期刊文献+
共找到5篇文章
< 1 >
每页显示 20 50 100
含长碳链季铵盐的丙烯酰胺类共聚物的合成及其水溶液特性
1
作者 李兰 黄焰根 孟卫东 《东华大学学报(自然科学版)》 CAS 北大核心 2022年第3期39-45,74,共8页
以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)和二烯丙基长链烷基苄基溴化铵(DC_(n)AB,n=14,16,18)为单体,通过胶束聚合法制备含长碳链季铵盐的丙烯酰胺类共聚物PAMQ1、PAMQ2、PAMQ3。通过核磁共振氢谱和红外光谱对共聚物分子结构... 以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)和二烯丙基长链烷基苄基溴化铵(DC_(n)AB,n=14,16,18)为单体,通过胶束聚合法制备含长碳链季铵盐的丙烯酰胺类共聚物PAMQ1、PAMQ2、PAMQ3。通过核磁共振氢谱和红外光谱对共聚物分子结构进行表征,通过热重分析仪和流变仪对共聚物的热稳定性和水溶液特性进行测试。结果表明:PAMQ1、PAMQ2、PAMQ3具有较高的热稳定性(主链的热失重温度均高于320℃)和表面活性以及较好的耐温、耐剪切和耐盐性能,且对水相有一定的增黏能力;80℃时溶液的表观黏度分别为40.0、43.7和50.8 mPa·s;剪切速率为200 s^(-1)时溶液的表观黏度分别为26.2、29.5和33.8 mPa·s;当NaCl和CaCl 2的质量浓度分别为200.0和30.0 g/L时,溶液的表观黏度最高分别保留至45.1和57.7 mPa·s;共聚物对稠油有一定乳化降黏能力,降黏率为78.2%~85.7%。季铵盐单体结构中长碳烷基链和苄基对共聚物性能具有显著影响。 展开更多
关键词 丙烯酰胺共聚物 季铵盐 水溶液特性 流变性能 乳化降黏 稠油
下载PDF
脂肪醇嵌段聚醚丙烯酸酯与丙烯酰胺共聚物及其水溶液特性的研究
2
作者 朱卓岩 欧阳坚 +1 位作者 王贵江 孙广华 《精细与专用化学品》 CAS 2004年第15期17-19,16,共4页
本文合成了脂肪醇嵌段聚醚丙烯酸酯单体 ,并与丙烯酰胺共聚 ,得到共聚物PEPO PAM。芘荧光光谱分析表明 ,该聚合物在水溶液中依靠分子链上的疏水基团形成一定的缔合作用。PEPO PAM相对于部分水解聚丙烯酰胺 (HPAM )具有更好的增粘性。通... 本文合成了脂肪醇嵌段聚醚丙烯酸酯单体 ,并与丙烯酰胺共聚 ,得到共聚物PEPO PAM。芘荧光光谱分析表明 ,该聚合物在水溶液中依靠分子链上的疏水基团形成一定的缔合作用。PEPO PAM相对于部分水解聚丙烯酰胺 (HPAM )具有更好的增粘性。通过调整分子的组成 ,可使该聚合物不仅具有较强的增粘性 ,同时具有良好的水溶性。 展开更多
关键词 脂肪醇嵌段聚醚丙烯酸酯 丙烯酰胺 共聚物 水溶液特性 水溶性高分子 疏水缔合 耐盐增粘
原文传递
Effect of Salt Solution on Characteristics of Soil Infiltration
3
作者 陈曦 潘英华 +1 位作者 郝春红 谭妍青 《Agricultural Science & Technology》 CAS 2012年第2期357-360,438,共5页
[Objective] The aim was to study the effect of salt solution on characteristics of soil infiltration, and to provide references for the further studies on the effect of water quality on soil infiltration characteristi... [Objective] The aim was to study the effect of salt solution on characteristics of soil infiltration, and to provide references for the further studies on the effect of water quality on soil infiltration characteristics and its mechanism. [Method] With the NaCl, CaCl2 solutions as the main test materials, the effect of different water quality and salt solution concentration on soil infiltration was studied under one-dimensional vertical ponded water infiltration at laboratory. [Result] The solution concentration could affect the infiltration performance. The trends of the infiltration rates, cumulative infiltrations and wetting front migration distances were all 50 mg/L 100 mg/L 10 mg/L. At the same concentration, the effect of NaCl solution on soil infiltration characteristics was more significant than CaCl2 solution: in the same time, cumulative infiltration and wetting front migration distance of NaCl solution were greater than CaCl2 solution; compared with NaCl solution, CaCl2 solution took longer time to infiltrate the same amount of water. The dynamic changes of infiltration rate, wetting front and cumulative infiltration were well fitted to the Philip model. [Conclusion] This study only conducted indoor experiment to the infiltration of salt solutions, involving in low concentration and small range. Although it provided some references for the study on the effect of water quality on soil infiltration characteristics and its mechanism, studies in larger areas and with bigger concentrations are demanding. 展开更多
关键词 Salt solution Soil moisture Infiltration characteristics
下载PDF
Effect of Injection Parameters on Evaporation and Thermolysis Characteristics of UWS (Urea-Water-Solution) in SCR (Selective Catalytic Reduction) Systems
4
作者 Sadashiva Prabhu S Nagaraj Shivappa Nayak Kapilan Natesan 《Journal of Energy and Power Engineering》 2015年第2期222-231,共10页
UWS (optimized Urea-Water Solution) injection system is required to increase the NH3 conversion efficiency of urea-based SCR (Selective Catalytic Reduction) system of modem automobiles. The focus of the current st... UWS (optimized Urea-Water Solution) injection system is required to increase the NH3 conversion efficiency of urea-based SCR (Selective Catalytic Reduction) system of modem automobiles. The focus of the current study is to do parametric studies by simulation in a three-dimensional model using CFD (Computational Fluid Dynamics) code AVL FIRE. Simulations were carried out to study the characteristics of evaporation and thermolysis UWS considering the effect of injection velocity, duration of injection, injection angle and for different types of injection. In the case of the injection velocities up to 20-50 m/sec, the ammonia concentration continues to increase. It is found that as the duration injection decreases, the concentration of ammonia increases. In case of continuous injection, the flow rate is less which results in lower velocity of injection, lesser atomization and slower evaporation resulting lesser conversion of UWS into NH3. Shorter duration of injection leads better atomization with increased velocity of injection which results in faster evaporation and thermolysis. 展开更多
关键词 EVAPORATION THERMOLYSIS SCR UWS injection parameters.
下载PDF
Drag-reduction of a nonionic surfactant aqueous solution and its rheological characteristics 被引量:7
5
作者 CAI ShuPeng SUZUKI Hiroshi KOMODA Yoshiyuki 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第3期772-778,共7页
In order to develop turbulent drag-reducing technology by using an environmentally friendly additive in a water-transporting system,the drag reducing characteristics in a non-ionic surfactant(Oleyldimethylamineoxide,O... In order to develop turbulent drag-reducing technology by using an environmentally friendly additive in a water-transporting system,the drag reducing characteristics in a non-ionic surfactant(Oleyldimethylamineoxide,ODMAO) dilute aqueous solution flowing in a circular pipe of 5 mm diameter have been experimentally investigated with an air-driven fluid resistance test device.The rheological characteristics of the solution have also been examined by a rheometer with a cone-plate flow cell.The results show that the ODMAO solutions are drag-reducing when concentration is 400 ppm or higher,that the critical Reynolds number corresponding to the maximum drag reduction rate increases with both concentration and temperature,and that the maximum drag reduction rate can reach up to 70% in the straight pipe.At low shear rates,the shear viscosity of ODMAO solutions with a relatively high drag-reduction behaves similarly to Newtonian fluids;at above a certain critical shear rate,it is firstly shear-thickening,then shear-thinning.Such shear-rate-dependent characteristics of the shear viscosity are attributed to the different transitions of micellar network structure induced by different shear rates.Relaxation of shear stress after removing an applied constant shear rate at which the solution is in the SIS(shear-induced structure) state is found to be well expressed by a 2-step Maxwell model with a tail relaxation time much shorter than that for a drag-reducing cationic surfactant,which indicates that for the ODMAO solution,a viscoelasticity as strong as a drag-reducing cationic surfactant is not needed to realize turbulent drag-reduction. 展开更多
关键词 nonionic surfactant drag-reduction shear viscosity shear stress relaxation
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部