加平 缪昌文 《Journal of Southeast University(English Edition)》 EI CAS 2004年第4期492-497,共6页
New high performance grouts with high volume stability and good fluidity were prepared with Portland cement and a multifunctional admixture (MFA). The theological characteristics and mechanical performance of the grou... New high performance grouts with high volume stability and good fluidity were prepared with Portland cement and a multifunctional admixture (MFA). The theological characteristics and mechanical performance of the grouts were investigated. The addition of MFA effectively improves the pseudo-plasticity of the grout. The Ma cone flow time decreases obviously, and the bleeding rate tends to be zero. The deformation behaviors of fresh mixture and hardened grout are systematically studied. Mercury injection method (MIP), scanning electron microscopy (SEM) and X-ray diffractory analysis experiments are used to analyze the microstructure evolution of the grouts, which manifests that the co-action of the early bubble reaction and the latter ettringite crystallization ensure the volume stability throughout the whole hydration process and result in refined pore structure of the grout. 展开更多
关键词 CEMENTS DEFORMATION Mechanical properties MICROSTRUCTURE Prestressed materials Scanning electron microscopy X ray diffraction analysis
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