The single phase La2（CO3）3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2（CO3）3·3.4H2O from 30 to 1000 °C were characteri...The single phase La2（CO3）3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2（CO3）3·3.4H2O from 30 to 1000 °C were characterized by XRD, FTIR and DTA-TG. The kinetics of dehydration of La2（CO3）3·3.4H2O in the temperature range of 30-366 °C was investigated under non-isothermal conditions. Flynn-Wall-Ozawa and Friedman isoconversion methods were used to calculate the activation energy and analyze the reaction steps; multivariate non-linear regression program was applied to determine the most probable mechanism and the kinetic parameters. The results show that the thermal dehydration of La2（CO3）3·3.4H2O is a kind of three-step competitive reaction, and controlled by an n-order initial reaction followed by n-order competitive reaction（FnFnFn model）. The activation energy matching with the most probable model is close to value obtained by Friedman method. The fitting curves match the original TG-DTG curves very well.展开更多
The beam horizontal orbit at Hefei Light Source(HLS)was drifting all along while the storage ring was operating.To study this phenomenon,the displacement and the temperature variation of the BPM chamber were measured....The beam horizontal orbit at Hefei Light Source(HLS)was drifting all along while the storage ring was operating.To study this phenomenon,the displacement and the temperature variation of the BPM chamber were measured.By analyzing the measurement results,the main reason that explained the drifting phenomenon was found. The vacuum chamber following the dipole magnets was heated by the synchrotron light,which caused the increasing of the chamber surface temperature.The variation of the chamber temperature was the main reason why the BPM chamber held the horizontal displacement.To suppress the orbit drifting,a compensation method of BPM movement was proposed and its experimental results were given.展开更多
基金Project(201011005-5)supported by the National Land and Resources Public Welfare Scientific Research Project of ChinaProject(41030426)supported by the National Natural Science Foundation of China+1 种基金Project(20095122110015)supported by Specialized Research Fund for the Doctoral Program of Higher Education of ChinaProject(2010-32)supported by Scientific Research Foundation of the Education Ministry for Returned Chinese Scholars,China
文摘The single phase La2（CO3）3·3.4H2 O was synthesized by hydrothermal method. The thermal decomposition and intermediates and final solid products of La2（CO3）3·3.4H2O from 30 to 1000 °C were characterized by XRD, FTIR and DTA-TG. The kinetics of dehydration of La2（CO3）3·3.4H2O in the temperature range of 30-366 °C was investigated under non-isothermal conditions. Flynn-Wall-Ozawa and Friedman isoconversion methods were used to calculate the activation energy and analyze the reaction steps; multivariate non-linear regression program was applied to determine the most probable mechanism and the kinetic parameters. The results show that the thermal dehydration of La2（CO3）3·3.4H2O is a kind of three-step competitive reaction, and controlled by an n-order initial reaction followed by n-order competitive reaction（FnFnFn model）. The activation energy matching with the most probable model is close to value obtained by Friedman method. The fitting curves match the original TG-DTG curves very well.
文摘The beam horizontal orbit at Hefei Light Source(HLS)was drifting all along while the storage ring was operating.To study this phenomenon,the displacement and the temperature variation of the BPM chamber were measured.By analyzing the measurement results,the main reason that explained the drifting phenomenon was found. The vacuum chamber following the dipole magnets was heated by the synchrotron light,which caused the increasing of the chamber surface temperature.The variation of the chamber temperature was the main reason why the BPM chamber held the horizontal displacement.To suppress the orbit drifting,a compensation method of BPM movement was proposed and its experimental results were given.
