水泥窑协同处置污泥和水泥物料中汞元素的测定方法研究

本文使用原子荧光光谱仪对水泥窑协同处置污泥和水泥物料中的汞元素的测定方法进行了研究开发。方法中采用倒王水沸水浴对污泥和水泥物料的样品等进行了沸水浴水浴溶解,以5%盐酸作为载流液,0.5%氢氧化钾和1.5%硼氢化钾作为还原剂,并优化了原子荧光光谱仪的测定条件,对样品检出限、精密度、准确度和回收率进行了实验研究。

水泥窑协同处置污泥及物料中重金属测定方法开发

本方法使用原子吸收光谱仪和原子荧光光谱仪对13种有毒有害重金属元素铜、铅、铬、镉、镍、钒、铊、汞、砷及锑等测定方法进行开发。方法中采用了酸组合体系、水浴法和微波消解方法对污泥、水泥及物料等进行了溶样方法探讨;对使用相关仪器测定时对应元素的仪器条件进行了优化;对样品的溶解程度、各元素的线性范围、检出限、精密度、准确度,以及回收率进行了实验研究和测定。

动态物料配比控制系统

本文介绍了用８０３１单片机实现水泥生产物料配比控制的硬件配置、软件设计及其特点。

水泥厂磨机节电技术

在水泥生产中,物料的粉磨量很大,每生产一吨水泥需粉磨各种物料3.5吨左右,粉磨作业电耗约占水泥总电耗的60～70%.降低粉磨作业电耗对水泥节能具有很重要的意义. 本文重点论述磨机的节电技术改造、应用的技术、新工艺和新材料.

复配乳液聚合物水泥防水涂料防护效果研究

本文以丙烯酸酯乳液和氯丁橡胶乳液复配的方法制备聚合物水泥防水涂料,以解决单一聚合物乳液水泥防水涂料在应用过程中易开裂、柔性不足等问题。将其涂覆于水泥砂浆试块表面,探讨了涂层对氯盐侵蚀、硫酸盐侵蚀、冻融循环、自然环境侵蚀下水泥砂浆试块质量、抗压强度的影响,分析了涂层对试块的防护效果。结果显示涂层水泥砂浆试块均无开裂、剥落现象,试块的质量损失率、抗压强度损失率均较小。采用复配乳液并添加外加剂制得涂层对水泥砂浆试块的防护效果最优,试块在氯盐、硫酸盐侵蚀180天、冻融循环100次后的抗压强度损失率分别为9.45%、10.84%、12.16%,自然环境侵蚀120天后,试块抗压强度可保持为29.80MPa远高于无涂层试块。还以其中防护效果最优配方制备聚合物水泥防水涂料,探讨了涂层涂覆方法对自然环境侵蚀下涂层水泥砂浆试块抗压强度的影响。结果显示固定涂层厚度,分多次涂覆制得涂层更致密,交叉涂覆方法制得涂层厚度更均匀,沿十字交叉方向分三次涂覆制得涂层对水泥砂浆试块的防护效果更优。

闭路破碎与节电效果

统计资料表明,水泥企业约有70%的电能消耗在物料的破碎与粉磨中.从能量的有效利用程度来看,粉碎是一个效率很低的过程.对于破碎机械来说,有效系数一般在0.2～0.4范围内,而粉磨机械一般在0.05～0.15范围内.生产和科研实验资料指出:物料破碎得细而均匀,就能提高磨机的产质量,且能降低破碎与粉磨的总电耗.因此,

Real-time in situ visualization of internal relative humidity in fluorescence embedded cement-based materials

The transmission and distribution of moisture in cement-based materials are of great significance to the properties and durability of materials. Traditional macro-humidity monitoring equipment in civil engineering cannot capture the microscale humidity inside cement-based materials in situ. In this paper, a method of using rhodamine 6G fluorescence to characterize the change in relative humidity in cement-based materials is proposed. Two kinds of moulding processes are designed, which are premixed and smeared after moulding, and the optimal preparation concentration is explored. The results showed that rhodamine 6G can reflect the relative humidity of cement-based materials in situ by its fluorescence intensity and had little effect on the hydration heat release and hydration products of cement-based materials;the fluorescence intensity was much higher when the internal relative humidity was 63% and 75%. The research results lead the application of polymer materials in the field of traditional building materials, help to explore the performance evolution law of cement-based materials in micro scale, and have important significance for the evolution from single discipline to interdisciplinary.

Permeability modeling of self-healing due to calcium carbonate precipitation in cement-based materials with mineral additives

The permeability modeling of self-healing due to calcium carbonate precipitation in cement-based materials with mineral additives was studied in this work. The parameters of calcium carbonate precipitation during self-healing were simulated. A permeability modeling of self-healing, combined with numerical simulation of calcium carbonate formation, was proposed based on the modified Poiseuille flow model. Moreover, the percentage of calcium carbonate in healing products was measured by TG-DTA. The simulated results show that self-healing can be dramatically promoted with the increase of pH and Ca2+ concentration. The calculated result of permeability is consistent with that measured for cracks appearing in middle or later stages of self-healing, it indicates that this model can be used to predict the self-healing rate to some extent. In addition, TG-DTA results show that the percentage of calcium carbonate in healing products is higher for mortar with only chemical expansion additives or cracks appearing in the later stage, which can more accurately predict the self-healing rate for the model.

Utilization of Concrete Waste Aggregates Using Geopolymer Cement

Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.

Influence of Mineral Admixtures on Essential Properties of Ternary Cement Blends

Two CaCO3-based materials （limestone and clamshells） and steel slag were used as mineral admixtures in cement to produce ternary blends and their influences on hydration and portlandite formation were analyzed. Additionally, mechanical properties were determined. These properties were determined using X-ray diffraction and scanning electron microscopic/energy dispersive X-ray analytical techniques as well as applying methods specified by EN （European Standards） and ASTM （American Standards for Testing and Materials）. The portlandite （Ca（OH）E） content was considerably reduced from 36.9% of reference cement to between 13.79% and 15.5%. With the water demand and setting times of the cements containing up to 10%, admixtures did not change significantly. The mechanical tests results showed that ternary blends produced 2-day strengths higher than that specified by EN 197-1 and that blends containing up to 20% admixtures can be used to produce both Class 32.5N and 42.5N cements.

Characterization of Stabilized Earth Blocks with Incorporation of Cement Expanded Polystyrene for Use in Buildings

This work focuses on the development of local building materials in Benin for their efficient use in buildings. It aims to make mud bricks lightened with good mechanical, thermal and sound properties and enhance the waste polystyrene. This article is the result of experimental work on a broad field of applied sciences： building mechanics. The study is focused on BTS （blocks of stabilized earth） chosen as reference materials to which we linked polystyrene. The percentage of polystyrene varies from 0% to 100% starting from a constant volume of each reference material. The results showed that the increase in polystyrene percentage lowers mechanical properties. These results also showed that the gradual addition of polystyrene to the laterite-cement mixture has a significant influence on the density and mechanical resistances of the final composite material.

Experimental Study of Concrete Column Shape Modification Using Fiber Reinforced Polymer Composite Shells and Expansive Cement Concrete

Fiber Reinforced Polymer （FRP） composites are an effective material for strengthening circular concrete columns. The effectiveness of FRP confinement for square and rectangular columns is greatly reduced due to stress concentrations at the sharp comers and loss of the membrane effect at the fiat sides of the cross-section. Shape modification can eliminate the effects of column comers and flat sides, and thereby restore the membrane effect and improve the compressive behavior of FRP-confined square and rectangular concrete columns. Shape modification using chemical post-tensioning, achieved by using expansive cement concrete, is described and several mix designs for obtaining the optimal level of expansion are presented. In addition, parametric studies regarding the optimal geometry of the shape-modified cross-section are presented utilizing the analytical model.

The Study of Resistance of Cement Composites against Microbial Attack

The start and the course of bio-corrosion are conditioned by many factors which include biological effects like the influence of vegetation and microorganisms causing the deterioration of materials. The influence of bacteria causing the deterioration of concrete has been linked to the generation of biogenic sulphuric and nitric acids which originate in corrosion process by dissolution of calcium containing minerals from the concrete matrices. This paper primarily focuses on the investigation of influence of sulphur-oxidising bacteria Acidithiobacillus thiooxidans and sulphate-reducing bacteria Desulfovibrio desulfuricans at the resistance degree of cement composites. Various concrete composites with 5% addition of black coal fly ash as cement replacement as well as the reference samples without coal fly ash addition were studied in the experiments environments of sewage system proceeded during 90 days. The The laboratory experiments as well as experiments in situ in real corrosion was manifested by surface changes and weight changes of cement composites samples as well as changes in pH values of leachates. Considerable surface changes were detected in all investigated samples by microscopic methods. Crystals precipitated on concrete samples surface were identified by EDX as mixture of gypsum and ettringite. The roughness increases of surface of cement microscopy. composites were determined by confocal laser scanning

Experimental Study on the Use of Trass as a Supplementary Cementitious Material in Pervious Concrete

Abstract： The purpose of this paper is to evaluate the suitability of using trass as a supplementary cementing material in pervious concrete. OPC （Ordinary Portland Cement） was replaced in the concrete mix by 15%, 25% and 35% weight percentages and the results were compared with reference mixtures with 100% Portland cement. The variables in this study were trass content, aggregate size and water to cement ratio. Sixteen eases of concrete mixtures were tested to study physical and mechanical properties of hardened concrete, including porosity, permeability, compressive strength, splitting-tensile strength and flexural strength at various ages. Results indicated that mechanical properties of the pervious concrete marginally decreased with the increased content of trass when compared to the reference mixtures. However, at later ages the differences were insignificant.

CO_2 Emissions from Typical Cement Plants in China

The objective is to know how the CO2 emits and how much the CO2 emits due to the cement manufacture in both direct and indirect ways with the increasing concerns about the global warming and the cement plants emitting huge CO2.A precise method to calculate CO2 emissions including three processes was established in this paper and a case study was provided.From the case of 23 typical plants in China,we can see the amount of CO2 emissions at the right level.The summary of CO2 emissions consists of emissions from raw materials,fuels and electricity.The average result of the 23 typical plants is 0.74 t CO2 per ton clinker in this study.Therefore,CO2 emissions from these typical cement plants were pictured and then measured.The creative point is that an approach provides a basic framework to identify various situations in different cement plants in China and other in the rest of the world.The framework would be useful in quantitatively evaluating CO2 emissions for government to know precisely CO2 emissions in the cement plants.