A TiO2 photocatalyst is coated on the surface of a zeolite fly ash bead(ZFAB) to improve its dispersability and exposure degree in a cement system.The application of Ag particles in TiO2/ZFAB modified cementitious m...A TiO2 photocatalyst is coated on the surface of a zeolite fly ash bead(ZFAB) to improve its dispersability and exposure degree in a cement system.The application of Ag particles in TiO2/ZFAB modified cementitious materials is to further enhance the photocatalytic performance.Various Ag@TiO2/ZFAB modified cementitious specimens with different Ag dosages are prepared and the characteristics and photocatalytic performance of the prepared samples are investigated.It is observed that the multi-level pore structure of ZFAB can improve the exposure degree of TiO2 in a cement system and is also useful to enhance the photocatalytic efficiency.With an increment of the amounts of Ag particles in the TiO2/ZFAB modified cementitious samples,the photocatalytic activities increased first and then decreased.The optimal Ag@TiO2/ZFAB modified cementitious sample reveals the maximum reaction rate constant for degrading benzene(9.91×10^-3 min^-1),which is approximately 3 and 10 times higher than those of TiO2/ZFAB and TiO2 modified samples,respectively.This suggests that suitable Ag particles coupled with a ZFAB carrier could effectively enhance the photocatalytic effects and use of TiO2 in a cement system.Thus,ZFAB as a carrier could provide a potential method for a high efficiency engineering application of TiO2 in the construction field.展开更多
Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive ...Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive mined-out gobs, enormous ore body under roadway and low recovery ratio of Yongshaba Mine, Kaiyang Phosphor Mine Group, Guizhou Province, China. An appropriate backfill system and craflwork were designed, using shattering milling method to crush gypsum, double-axles mixing and strong activation mixing way to mix slurry, cemented slurry and mullock backfill alternately process. The results show that gypsum is fit for backfilling afterwards by adding fly ash, though it is not an ideal aggregate for fine granule and coagulate retardation. The suggested dosage (the mass ratio of cement to fly ash to gypsum) is 1:1:6-1:1:8 with mass fraction of solid materials 60%-63%. Slurry is transported in suspend state with non-plastic strength, and then in concretion state after backfilling. The application to mine shows the technology is feasible, and gypsum utilization ratio is up to 100%. Transportation and backfill effect is very good for paste-like slurry and drenching cemented slurry into mullock, and the compressive strength and recovery ratio are 2.0 MPa and 82.6%, respectively, with the maximum subsidence of surface only 1.307 mm. Furthermore, the investment of system is about 7 × 10^6 yuan (RMB), only 1/10 of that of traditional paste backfill system.展开更多
Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the ...Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the underlying untreated stratum. Due to the changing permeability property of CFG piles, the whole consolidation process of the composite ground with CFG piles was divided into two stages, i.e., the early stage(permeable CFG pile bodies) and the later stage(impermeable pile bodies). Then, the consolidation equation of the composite foundation with CFG piles was established by using the Terzaghi one-dimensional consolidation theory. Consequently, the unified formula to calculate the excess pore water pressure was derived with the specific solutions for the consolidation degree of composite ground, reinforced area and underlying stratum under instant load obtained respectively. Finally, combined with a numerical example, influencing rules by main factors(including the replacement rate m, the treatment depth h1, the permeability coefficient Ks1, Kv2 and compression modulus Es1, Es2 of reinforced area and underlying stratum) on the consolidation property of composite ground with CFG piles were discussed in detail. The result shows that the consolidation velocity of underlying stratum is slower than that of the reinforced area. However, the consolidation velocity of underlying stratum is slow at first then fast as a result of the transferring of effective stress to the underlying stratum during the dissipating process of excess pore water pressure.展开更多
Based on back analysis of lateral displacements measured in situ by using the analytical solution, a useful method for estimating stress concentration ratio of geosynthetic-reinforced and pile-supported(GRPS) embankme...Based on back analysis of lateral displacements measured in situ by using the analytical solution, a useful method for estimating stress concentration ratio of geosynthetic-reinforced and pile-supported(GRPS) embankments was proposed. In order to validate the proposed method, a full-scale high-speed railway embankment(HSRE) with four instrumented subsections over medium compressibility silty clay was constructed in three stages. The soil profile, construction procedure and monitoring of settlements and lateral displacements of the four test sections were described. The field deformation analysis results show that 1) the combined reinforcement of CFG piles and geosynthetic layer perform well in terms of reducing lateral displacements; 2) the development of lateral displacements lags behind the increase of fill load, which can be attributed to the vertical load transfer mechanism of the pile foundation; and 3) pile length has a dominant effect on the stress distribution proportion between piles and surrounding soils. The comparison between predicted and experimental results suggests that the proposed analytical solution and the back analysis-based method are capable of reasonably estimating the lateral deformation and the stress concentration ratio, respectively, if the appropriate soil elastic modulus is chosen.展开更多
The paper describes assessment of the performance of cement-poor concretes on the basis of packing theory. The concretes are intended for sealing segments of deep boreholes and have a small amount of cement for minimi...The paper describes assessment of the performance of cement-poor concretes on the basis of packing theory. The concretes are intended for sealing segments of deep boreholes and have a small amount of cement for minimizing the mutual chemical impact on the contacting clay seals. The composition is examined by application of packing theory with respect to the cement/aggregate ratio and the gradation of the aggregate material which is crushed quartzite for providing high internal friction after maturation, as well as to talc added for fluidity and to the small amount of cement. Low porosity and micro-structural stability must be guaranteed for very long periods of time. The study exemplifies how packing theory assist designers in selecting optimal proportions of the various components. Optimum particle packing implies minimizing the porosity and thereby reducing the amount of cement paste needed to fill the voids between the aggregate particles. The use of talc as inorganic super-plasticizer since ordinary organic additives for reaching high fluidity at casting are undesirable, and since talc reacts with cement and provides high strength in along-term perspective.展开更多
This article studies the effects of limestone powder on rheological properties of cement - fly ash mortar with RHEOLAB QC type rotation viscometer. The Bingham fluid model is introduced to fit the yielding stress and ...This article studies the effects of limestone powder on rheological properties of cement - fly ash mortar with RHEOLAB QC type rotation viscometer. The Bingham fluid model is introduced to fit the yielding stress and plastic viscosity of the mortar. The POWER LAW fluid model is introduced to fit the rheological index of the mortar. The results show that, adding limestone powder and fly ash to the cement mortar significantly decreases the yield stress of the mortar, changes the plastic viscosity of the mortar, increases the rheological index, decreases the degree of shear thinning of the mortar, and thereby improves the mortar' s workability. In the case of cement - fly ash mortar, with the increase of limestone powder content, both the yield stress and plastic viscosity of the mortar increase. When the limestone powder content is not higher than 14%, the increase of yield stress is not significant. When the limestone powder content is lower than 8%, the increase of plastic viscosity is not significant. When the content of limestone powder is higher than 22%, the rheological index of the mortar decreases and the degree of shear thinning increases. The effects of limestone powder' s packing density, shape and size, specific surface area, and fluid volume, are found to be the four major factors responsible for the changes ofrheological properties of the mortar.展开更多
基金supported by the National Natural Science Foundation of China (51478370)the Engineering and Physical Sciences Research Council of UK–Natural Science Foundation of China (EPSRC-NSFC) International Joint Research Project (51461135005)~~
文摘A TiO2 photocatalyst is coated on the surface of a zeolite fly ash bead(ZFAB) to improve its dispersability and exposure degree in a cement system.The application of Ag particles in TiO2/ZFAB modified cementitious materials is to further enhance the photocatalytic performance.Various Ag@TiO2/ZFAB modified cementitious specimens with different Ag dosages are prepared and the characteristics and photocatalytic performance of the prepared samples are investigated.It is observed that the multi-level pore structure of ZFAB can improve the exposure degree of TiO2 in a cement system and is also useful to enhance the photocatalytic efficiency.With an increment of the amounts of Ag particles in the TiO2/ZFAB modified cementitious samples,the photocatalytic activities increased first and then decreased.The optimal Ag@TiO2/ZFAB modified cementitious sample reveals the maximum reaction rate constant for degrading benzene(9.91×10^-3 min^-1),which is approximately 3 and 10 times higher than those of TiO2/ZFAB and TiO2 modified samples,respectively.This suggests that suitable Ag particles coupled with a ZFAB carrier could effectively enhance the photocatalytic effects and use of TiO2 in a cement system.Thus,ZFAB as a carrier could provide a potential method for a high efficiency engineering application of TiO2 in the construction field.
基金Project(2006BAB02A03)supported by the National Key Technology Research and Development ProgramProject(08MX16)supported by Mittal Scientific and Technological Innovation Projects of Central South University during 2008
文摘Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive mined-out gobs, enormous ore body under roadway and low recovery ratio of Yongshaba Mine, Kaiyang Phosphor Mine Group, Guizhou Province, China. An appropriate backfill system and craflwork were designed, using shattering milling method to crush gypsum, double-axles mixing and strong activation mixing way to mix slurry, cemented slurry and mullock backfill alternately process. The results show that gypsum is fit for backfilling afterwards by adding fly ash, though it is not an ideal aggregate for fine granule and coagulate retardation. The suggested dosage (the mass ratio of cement to fly ash to gypsum) is 1:1:6-1:1:8 with mass fraction of solid materials 60%-63%. Slurry is transported in suspend state with non-plastic strength, and then in concretion state after backfilling. The application to mine shows the technology is feasible, and gypsum utilization ratio is up to 100%. Transportation and backfill effect is very good for paste-like slurry and drenching cemented slurry into mullock, and the compressive strength and recovery ratio are 2.0 MPa and 82.6%, respectively, with the maximum subsidence of surface only 1.307 mm. Furthermore, the investment of system is about 7 × 10^6 yuan (RMB), only 1/10 of that of traditional paste backfill system.
基金Project(51378197)supported by the National Natural Science Foundation of China
文摘Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the underlying untreated stratum. Due to the changing permeability property of CFG piles, the whole consolidation process of the composite ground with CFG piles was divided into two stages, i.e., the early stage(permeable CFG pile bodies) and the later stage(impermeable pile bodies). Then, the consolidation equation of the composite foundation with CFG piles was established by using the Terzaghi one-dimensional consolidation theory. Consequently, the unified formula to calculate the excess pore water pressure was derived with the specific solutions for the consolidation degree of composite ground, reinforced area and underlying stratum under instant load obtained respectively. Finally, combined with a numerical example, influencing rules by main factors(including the replacement rate m, the treatment depth h1, the permeability coefficient Ks1, Kv2 and compression modulus Es1, Es2 of reinforced area and underlying stratum) on the consolidation property of composite ground with CFG piles were discussed in detail. The result shows that the consolidation velocity of underlying stratum is slower than that of the reinforced area. However, the consolidation velocity of underlying stratum is slow at first then fast as a result of the transferring of effective stress to the underlying stratum during the dissipating process of excess pore water pressure.
基金Project(2010G003-F)supported by Technological Research and Development Programs of the Ministry of Railways,China
文摘Based on back analysis of lateral displacements measured in situ by using the analytical solution, a useful method for estimating stress concentration ratio of geosynthetic-reinforced and pile-supported(GRPS) embankments was proposed. In order to validate the proposed method, a full-scale high-speed railway embankment(HSRE) with four instrumented subsections over medium compressibility silty clay was constructed in three stages. The soil profile, construction procedure and monitoring of settlements and lateral displacements of the four test sections were described. The field deformation analysis results show that 1) the combined reinforcement of CFG piles and geosynthetic layer perform well in terms of reducing lateral displacements; 2) the development of lateral displacements lags behind the increase of fill load, which can be attributed to the vertical load transfer mechanism of the pile foundation; and 3) pile length has a dominant effect on the stress distribution proportion between piles and surrounding soils. The comparison between predicted and experimental results suggests that the proposed analytical solution and the back analysis-based method are capable of reasonably estimating the lateral deformation and the stress concentration ratio, respectively, if the appropriate soil elastic modulus is chosen.
文摘The paper describes assessment of the performance of cement-poor concretes on the basis of packing theory. The concretes are intended for sealing segments of deep boreholes and have a small amount of cement for minimizing the mutual chemical impact on the contacting clay seals. The composition is examined by application of packing theory with respect to the cement/aggregate ratio and the gradation of the aggregate material which is crushed quartzite for providing high internal friction after maturation, as well as to talc added for fluidity and to the small amount of cement. Low porosity and micro-structural stability must be guaranteed for very long periods of time. The study exemplifies how packing theory assist designers in selecting optimal proportions of the various components. Optimum particle packing implies minimizing the porosity and thereby reducing the amount of cement paste needed to fill the voids between the aggregate particles. The use of talc as inorganic super-plasticizer since ordinary organic additives for reaching high fluidity at casting are undesirable, and since talc reacts with cement and provides high strength in along-term perspective.
文摘This article studies the effects of limestone powder on rheological properties of cement - fly ash mortar with RHEOLAB QC type rotation viscometer. The Bingham fluid model is introduced to fit the yielding stress and plastic viscosity of the mortar. The POWER LAW fluid model is introduced to fit the rheological index of the mortar. The results show that, adding limestone powder and fly ash to the cement mortar significantly decreases the yield stress of the mortar, changes the plastic viscosity of the mortar, increases the rheological index, decreases the degree of shear thinning of the mortar, and thereby improves the mortar' s workability. In the case of cement - fly ash mortar, with the increase of limestone powder content, both the yield stress and plastic viscosity of the mortar increase. When the limestone powder content is not higher than 14%, the increase of yield stress is not significant. When the limestone powder content is lower than 8%, the increase of plastic viscosity is not significant. When the content of limestone powder is higher than 22%, the rheological index of the mortar decreases and the degree of shear thinning increases. The effects of limestone powder' s packing density, shape and size, specific surface area, and fluid volume, are found to be the four major factors responsible for the changes ofrheological properties of the mortar.