宝钢1号高炉水热媒余热回收装置的设计与运行

高炉上热风炉余热回收装置是钢铁工业的重要节能措施。本文介绍了宝钢设计院在场地十分紧张且要维持高炉正常生产的条件下,为本厂特大型1号高炉所做的热风炉水热媒余热回收装置的设计。我国是首次做这项设计。近一年来的生产表明,该装置的工艺设计和各项非标准设计是成功的,为设汁、布置难点所采取的措施是正确的,监控系统可靠、灵敏;焦炉煤气混烧比降低2％左右,热风炉热效率提高4%以上,每小时可节约焦炉煤气3000～4000m^3,投资可在两年内收回。

Thermal Evolution of Organic Matter and Secondary Hydrocarbon Generation from Upper Paleozoic Coal Deposits in Northern China

The metamorphism and hydrocarbon generation from the Upper Paleozoic coal-bearing strata in Northern China have been widely studied by Chinese geologists since the 1990s. Based on a large amount of data of Ro values,combined with geological background,we have systematically analyzed the thermal evolutionary characteristics of or-ganic matter and the stages of hydrocarbon generation from the Permo-Carboniferous coal deposits and discussed the condition of secondary hydrocarbon generation. The distribution range of secondary hydrocarbon generation in North-ern China is thus determined. It is shown that the coal ranks of the Upper Paleozoic coal deposits are higher in the southern and western belts than those in the northern and eastern belts. Really significant secondary hydrocarbon gen-eration is mainly related to the thermal evolution of organic matter during the Himalayan Period. Profitable areas for secondary hydrocarbon generation should be buried at 3000-4000 m up to the present. Maturity of the Permo-Carbon-iferous source rocks is not very high. It is suggested that the Bohai Bay depression is favourable for secondary hydro-carbon generation and has good oil and gas prospects.

GC/MS Analysis of Organic Compounds in Hot Water-Extractable Fraction from Shenfu Coal

Shenfu Coal was extracted with hot pure water and slurry was isolated. The concentrated benzene-soluble fraction (CBSF) was analyzed with GC/MS and four types of organic compounds (OCs) were detected: HACOCs,DTEs,DMDT and LCAs. The amount of benzyl benzoate which is the most abundant OC was calculated by an inter-nal standard method with an indicated amount of BP. The broken hydrogen bonds and ether bonds were responsible for the extraction of OCs from the coal .DTEs,DMDT and LCAs are essentially insoluble in water,whereas they are soluble,probably owing to intermolecular interaction of OCs with HACOCs.

STUDY ON THE INFLUENCE OF WETTING HEAT ON COAL SLURRYABILITY

Wetting Heat of various ranks of coals in water was measured by using SETARAM C80D Calorimeter. The data were correlated to coals' slurryability which is characterized by the solid load at the viscosity of 1 Pa's and 25℃. The results showed that the heat of wetting by wa-ter decreases as coal rank increases in the range of brawn coal to bituminous coaI with carbon content of 89% ~90% (daf), and then, increases a little for anthracite. This trend fitted well to the relationship of slurryability to coal rank. The heat of wetting was also correlated to the inher-ent moisture content and the oxygen content of coal, which are commonly considered as slurrya-bility indication parameters. Hence, the wetting heat is another measure of coal's slurryability.

Silica-alumina molar ratio and some factors effect on the synthesis of zeolites from fly ash

In order to improve the activity and eliminate some impurities, pretreatment was used before hydrothermal synthesis. The fly ash was mixed with an aqueous NaOH solution, the alkali melted fly ash was also adopted, which is hydrothermally treated at about 104 ℃, and the liquid/solid ratio was controlled at 6：1. In order to control Si/Al molar ratio, SiO2 or Al2O3 powers were added to the fly ash. The results of XRD and SEM show that the alkali melted can activate fly ash and eliminate its quartz and mullite, along with the improvement of Si/Al molar ratio and alkalinity. In addition, zeolite Na-A changes into sodalite gradually, and nepheline is the synthesized intermediate product. Those results were discussed on the basis of a formation mechanism of zeolite from fly ash.

Influence of Hydrothermal Pre-Treatment of Coal Fly on the Synthesis of Belite Phase

In this paper, the results of an extensive investigation of hydrothermal pre-treatment for synthesizing belite phase from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of one waste kinds （bottom ash-BA or fly ash-FA） from fluidised brown coal combustion in Slovakian power plant and CaO （analytical grade reagent） addition are summarized. Changes in structure and phase composition of hydrothermally synthesized belite precursors and subsequent calcinated products were compared with those of starting mixtures. Based on XRD diffraction patterns, the formation of the new profiles corresponding to CSH phases with low degree of ordering as belite precursors after hydrothermal treatment was confirmed. Calcination of hydrotermally treated products at 900℃ led to transformation of CSH phases to wollastonite, belite and gehlenite phase. Differences in phase composition of products before and after calcination depend upon waste quality and precursor＇s synthesis conditions. Bottom ash isn＇t suitable as raw material for synthesizing belite phase because of high CaO content fixed in anhydrite form （44.1%）. Coal fly ash with low CaO content in anhydrite form （4.2%） and its hydrothermal treatment in combination with subsequent heating offer opportunities for the utilization of coal fly ash as raw material for belite production.

Optimal design of heat exchanger header for coal gasification in supercritical water through CFD simulations

Heat exchangers play an important role in supercritical water coal gasification systems for heating feed and cooling products. However, serious deposition and plugging problems always exist in heat exchangers. CFD modeling was used to simulate the transport characteristics of solid particles in supercdtical water through the shell and tube of heat exchangers to alleviate the problems. In this paper, we discuss seven types of exchangers CA, B, C D, E, F and G）, which vary in inlet nozzle configuration, header height, inlet pipe diameter and tube pass distribution. In the modeling, the possibility of deposition in the header was evaluated by accumulated mass of particles; we used the velocity contour of supercritical water （SCW） to evaluate the uniformity of the velocity dis- tribution among the tube passes. Simulation results indicated that the optimum heat exchanger had structure F, which had a rectangular configuration of tube pass distractions, a bottom inlet, a 200-mm header height and a 10-ram inlet pipe diameter.

Low-temperature Synthesis of Belite Cement from Reactive Mixtures Based on Coal Fly Ash

This paper summarizes the selected results of an extensive investigation of application of two methods （hydrothermal and mechanochemical） assisted by calcination for synthesizing belite cement from reactive mixtures （CaO/SiO2 molar ratio of 2） consisting of various waste kinds from fluidized brown coal combustion in Slovakian power plant and CaO addition. Based on XRD diffraction patterns and infrared spectra ofpre-treatment products, the formation of the new profiles corresponding to CSH phases with low degree of ordering as belite precursors after hydrothermal treatment as well as metastables calcium silicates and aluminosilicates in mechanosynthesized products was confirmed. Calcination of hydrothermally treated products led to transformation of CSH phases to wollastonite （CS）, belite and gehlenite phase, whereas creation oft^- and I^-C2S or wollastonite in milled reactive mixture took place. Differences in phase composition of products before and after calcination depend upon waste quality and precursor＇s synthesis conditions. Bottom ash isn＇t suitable as raw material for synthesizing belite phase because of high CaO content fixed in anhydrite form （44.1%）. Coal fly ash with low CaO content in anhydrite form （4.2%） and its mechanochemical or hydrothermal treatment in combination with subsequent heating offer opportunities for the utilization of coal fly ash as raw material for belite production.

Integrated utilization of low-grade thermal energy in hot coal mine

This paper explores the integrated utilization of low-grade thermal energy in hot coal mines, based on analysis of original heating, refrigerating, mine draining, bath draining and air exhaust systems, and in combination with the actual conditions of Tangkou Coal Mine in Shandong Province. It presents a set of comprehensive and integrated utilization schemes for the various different kinds of low quality heat energy. With heat pumps, the recycling of the low quality heat energy from the drainage, bathing water and the exhaust air can occur in winter, and in summer, there exists condensed heat of the refrigerating system. When in conjunction with solar collectors, the thermal utilization of solar power can be realized for the whole year. The system achieves mine drainage and bathing water purification and recycling, as well as purifying exhaust air by water spraying. It also satisfies the demands of a whole year＇s bathing heat for the coal mine, with refrigeration in summer, and heating for the ground house and shaft house in winter. It is able to integrate different kinds of low quality heat energy and low emission drainage and dust, and can replace the traditional boiler heating system. Finally, the system reduces conventional energy consumption and the amount of mine water drainage.