外加剂对低温水泥浆性能的影响试验研究

为解决在普通硅酸盐水泥(P.O42.5)或混凝土施工中遭遇低温环境而不能顺利凝固的问题。对普遍使用的硅酸盐水泥进行了基础性能测试试验,使用早强剂与高效减水剂对水泥进行调整性能,寻找出最佳的调整方案,对比调整前后水泥浆及水泥石强度等各项数据。结果表明10%早强剂、2‰JSS高效减水剂的调整方案较好地改善了水泥浆的流动性、凝结时间、水化热放热速率、结石率及水泥石的早期强度等问题。研究成果对低温条件下的混凝土施工有一定的参考价值。

功能单体对聚羧酸减水剂性能的影响

采用自由基聚合法,以丙烯酰胺(AM),N,N-二甲基丙烯酰胺(DMAA)和2-丙烯酰胺基-2-甲基丙磺酸(AMPS)作为功能单体,以不同摩尔比替代聚羧酸减水剂合成过程中小分子单体丙烯酸(AA),合成一系列带有不同官能团的聚羧酸减水剂,采用傅里叶红外表征了减水剂的分子结构,通过测试掺有减水剂的水泥净浆流动度、减水剂在水泥浆体中的吸附量、水泥浆体的zeta电位及水泥水化热曲线,来研究不同主链官能团对减水剂各项性能的影响,结果表明:功能单体AM,DMAA,AMPS完全代替AA后,所合成的减水剂对水泥浆体的减水分散能力均有所减弱,甚至完全丧失;减水剂分子链所带负电荷越多,其在水泥浆体中吸附量越大;-SO_3^-对减水剂在水泥表面的吸附能力贡献小于-COO^-,这主要是-COO^-与Ca^(2+)较强的络合作用所致;羧基是减水剂对水泥水化进程起到延缓作用的关键因素。

Study on the compatibility of cement-superplasticizer system based on the amount of free solution

The changes of free solution amount, fluidity and the time-depended fluidity loss of cement paste were examined by varying the water-cement ratio and the dosages of superplasticizer. The distribution of solution and flocculation microstructure in flesh cement paste was observed with optical microscope. The change of free solution amount and its effect on the fluidity and bleeding of cement paste was studied. The results show that the adsorbed solution amount has a great influence on the com- patibility of cement-superplasticizer system, including the bleeding degree, the fluidity and the time-depended fluidity loss of cement paste. Superplasticizer increases the fluidity of cement paste by destroying the flocculated cement particle structure and increasing the amount of adsorbed solution. Polycarboxylate superplasticizer shows higher ability of adsorption than naphtha- lene superplasticizer. Over dosage of superplasticizer is not the primary cause of bleeding. The principle reason of bleeding is the high water-cement ratio and the insufficient enhancing ability of water adsorption of superplasticizer.